2,3-bis(difluoramino)propyl acrylate | 21695-79-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2,3-bis(difluoramino)propyl acrylate
• 英文别名: 2,3-Bis(difluoroamino)propyl prop-2-enoate
• CAS: 21695-79-4
• 化学式: C₆H₈F₄N₂O₂
• 分子量: 216.135
• InChiKey: GIFZJPXYIFPWKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  32.8
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2,3-bis(difluoramino)propyl α,β-dibromopropionate 在 亚磷酸三乙酯 作用下， 以 苯 为溶剂， 以30%的产率得到2,3-bis(difluoramino)propyl acrylate
  参考文献：
  名称：

  US3968150

  摘要：

  公开号：

文献信息

• Process for the preparation of nitrogen- and fluorine-containing
  申请人：Rohm and Haas Company

  公开号：US03968150A1

  公开（公告）日：1976-07-06

  1. A method for the preparation of difluoraminoalkyl acrylates and methacrylates in which there are at least two difluoramino groups present and the alkyl contains two to eighteen carbon atoms which comprises reacting in the temperature range of about 0.degree. C. up to the reflux temperature of the reaction mixture a member from the class consisting of a difluoraminoalkyl .alpha.,.beta.-dibromopropionate and difluoraminoalkyl .alpha.,.beta.-dibromoisobutyrate in the presence of a compound having the formula ##EQU1## wherein R is a member from the group consisting of alkoxy one to four carbon atoms, alkyl one to eight carbon atoms, phenyl, alkylphenyl in which the alkyl portion contains from one to eight carbon atoms, phenoxy and alkylphenoxy in which the alkyl portion contains from one to eight carbon atoms.

  一种制备含有至少两个二氟氨基基团和烷基含有2-18个碳原子的二氟氨基丙烯酸酯和甲基丙烯酸酯的方法，包括在约0℃到反应混合物的回流温度范围内反应二氟氨基烷基α,β-二溴丙酸酯和二氟氨基烷基α,β-二溴异丁酸酯中的一种，同时存在化合物，其化学式为##EQU1##其中R为一种选自以下组的成员：一至四个碳原子的烷氧基，一至八个碳原子的烷基，苯基，其中烷基部分含有一至八个碳原子的烷基苯基，苯氧基和其中烷基部分含有一至八个碳原子的烷基苯氧基。
• Rubber composition comprising nitrile group-containing highly saturated copolymer rubber and ethylenically saturated copolymer rubber
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0704480A1

  公开（公告）日：1996-04-03

  A rubber composition comprising (i) a nitrile group-containing highly saturated copolymer rubber, which is a product obtained by hydrogenating the conjugated diene portion of an unsaturated nitrile-conjugated diene copolymer, and (ii) an ethylene-α-olefin-non-conjugated diene copolymer rubber. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and has a sulfur atom which is directly bound to at least one of the tertiary carbon atoms; and the highly saturated copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80.

  一种橡胶组合物，包括(i)含腈基的高饱和度共聚橡胶，它是通过氢化不饱和腈-共轭二烯共聚物的共轭二烯部分而得到的产物，以及(ii)乙烯-α-烯烃-非共轭二烯共聚橡胶。高饱和共聚橡胶具有一个具有 12 至 16 个碳原子的烷硫基，其中包括至少三个叔碳原子，并具有一个与至少一个叔碳原子直接结合的硫原子；高饱和共聚橡胶的门尼粘度为 15 至 200，碘值不大于 80。
• Highly saturated nitrile rubber, process for producing same, vulcanizable rubber composition, aqueous emulsion and adhesive composition
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0704459A1

  公开（公告）日：1996-04-03

  A nitrile group-containing highly saturated copolymer rubber which is a hydrogenated product of an unsaturated nitrile-conjugated diene copolymer. The highly saturated copolymer rubber has an alkylthio group having 12 to 16 carbon atoms, which include at least three tertiary carbon atoms, and having a sulfur atom which is directly bound to at least one of the tertiary carbon atoms, and the highly saturated copolymer rubber further has a Mooney viscosity of 15 to 200 and an iodine value not larger than 80. The highly saturated copolymer rubber is produced by copolymerizing an unsaturated nitrile and a conjugated diene by using as a specific alkylthiol molecular weight modifier. The highly saturated copolymer rubber exhibits a high-rate vulcanizability with a sulfur-containing vulcanizer.

