1,1a(2)-(3,3,5-Trimethylcyclohexylidene)bis[2-(1,1-dimethylpropyl) peroxide] | 88467-53-2

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 英文名称: 1,1a(2)-(3,3,5-Trimethylcyclohexylidene)bis[2-(1,1-dimethylpropyl) peroxide]
• 英文别名: 1,1,5-trimethyl-3,3-bis(2-methylbutan-2-ylperoxy)cyclohexane
• CAS: 88467-53-2
• 化学式: C₁₉H₃₈O₄
• 分子量: 330.5
• InChiKey: VMJIDDGLSSJEFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• THERMOPLASTIC RESIN COMPOSITION FOR SEALING SOLAR CELL, SHEET FOR SEALING SOLAR CELL AND SOLAR CELL
  申请人：Hoya Hiroshi

  公开号：US20100000600A1

  公开（公告）日：2010-01-07

  An object of the present invention is to provide a material used for producing a sheet for sealing a solar cell which is excellent in mechanical strength, solar cell sealing property and transparency if the material is not cross-linked. The thermoplastic resin composition of the present invention for sealing a solar cell is characterized by comprising: (A) 0 to 70 parts by weight of a propylene-based polymer having a melting point of 100° C. or higher and (B) 30 to 100 parts by weight of a propylene-based copolymer satisfying the following requisite (b); (b): MFR (230° C., load: 2.16 kg) falls in a range of 0.01 to 100 g/10 minutes, and at least one of the following requisites (b-1) and (b-2) is satisfied; (b-1): an rr fraction is 60% or more and (b-2): a structural unit derived from propylene is contained in an amount of 55 to 90 mole %, and a structural unit derived from α-olefin having 2 to 20 carbon atoms (excluding propylene) is contained in an amount of 10 to 45 mole %; and an intrinsic viscosity [η] (dL/g) measured in decalin at 135° C. and MFR described above satisfy a specific relational equation.

  本发明的目的是提供一种用于制造太阳能电池密封片的材料，如果该材料未交联，则在机械强度、太阳能电池密封性和透明度方面优异。本发明的用于密封太阳能电池的热塑性树脂组合物的特征在于包括：（A）具有100°C或更高熔点的丙烯基聚合物的0至70重量部分和（B）满足以下必要条件（b）的丙烯基共聚物的30至100重量部分；（b）：MFR（230°C，负载：2.16公斤）在0.01至100克/10分钟的范围内，且满足以下至少一个必要条件（b-1）和（b-2）之一；（b-1）：rr分数为60％或更高，（b-2）：从丙烯基衍生的结构单元的含量为55至90摩尔％，从具有2至20个碳原子（不包括丙烯）的α-烯烃衍生的结构单元的含量为10至45摩尔％；并且在135°C的十二烷基中测量的固有粘度[η]（dL/g）和上述MFR满足特定的关系式。
• Propylene resin composition and use thereof
  申请人：Hoya Hiroshi

  公开号：US20070251572A1

  公开（公告）日：2007-11-01

  The thermoplastic resin composition (Xi) of the present invention comprises (A1), (B1), (C1), and optionally (D1) below: 1 to 90 wt % of an isotactic polypropylene (A1); 9 to 98 wt % of a propylene/ethylene/α-olefin copolymer (B1) containing 45 to 89 mol% of propylene-derived structural units, 10 to 25 molt of ethylene-derived structural units, and optionally, 0 to 30 mol% of C 4 -C 20 α-olefin-derived structural units (a1); 1 to 80 wt % of a styrene-based elastomer (C1); and 0 to 70 wt % of an ethylene/α-olefin copolymer (D1) whose density is in the range of 0.850 to 0.910 g/cm 3 , wherein (A1)+(B1)+(C1)+(D1)=100 wt %.

  本发明的热塑性树脂组合物（Xi）包括以下成分（A1）、（B1）、（C1）和可选的（D1）：1至90重量％的异相聚丙烯（A1）; 9至98重量％的丙烯/乙烯/α-烯烃共聚物（B1），其中含有45至89摩尔％的丙烯衍生结构单元，10至25摩尔％的乙烯衍生结构单元，以及可选地0至30摩尔％的C4-C20α-烯烃衍生结构单元（a1）; 1至80重量％的苯乙烯弹性体（C1）; 以及密度在0.850至0.910 g/cm3范围内的乙烯/α-烯烃共聚物（D1），其中（A1）+（B1）+（C1）+（D1）= 100重量％。
• PROPYLENE BASED RESIN COMPOSITION AND USE THEREOF
  申请人：HOYA Hiroshi

  公开号：US20130011649A1

  公开（公告）日：2013-01-10

  Means for solving the problems The thermoplastic resin composition (X1) of the present invention comprises (A1), (B1), (C1), and optionally (D1) below: 1 to 90 wt % of an isotactic polypropylene (A1); 9 to 98 wt % of a propylene/ethylene/α-olefin copolymer (B1) containing 45 to 89 mol % of propylene-derived structural units, 10 to 25 mol % of ethylene-derived structural units, and optionally, 0 to 30 mol % of C 4 -C 20 α-olefin-derived structural units (a1); 1 to 80 wt % of a styrene-based elastomer (C1); and 0 to 70 wt % of an ethylene/α-olefin copolymer (D1) whose density is in the range of 0.850 to 0.910 g/cm 3 , wherein (A1)+(B1)+(C1)+(D1)=100 wt %.

