1-(2-Methyl-1H-inden-4-yl)-1H-indole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1-(2-Methyl-1H-inden-4-yl)-1H-indole
• 英文别名: 1-(2-methyl-1H-inden-4-yl)indole
• 化学式: C₁₈H₁₅N
• 分子量: 245.3
• InChiKey: SSUBKVVMCBXOMU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Heterocyclic substituted metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20050261449A1

  公开（公告）日：2005-11-24

  This invention relates to compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition, lanthanide, or actinide metal atom; E is an indenyl ligand substituted in any position with at least one aromatic or pseudoaromatic heterocyclic substituent that is bonded to the indenyl ring through a nitrogen or phosphorous ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl, heterocyclopentadienyl, indenyl, heteroindenyl, fluorenyl, or heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be E; Y is an optional bridging group; y is zero or one; X are, independently, univalent anionic ligands, and provided that when A is E, and y is one, and Y is bonded to the one position of each indenyl ligand, and per indenyl ligand there is only one aromatic heterocyclic or pseudoaromatic heterocyclic that is bonded to the indenyl ligand.

  本发明涉及以下式表示的化合物： 其中，M是3、4、5或6族过渡金属、镧系金属或锕系金属原子；E是任何位置上至少带有一种芳香或伪芳香杂环取代基的茚基配体，该取代基通过氮或磷杂环原子与茚环相连；A是取代或未取代的环戊二烯基、杂环戊二烯基、茚基、杂茚基、芴基或杂芴基配体，或其他单阴离子配体，或A可以独立地是E；Y是可选的桥接基团；y为零或一；X是独立的一价阴离子配体，且当A为E，y为一，并且Y与每个茚基配体的一位置相连时，每个茚基配体仅与一个芳香杂环或伪芳香杂环相连。
• Production of propylene-based polymers
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：EP2103634A1

  公开（公告）日：2009-09-23

  In a process for producing a propylene-based olefin homopolymer or copolymer, a monomer composition comprising propylene is contacted with a polymerization catalyst system under homogeneous polymerization conditions (such as solution, supersolution or supercritical conditions), wherein the polymerization catalyst system includes an activator and a bridged bis-indenyl transition metal (group 4) compound substituted with a carbazole (unsubstituted or substituted) at the 4 position.

  在一种生产丙烯基烯烃均聚物或共聚物的工艺中，包含丙烯的单体组合物在均相聚合条件（如溶液、超溶液或超临界条件）下与聚合催化剂体系接触，其中聚合催化剂体系包括活化剂和在 4 位被咔唑（未取代或取代）取代的桥联双烯基过渡金属（第 4 族）化合物。
• Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
  申请人：CHISSO CORPORATION

  公开号：US20010053833A1

  公开（公告）日：2001-12-20

  The present invention provides a metallocene compound which produces an olefin polymer having a high molecular weight with a high stereoregularity. The metallocene compound has the following formula (1): Q(C 5 H 4-m R 1 m )(C 5 H 4-n R 2 n )MXY  (1) wherein (C 5 H 4-m R 1 m ) and (C 5 H 4-n R 2 n ) each independently represent a cyclopentadienyl group; C 5 H 4-m and C 5 H 4-n each independently represent a cyclopentadienyl ring; m represents an integer of 1-3; n represents an integer of 2 or 3; R 1 and R 2 are each independently a substituent bonded respectively to C 5 H 4-m and C 5 H 4-n , and represent a hydrocarbon group of 1-20 carbon atoms, a silicon-containing hydrocarbon group of 1-20 carbon atoms or a heteroaromatic group; each R 1 m and each R 2 n may be the same or different; one pair of R 2 's in the R 2 n are bonded to each other to form at least one ring; Q represents a divalent group for cross-linking (C 5 H 4-m R 1 m ) and (C 5 H 4-n R 2 n ); M represents a titanium atom, a zirconium atom or a hafnium atom; and X and Y are the same or different and each a hydrogen atom, a halogen atom or a hydrocarbon group.

  本发明提供了一种茂金属化合物，它可以生产出具有高分子量和高立体规整度的烯烃聚合物。该茂金属化合物具有下式（1）： Q(C 5 H 4-m R 1 m )(C 5 H 4-n R 2 n )MXY (1) 其中 (C 5 H 4-m R 1 m ）和（C 5 H 4-n R 2 n )各自独立地代表一个环戊二烯基团； C 5 H 4-m 和 C 5 H 4-n 各自独立地代表一个环戊二烯环； m 代表 1-3 的整数 n 代表 2 或 3 的整数； R 1 和 R 2 分别独立地作为取代基与 C 5 H 4-m 和 C 5 H 4-n 代表 1-20 个碳原子的烃基、1-20 个碳原子的含硅烃基或杂芳族基团； 每个 R 1 m 和每个 R 2 n 可以相同，也可以不同；一对 R 2 中的一对 R 2 n 中的一对 R 2 '相互键合，形成至少一个环； Q 代表用于交联的二价基团（C 5 H 4-m R 1 m ）和（C 5 H 4-n R 2 n ); M 代表钛原子、锆原子或铪原子；以及 X 和 Y 相同或不同，各自为氢原子、卤素原子或烃基。
• METALLOCENE COMPOUNDS AS CATALYST COMPONENTS FOR OLEFIN POLYMERIZATION
  申请人：Chisso Corporation

  公开号：EP1066300A1

  公开（公告）日：2001-01-10
• HETEROCYCLIC SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION
  申请人：Exxonmobil Chemical Company Inc.

  公开号：EP1735354A1

  公开（公告）日：2006-12-27