蚁酸与2-(二甲基氨基)乙醇的化合物 | 59101-30-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 蚁酸与2-(二甲基氨基)乙醇的化合物
• 英文名称: N,N-dimethylethanolammonium formate
• 英文别名: N,N-dimethyl-N-hydroxyethyl ammonium formate；2-hydroxy-N,N-dimethylethanaminium formate；2-hydroxyethyldimethylammonium formate；2-hydroxyethyl(dimethyl)azanium;formate
• CAS: 59101-30-3
• 化学式: CH₂O₂*C₄H₁₁NO
• 分子量: 135.163
• InChiKey: VHVATZZFHAQBPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.76
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  60.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  蚁酸与2-(二甲基氨基)乙醇的化合物 、 sodium 1,4-bis(2-ethylhexyl)sulfosuccinate 以 二氯甲烷 、 水 为溶剂， 反应 12.0h， 以91%的产率得到N,N-dimethylethanolammonium 1,4-bis(2-ethylhexyl)sulfosuccinate
  参考文献：
  名称：

  A Step toward the Development of High-Temperature Stable Ionic Liquid-in-Oil Microemulsions Containing Double-Chain Anionic Surface Active Ionic Liquid

  摘要：

  Owing to their fascinating properties and wide range of potential applications, interest in nonaqueous microemulsions has escalated in the past decade. In the recent past, nonaqueous microemulsions containing ionic liquids (ILs) have been utilized in performing chemical reactions, preparation of nanomaterials, synthesis of nanostructured polymers, and drug delivery systems. The most promising fact about IL-in-oil microemulsions is their high thermal stability compared to that of aqueous microemulsions. Recently, surfactant-like properties of surface active ionic liquids (SAILs) have been used for preparation of microemulsions with high-temperature stability and temperature insensitivity. However, previously described methods present a limited possibility of developing IL-in-oil microemulsions with a wide range of thermal stability. With our previous work, we introduced a novel method of creating a huge number of IL-in-oil microemulsions (Rao, V. G.; Ghosh, S.; Ghatak, C.; Mandal, S.; Brahmachari, U.; Sarkar, N. J. Phys. Chem. B 2012, 116, 2850-2855), composed of a SAIL as a surfactant, room-temperature ionic liquids as a polar phase, and benzene as a nonpolar phase. The use of benzene as a nonpolar solvent limits the application of the rnicroemulsions to temperatures below 353 K. To overcome this limitation, we have synthesized N,N-dimethylethanolammonium 1,4-bis(2-ethylhexyl) sulfosuccinate (DAAOT), which was used as a surfactant. DAAOT in combination with isopropyl myristate (IPM, as an oil phase) and ILs (as a polar phase) produces a huge number of high-temperature stable IL-in-oil microemulsions. By far, this is the first report of a huge number of high-temperature stable IL-in-oil microemulsions. In particular, we demonstrate the wide range of thermal stability of [C(6)mim][TF2N]/DAAOT/IPM microemulsions by performing a phase behavior study, dynamic light scattering measurements, and H-1 NMR measurements and by using coumarin-480 (C-480) as a fluorescent probe molecule.

  DOI：

  10.1021/jp403265p
• 作为产物：
  描述：

  N,N-二甲基乙醇胺 、 甲酸 反应 24.5h， 生成 蚁酸与2-(二甲基氨基)乙醇的化合物
  参考文献：
  名称：

  Extraction process of sulfur compounds from fuels with protic ionic liquids

  摘要：

  燃料中的硫化合物对环境有害，构成了一项巨大挑战。本研究设计了一系列质子离子液体（PILs），并评估了它们的萃取脱硫能力。

  DOI：

  10.1039/c4ra16186f

文献信息

• Synthesis and structure-properties relationship studies of biodegradable hydroxylammonium-based protic ionic liquids
  作者：Andromachi Tzani、Marianthi Elmaloglou、Charalampos Kyriazis、Dionysia Aravopoulou、Ioannis Kleidas、Achilleas Papadopoulos、Efstathia Ioannou、Apostolos Kyritsis、Epaminondas Voutsas、Anastasia Detsi

  DOI：10.1016/j.molliq.2016.09.086

  日期：2016.12

  Abstract In this work sixteen hydroxyl ammonium Protic Ionic Liquids derived from a proton transfer reaction between four different substituted amines and four different low molecular weight aliphatic and alicyclic carboxylic acids have been synthesized. The synthesized PILs were structurally characterized by NMR and FT-IR spectroscopy whereas two of their more important physicochemical properties