  解决问题的方法本发明的热塑性树脂组合物（X1）包括以下成分（A1）、（B1）、（C1）和可选的（D1）：1至90重量％的异相聚丙烯（A1）；9至98重量％的丙烯/乙烯/α-烯烃共聚物（B1），其中含有45至89摩尔％的丙烯衍生结构单元，10至25摩尔％的乙烯衍生结构单元，以及可选的0至30摩尔％的C4-C20α-烯烃衍生结构单元（a1）；1至80重量％的苯乙烯基弹性体（C1）；以及密度在0.850至0.910 g/cm3范围内的乙烯/α-烯烃共聚物（D1），其中（A1）+（B1）+（C1）+（D1）= 100重量％。
• SOLAR-CELL SEALANT AND SOLAR-CELL MODULE USING SAME
  申请人：Ikenaga Shigenobu

  公开号：US20130233376A1

  公开（公告）日：2013-09-12

  A solar-cell sealant that has excellent properties such as transparency, flexibility, adhesiveness, heat resistance, appearance, cross-linking characteristics, electrical characteristics, and calenderability. A solar-cell sealant that contains an ethylene/α-olefin/unconjugated-polyene copolymer satisfying requirements (a1) through (a3). Requirement (a1) is that constituent units derived from ethylene constitute 80-90 mol %, constituent units derived from C3-20 α-olefin constitute 9.99-19.99 mol %, and constituent units derived from an unconjugated polyene constitute 0.01-5.0 mol % of said copolymer. Requirement (a2) is that the MFR of said copolymer, as measured in accordance with ASTM D1238 at 190° C. under a 2.16 kg load, be at least 2 g/10 min. and less than 10 g/10 min. Requirement (a3) is that the Shore A hardness of said copolymer, as measured in accordance with ASTM D2240, be 60 to 85.

  一种太阳能电池密封剂，具有透明度、柔韧性、粘附性、耐热性、外观、交联特性、电特性和卷取性等优良性能。该太阳能电池密封剂包含满足要求(a1)至(a3)的乙烯/α-烯烃/非共轭聚烯共聚物。要求(a1)是，乙烯衍生的组分单元占80-90摩尔％，C3-20α-烯烃衍生的组分单元占9.99-19.99摩尔％，非共轭聚烯衍生的组分单元占0.01-5.0摩尔％。要求(a2)是，按照ASTM D1238在190℃下施加2.16kg载荷测量的该共聚物的熔体流率至少为2g/10min，且小于10g/10min。要求(a3)是，按照ASTM D2240测量的该共聚物的Shore A硬度为60至85。
• IN SITU SOLIDIFYING COMPLEX COACERVATES AND METHODS OF MAKING AND USING THEREOF
  申请人：UNIVERSITY OF UTAH RESEARCH FOUNDATION

  公开号：US20170157285A1

  公开（公告）日：2017-06-08

  Described herein are fluid complex coacervates that produce solid adhesives in situ. Oppositely charged polyelectrolytes were designed to form fluid adhesive complex coacervates at ionic strengths higher than the ionic strength of the application site, but an insoluble adhesive solid or gel at the application site. When the fluid, high ionic strength adhesive complex coacervates are introduced into the lower ionic strength application site, the fluid complex coacervate is converted to a an adhesive solid or gel as the salt concentration in the complex coacervate equilibrates to the application site salt concentration. In one embodiment, the fluid complex coacervates are designed to solidify in situ at physiological ionic strength and have numerous medical applications. In other aspects, the fluid complex coacervates can be used in aqueous environment for non-medical applications.

  本文描述了一种可在原位产生固体粘合剂的流体复合共沉淀物。设计了带有相反电荷的聚电解质，以形成在离子强度高于应用现场的离子强度时形成流体粘合复合共沉淀物，但在应用现场形成不溶性粘合固体或凝胶。当将流体高离子强度粘合复合共沉淀物引入较低离子强度的应用现场时，复合共沉淀物中的盐浓度与应用现场的盐浓度达到平衡时，流体复合共沉淀物转化为粘合固体或凝胶。在一种实施方式中，流体复合共沉淀物被设计为在生理离子强度下原位固化，并具有众多医疗应用。在其他方面，流体复合共沉淀物可用于非医疗应用的水环境中。