3-(tert-Butylperoxy)-1,1,5-trimethylcyclohexane | 77061-52-0

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 3-(tert-Butylperoxy)-1,1,5-trimethylcyclohexane
• 英文别名: 3-tert-butylperoxy-1,1,5-trimethylcyclohexane
• CAS: 77061-52-0
• 化学式: C₁₃H₂₆O₂
• 分子量: 214.34
• InChiKey: OXGOEZHUKDEEKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Thermoplastic resin composition having improved external appearance and excellent weatherability
  申请人：Kim Dong-sung

  公开号：US20060148992A1

  公开（公告）日：2006-07-06

  The present invention relates to an acrylonitrile (ASA) type thermoplastic resin composition with excellent weatherability and appearance properties, and more particularly, to an acrylate-styrene-acrylonitrile type thermoplastic resin composition comprising a) an acrylate-styrene-acrylonitrile graft copolymer; b) a butadienc-acrylonitrile mcthylmethacrylate graft copolymer; c) a copolymer of aromatic vinyl compound and vinylcyanide compound; and d) an alkyl acrylate copolymer, which has remarkably improved appearance properties such as scratch resistance, color (color stability) and gloss as well as excellent basic properties and weatherability.

  本发明涉及一种具有优异耐候性和外观特性的丙烯腈(ASA)型热塑性树脂组合物，更具体地，涉及一种丙烯酸酯-苯乙烯-丙烯腈型热塑性树脂组合物，包括a)丙烯酸酯-苯乙烯-丙烯腈嫁接共聚物；b)丁二烯-丙烯腈-甲基甲基丙烯酸酯嫁接共聚物；c)芳香族乙烯化合物和氰基乙烯化合物的共聚物；和d)烷基丙烯酸酯共聚物，其具有显著改善的外观特性，如耐划痕性、颜色稳定性和光泽度，以及优异的基本性能和耐候性。
• Resin composition for optical material
  申请人：Yonezawa Jun

  公开号：US20080266493A1

  公开（公告）日：2008-10-30

  An optical material having a high birefringence and a small absolute value of a photoelastic coefficient is provided by use of a resin composition for an optical material comprising a resin (a) having a positive photoelastic coefficient and a negative inherent birefringence and a resin (b) having a negative photoelastic coefficient and a negative inherent birefringence.

  通过使用光学材料的树脂组合物，提供具有高双折射和小光弹性系数绝对值的光学材料。该组合物包括具有正光弹性系数和负固有双折射的树脂(a)和具有负光弹性系数和负固有双折射的树脂(b)。
• Expandable thermoplastic polymer beads and process for their production
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0017086A1

  公开（公告）日：1980-10-15

  Expandable thermoplastic polymer beads are described which comprise composite beads consisting of a core and a skin and containing a foaming agent; the core being composed of a polymer made from one or more vinyl monomers; the skin being composed of an olefin polymer containing some or all of said vinyl monomers; the foaming agent being a gas or a liquid at ordinary temperatures and pressures and having a boiling point below the softening point of the core material of the beads. Furthermore a process for the production of the expandable thermoplastic polymer beads is described, which comprises suspending grains of a vinyl polymer, a powdered olefin polymer, one or more vinyl monomers and a cross-linking agent in an aqueous medium containing a dispersing agent, and polymerizing the vinyl monomers in the presence of an initiator, wherein a foaming agent is added to the dispersion mixture during or after the polymerization or grains of the vinyl polymer containing the foaming agent are used as starting material, the foaming agent being a gas or a liquid at iordinary temperature and pressure.

  所述可膨胀热塑性聚合物珠由复合珠组成，复合珠由芯材和表皮组成，并含有发泡剂；芯材由一种或多种乙烯基单体制成的聚合物组成；表皮由含有部分或全部所述乙烯基单体的烯烃聚合物组成；发泡剂在常温常压下为气体或液体，其沸点低于珠芯材料的软化点。此外，还描述了一种生产可膨胀热塑性聚合物珠的工艺，该工艺包括将乙烯基聚合物颗粒、粉末状烯烃聚合物、一种或多种乙烯基单体和交联剂悬浮在含有分散剂的水介质中、在聚合过程中或聚合后向分散混合物中加入发泡剂，或使用含有发泡剂的乙烯基聚合物颗粒作为起始材料，发泡剂在常温常压下为气体或液体。
• Expanded shaped articles of a heat resistant synthetic resin
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0032582A2

  公开（公告）日：1981-07-29

  Disclosed are expanded shaped articles of a heat resistant synthetic resin which are obtained by pre-expanding expandable polymer particles containing a foaming agent, whose monomeric composition comprises 20 to 100% by weight of tertiary butyl styrene and 80 to 0% by weight of other polymerizable monomers, and heating the resulting preexpanded particles to thereby produce expanded shaped articles. Expanded shaped articles are also obtained by extrusion foaming.

  本发明公开了一种耐热合成树脂膨化定型制品，该制品是通过预膨化含有发泡剂的可膨化聚合物颗粒获得的，其单体成分包括 20%至 100%（按重量计）的叔丁基苯乙烯和 80%至 0%（按重量计）的其他可聚合单体，并通过加热所得预膨化颗粒来生产膨化定型制品。也可通过挤压发泡获得膨胀定型产品。
• Curable molding composition and its use for producing thermoset fiber-reinforced molded articles
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0052881A2

  公开（公告）日：1982-06-02

  Curable molding compositions comprising a mixture of: I. from about 25 to about 90 weight percent of a thermosetting resin containing: (a) from about 5 to about 95 weight percent of a polyester resin derived from the reaction of a poly(acrylate) and a vinyl monomer, said poly(acrylate) and vinyl monomer essentially free from functional groups reactive with the polyol of the polyisocyanate of (b); (b) from about 95 to about 5 weight percent of a polyurethane derived from the reaction of a saturated polyol and a polyisocyanate, said polyol and polyisocyanate free from unsaturated groups capable of copolymerizing with the poly(acrylate) or vinyl monomer of (a); and II. from about 75 to about 10 weight percent of one or more fibers with a melting point or a glass transition temperature above about 130°C; wherein (b) constitutes less than 40 weight percent of (I) and (II). These compositions are especially suited to produce thermoset fiber-reinforced molded articles by rapid injection molding techniques.

  可固化成型组合物，由以下物质的混合物组成 I. 约 25 至约 90 重量百分比的热固性树脂，其中含有 (a) 约 5%至约 95%的聚酯树脂，由聚丙烯酸酯和乙烯基单体反应生成，所述 聚丙烯酸酯和乙烯基单体基本上不含与(b)的多异氰酸酯的多元醇反应的官能团； (b) 约 95%至约 5%的由饱和多元醇和多异氰酸酯反应生成的聚氨酯，所述 多元醇和多异氰酸酯不含能与(a)的聚丙烯酸酯或乙烯基单体共聚的不饱和基 团；以及 II. 一种或多种熔点或玻璃化转变温度高于约 130°C 的纤维的重量百分比从约 75% 到约 10%；其中(b)占(I)和(II)的重量百分比小于 40%。这些组合物特别适用于通过快速注塑成型技术生产热固性纤维增强模塑制品。