  摘要 在这项工作中，合成了 16 种羟基铵质子离子液体，这些质子离子液体源自四种不同的取代胺和四种不同的低分子量脂肪族和脂环族羧酸之间的质子转移反应。合成的 PIL 通过 NMR 和 FT-IR 光谱进行结构表征，同时评估了它们的两个更重要的物理化学性质，即粘度和玻璃化转变温度 (T g )。讨论了烷基链长度和取代对 PILs 支架的阴离子和阳离子组分的影响，以研究其性质。似乎 T g 值主要受羧酸根阴离子结构的影响，而粘度主要受 PIL 的阳离子部分的结构特征控制。为了估计它们的环境影响并加强它们的“绿色”特性，还进行了生物降解研究以及毒性评估实验。合成的 PILs 可以自信地标记为绿色，因为它们对盐水虾 A. salina 的无节幼体无毒或毒性低，而根据测量生物的压力呼吸测量法，它们显示出 41-64% 的生物降解性水平。微生物的需氧量 (BOD 5 )，以便在五天内通过生物氧化降解 PIL。
• Hydroxyl ammonium ionic liquids as media for biocatalytic oxidations
  作者：Athena A. Papadopoulou、Andromachi Tzani、Dimitrios Alivertis、Maria H. Katsoura、Angeliki C. Polydera、Anastasia Detsi、Haralambos Stamatis

  DOI：10.1039/c5gc02381e

  日期：——

  Hydroxyl ammonium ionic liquids are a biodegradable, non-toxic family of third generation ionic liquids with a beneficial effect on the catalytic efficiency of metalloproteins such as cytochrome c.

  羟基铵离子液体是一种可生物降解、无毒的第三代离子液体家族，对金属蛋白如细胞色素c的催化效率具有益处。
• Extraction process of sulfur compounds from fuels with protic ionic liquids
  作者：Zhuo Li、Jinggang Xu、Dan Li、Changping Li

  DOI：10.1039/c4ra16186f

  日期：——

  Sulfur compounds in fuels are hazardous to the environment and present a great challenge. In this study, a series of protic ionic liquids (PILs) was designed and their extraction desulfurization capability was evaluated.

  燃料中的硫化合物对环境有害，构成了一项巨大挑战。本研究设计了一系列质子离子液体（PILs），并评估了它们的萃取脱硫能力。
• A Step toward the Development of High-Temperature Stable Ionic Liquid-in-Oil Microemulsions Containing Double-Chain Anionic Surface Active Ionic Liquid
  作者：Vishal Govind Rao、Chiranjib Banerjee、Surajit Ghosh、Sarthak Mandal、Jagannath Kuchlyan、Nilmoni Sarkar

  DOI：10.1021/jp403265p

  日期：2013.6.20

  Owing to their fascinating properties and wide range of potential applications, interest in nonaqueous microemulsions has escalated in the past decade. In the recent past, nonaqueous microemulsions containing ionic liquids (ILs) have been utilized in performing chemical reactions, preparation of nanomaterials, synthesis of nanostructured polymers, and drug delivery systems. The most promising fact about IL-in-oil microemulsions is their high thermal stability compared to that of aqueous microemulsions. Recently, surfactant-like properties of surface active ionic liquids (SAILs) have been used for preparation of microemulsions with high-temperature stability and temperature insensitivity. However, previously described methods present a limited possibility of developing IL-in-oil microemulsions with a wide range of thermal stability. With our previous work, we introduced a novel method of creating a huge number of IL-in-oil microemulsions (Rao, V. G.; Ghosh, S.; Ghatak, C.; Mandal, S.; Brahmachari, U.; Sarkar, N. J. Phys. Chem. B 2012, 116, 2850-2855), composed of a SAIL as a surfactant, room-temperature ionic liquids as a polar phase, and benzene as a nonpolar phase. The use of benzene as a nonpolar solvent limits the application of the rnicroemulsions to temperatures below 353 K. To overcome this limitation, we have synthesized N,N-dimethylethanolammonium 1,4-bis(2-ethylhexyl) sulfosuccinate (DAAOT), which was used as a surfactant. DAAOT in combination with isopropyl myristate (IPM, as an oil phase) and ILs (as a polar phase) produces a huge number of high-temperature stable IL-in-oil microemulsions. By far, this is the first report of a huge number of high-temperature stable IL-in-oil microemulsions. In particular, we demonstrate the wide range of thermal stability of [C(6)mim][TF2N]/DAAOT/IPM microemulsions by performing a phase behavior study, dynamic light scattering measurements, and H-1 NMR measurements and by using coumarin-480 (C-480) as a fluorescent probe molecule.