(E)-6-tetradecene-1-ol | 68760-62-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-6-tetradecene-1-ol
• 英文别名: 6E-tetradecen-1-ol；6-Tetradecen-1-ol, (E)；(E)-tetradec-6-en-1-ol
• CAS: 68760-62-3
• 化学式: C₁₄H₂₈O
• 分子量: 212.376
• InChiKey: MVQIAKPRNQLLOQ-CMDGGOBGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (E)-6-tetradecene-1-ol 在 重铬酸吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 (E)-6-tetradecenal
  参考文献：
  名称：

  摘要：

  The Iepidopteran genus Saturnia has three representatives in North America, S. walterorum, S.mendocino, and S. albofasciata. (E4,Z9)-Tetradecadienal (E4,Z9-14 : Ald) was identified as a sex pheromone component for all three species by combinations of coupled gas chromatography-electroantennogram detection (GC-EAD), GC-mass spectrometry (MS), and field trials. In field trials, all three species were strongly attracted to (E4,Z9-14 : Ald) as a single component. Small amounts of (Z)-9-tetradecenal (Z9-14: Ald) also were found in extracts of all three species, but blends of this compound with E4,Z9-14 : Aid were no more attractive to male moths than E4,Z9-14 : Aid alone. Extracts of pheromone glands of female S. walterorum occasionally contained a third, trace compound eliciting responses from male antennae in GC-EAD experiments, but this compound was not identified. It is suggested that the three species can use the same, single component as a sex attractant because the flight period of S. albofasciata (Fall) is different than that of the other two species (spring), whereas the geographic distributions of S. mendocino and S. walterorum overlap over only small portions of their ranges. Furthermore, the latter two species readily hybridize, so there may be minimal fitness cost to cross-attraction.

  DOI：

  10.1023/a:1010310204552

文献信息

• External preparation
  申请人：Sansho Seiyaku Co., Ltd.

  公开号：EP0355842A2

  公开（公告）日：1990-02-28

  This invention provides an external preparation effectively preventing skin pigmentation caused by melanin production, i.e. spots or freckle, and having also superior actions on fair-skin making up, the external preparation containing unsaturated straight-­chain fatty acids or unsaturated straight-chain aliphatic alcohols or the derivatives thereof as effective ingredients.

  本发明提供了一种外用制剂，可有效防止因黑色素生成而引起的皮肤色素沉着，即色斑或雀斑，同时对白皙皮肤的妆容也有卓越功效，该外用制剂含有不饱和直链脂肪酸或不饱和直链脂肪醇或其衍生物作为有效成分。
• Process for the preparation of lactones
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0341773B1

  公开（公告）日：1996-09-11
• US4960906A
  申请人：——

  公开号：US4960906A

  公开（公告）日：1990-10-02
• US5025092A
  申请人：——

  公开号：US5025092A

  公开（公告）日：1991-06-18
• US5128438A
  申请人：——

  公开号：US5128438A

  公开（公告）日：1992-07-07