  一种含有腈基的高饱和共聚橡胶，它是不饱和腈-共轭二烯共聚物的氢化产物。该高饱和度共聚橡胶具有一个具有 12 至 16 个碳原子的烷硫基，其中包括至少三个叔碳原子，并具有一个直接与至少一个叔碳原子结合的硫原子，该高饱和度共聚橡胶的门尼粘度为 15 至 200，碘值不大于 80。高饱和度共聚橡胶是通过使用特定的烷基硫醇分子量改性剂，使不饱和腈和共轭二烯共聚而成。高饱和度共聚物橡胶在含硫硫化剂的作用下可进行高速硫化。
• CURABLE RUBBER COMPOSITION FOR THE SEAL AGAINST HOT WATER
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0869144A1

  公开（公告）日：1998-10-07

  This invention provides a vulcanizable rubber composition for use as hot-water seals comprising 100 parts by weight of a rubber mixture composed of 90 to 50% by weight of a nitrile-containing highly saturated copolymer rubber obtained by hydrogenating the conjugated diene portions of an unsaturated nitrile-conjugated diene copolymer rubber or unsaturated nitrile-conjugated diene-ethylenically unsaturated monomer terpolymer rubber, and 10 to 50% by weight of an ethylene-α-olefin copolymer rubber; 0.1 to 30 parts by weight of an organic peroxide vulcanizing agent; and optionally 10 to 100 parts by weight of carbon black. Seals formed by vulcanizing this composition show a very low percent change in volume and elongation, and are not liable to the release of carbon black or the production of surface cracks, upon exposure to hot water containing bleaching powder.

  本发明提供了一种用作热水密封件的可硫化橡胶组合物，该组合物包括 100 份（重量）橡胶混合物，其中 90 至 50%（重量）为通过氢化不饱和腈-共轭二烯共聚物橡胶或不饱和腈-共轭二烯-乙烯基不饱和单体三元共聚物橡胶的共轭二烯部分而获得的含腈高饱和度共聚物橡胶；10 至 50%（重量）为乙烯-α-烯烃共聚物橡胶；0.1 至 30 重量份的有机过氧化物硫化剂；以及 10 至 100 重量份的炭黑。通过硫化这种组合物形成的密封件在暴露于含有漂白粉的热水中时，体积和伸长率的百分率变化非常小，而且不易释放碳黑或产生表面裂纹。
• RUBBER COMPOSITION LOWERED IN HEAT BUILD-UP AND ROLLS
  申请人：NIPPON ZEON CO., LTD.

  公开号：EP0878503A1

  公开（公告）日：1998-11-18

  A rubber composition having a reduced heat build-up, which comprises (a) 100 wt. parts of an elastomer capable of being crosslinked by an organic peroxide crosslinking agent, (b) 10 - 150 wt. parts of a metal salt of an α,β-ethylenically unsaturated carboxylic acid, (c) 5 to 100 wt. parts of magnesium oxide having a BET specific surface area not larger than 25 m2/g, and (d) 0.1 to 30 wt. parts of an organic peroxide crosslinking agent. A roll having an outer peripheral surface portion composed of a vulcanizate of the rubber composition. The roll has high strengths and reduced heat build-up, and is especially suitable for use under a high load.

  一种可减少热积累的橡胶组合物，其中包括：(a) 100 重量份可被有机过氧化物交联剂交联的弹性体；(b) 10 - 150 重量份的α，β-乙烯基不饱和羧酸的金属盐；(c) 5 - 100 重量份的氧化镁，其 BET 比表面积不大于 25 m2/g；(d) 0.1 - 30 重量份的有机过氧化物交联剂。辊子的外周表面部分由橡胶组合物硫化而成。该辊强度高，热量积聚少，特别适合在高负荷下使用。