11H-Benzo(a)carbazole, 5,5'-(phenylmethylene)bis(11-ethyl- | 82926-35-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 11H-Benzo(a)carbazole, 5,5'-(phenylmethylene)bis(11-ethyl-
• 英文别名: 11-ethyl-5-[(11-ethylbenzo[a]carbazol-5-yl)-phenylmethyl]benzo[a]carbazole
• CAS: 82926-35-0
• 化学式: C₄₃H₃₄N₂
• 分子量: 578.7
• InChiKey: NAYABQYUYAOVNR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.2
• 重原子数：
  45
• 可旋转键数：
  5
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  9.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  11H-Benzo(a)carbazole, 5,5'-(phenylmethylene)bis(11-ethyl- 生成 11-ethyl-5-[(E)-(11-ethylbenzo[a]carbazol-11-ium-5-ylidene)-phenylmethyl]benzo[a]carbazole;tetrafluoroborate
  参考文献：
  名称：

  BROWN, D. E.;REYNOLDS, KENNETH

  摘要：

  DOI：

文献信息

• Triarylmethane compounds, their preparation and use as photoconductive systems
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0102745A2

  公开（公告）日：1984-03-14

  Compounds which are useful as sensitisers of photoconductors, having the general formula: in which: like symbols represent identical substituents, at least 4 of R1 to R9 represent hydrogen atoms and the remaining R1 to R9 pairs of groups independently represent: (i) hydrogen, an alkyl group having from 1 to 18 carbon atoms, a substituted alkyl group or an aryl or substituted aryl group, (ii) a halogen atom, a cyano group, a carboxy or alkoxycarbonyl group, a hydroxy group, an alkoxy group, a nitro group or a sulphonic acid group, providing that not more than two such groups (ii) are present in each ring, (iii) an acylamino group, a secondary acylamino group, or a tertiary amino group, in which the pendant substituent groups on the nitrogen atom are alkyl, aryl or aralkyl, providing not more than two sush groups (iii) may be present in each benzocarbazole ring, and (iv) any two groups R1 to R9 on adjacent carbon atoms in a ring may represent the necessary atoms to complete a fused alicyclic, aromatic or heterocyclic ring, R10 represents an alkyl or substituted alkyl group, an aralkyl group, or an aryl or substituted aryl group, Ar represents a heteroaromatic nucleus eontaining 5 or 6 members in the ring at least one of which is O, N or S, or an aromatic ring of the formula: in which: R11 to R16 independently represent a hydrogen or halogen atom, an alkyl or substituted alkyl, an aryl or substituted aryl, hydroxy, alkoxy or aryloxy group, one of R" to R15 may additionally represent an aldehyde or acetyl group or a dialkylamino group, up to two of R" to R15 may additionally represent a cyano, carboxy, alkoxy carbonyl, sulphonic acid or nitro group, and any two adjacent R" to R15 groups may represent the necessary atoms to complete a fused alicyclic, aromatic or heterocyclic ring, and X represents an anion.

  可用作光电导体敏化剂的化合物，其通式为 其中 同类符号代表相同的取代基，R1 至 R9 中至少有 4 个代表氢原子，其余 R1 至 R9 对基团分别代表 (i) 氢、具有 1 至 18 个碳原子的烷基、取代的烷基或芳基或取代的芳基、 (ii) 卤素原子、氰基、羧基或烷氧基羰基、羟基、烷氧基、硝基或磺酸基， 但每个环中的(ii)基不得超过两个、 (iii) 一个酰氨基、一个仲酰基氨基或一个叔氨基，其中氮原子上的悬垂取代基为 烷基、芳基或芳烷基，但每个苯并咔唑环中不能有两个以上的此类基团 （iii）、(iv) 环中相邻碳原子上的任意两个基团 R1 至 R9 可代表完成融合脂环、芳环或杂环所需的原子，R10 代表烷基或取代烷基、芳烷基或芳基或取代芳基、 Ar 代表在环中包含 5 或 6 个成员（其中至少一个是 O、N 或 S）的杂芳香族核，或式 其中 R11 至 R16 分别代表氢原子或卤素原子、烷基或取代烷基、芳基或取代芳基、羟基、烷氧基或芳氧基、 R "至 R15 中的一个可另外代表醛基、乙酰基或二烷基氨基、 R" 至 R15 中最多两个可另外代表氰基、羧基、烷氧基羰基、磺酸基或硝基，以及 任何两个相邻的 R "至 R15 基团可代表完成融合脂环、芳香环或杂环所需的原子，以及 X 代表阴离子。
• Dyes suitable for sensitization of photoconductive systems
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0292322A2

  公开（公告）日：1988-11-23

  Cyanine dyes, particularly indocyanine dyes, having at least 7 carbon atoms in the polymethine chain which may possess a fused cyclopentene or cyclohexene ring in the form of a tri-iodide salt exhibit a substantial reduction in the propensity to associate compared to dyes having the identical cation but different anion. The tri-iodide salts are particularly useful as sensitizers in organic photoconductor systems.

  与具有相同阳离子但不同阴离子的染料相比，三碘化盐形式的聚甲基链中至少有 7 个碳原子的氰基染料，特别是吲哚菁染料，其融合环戊烯环或环己烯环的结合倾向大大降低。三碘化盐在有机光电导体系统中用作敏化剂特别有用。
• BROWN, D. E.;REYNOLDS, KENNETH
  作者：BROWN, D. E.、REYNOLDS, KENNETH

  DOI：——

  日期：——
• US4853310A
  申请人：——

  公开号：US4853310A

  公开（公告）日：1989-08-01
• US4820846A
  申请人：——

  公开号：US4820846A

  公开（公告）日：1989-04-11