[4-(羟基甲基)环己基]甲基丙烯酸酯 | 23117-36-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: [4-(羟基甲基)环己基]甲基丙烯酸酯
• 中文别名: 1,4-环己烷二甲醇单丙烯酸酯
• 英文名称: 1,4-cyclohexanedimethanol monoacrylate
• 英文别名: CHDMMA；2-Propenoic acid, [4-(hydroxymethyl)cyclohexyl]methyl ester；[4-(hydroxymethyl)cyclohexyl]methyl prop-2-enoate
• CAS: 23117-36-4
• 化学式: C₁₁H₁₈O₃
• 分子量: 198.262
• InChiKey: URLYGBGJPQYXBN-UHFFFAOYSA-N

物化性质

• 沸点：
  294.2±13.0 °C(Predicted)
• 密度：
  1.020±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  [4-(羟基甲基)环己基]甲基丙烯酸酯 在 N,N-二乙基烯丙胺 、 4,4'-亚丁基双(6-叔丁基-3-甲基苯酚) 、 对苯二酚 作用下， 反应 28.0h， 生成
  参考文献：
  名称：

  ホスホリルコリン基又はその類似基含有重合性化合物、化合物の製造方法及び重合体、並びに化合物を用いた樹脂組成物

  摘要：

  【課題】優れた生体適合性を有し、熱や活性エネルギー線に対する重合性や硬化性が高く、ホスホリルコリン基又はその類似基を有する重合性化合物、それらの製造方法及びそれらを用いた重合体、硬化性樹脂組成物等を提供する。【解決手段】本発明の化合物は、分子内に不飽和基２個以上とホスホリルコリン基及び／又はホスホリルコリン類似基１個以上を有する重合性化合物、及び分子内に不飽和基１個とホスホリルコリン基及び／又はホスホリルコリン類似基２個以上を有する重合性化合物である。【選択図】なし

  公开号：

  JP2023026106A

文献信息

• DENTAL POLYMERIZABLE MONOMER COMPOSITIONS
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20170181932A1

  公开（公告）日：2017-06-29

  Provided are dental polymerizable monomer compositions that can give cured products having high toughness and high rigidity, and dental compositions containing such dental polymerizable monomer compositions and cured products thereof having high mechanical properties. The dental polymerizable monomer composition includes a urethane acrylate compound (A) and a polymerizable compound (B) having at least one polymerizable group selected from methacryloyl groups and acryloyl groups, the urethane acrylate compound (A) being obtained by reacting a specific hydroxyacrylate (a1) with a diisocyanate (a2) having two isocyanate groups bonded to a divalent C 6-9 aromatic hydrocarbon group or a divalent C 6-9 bridged cyclic hydrocarbon group via a methylene group optionally substituted with a hydrocarbon group in place of a hydrogen atom, the proportion of the number of acryloyl groups present in the urethane acrylate compound (A) being 10% to less than 90% relative to the total number of (meth)acryloyl groups in the monomer composition.

  提供了一种牙科可聚合单体组合物，可使固化产物具有高韧性和高刚度，并且含有这种牙科可聚合单体组合物和具有高机械性能的固化产物的牙科组合物。该牙科可聚合单体组合物包括一种脲基丙烯酸酯化合物（A）和一种具有至少一种可聚合基团，所述可聚合基团选自甲基丙烯酰基团和丙烯酰基团的可聚合化合物（B），脲基丙烯酸酯化合物（A）是通过将特定的羟基丙烯酸酯（a1）与具有两个异氰酸基团与一个二价C6-9芳香烃基或一个二价C6-9桥环烃基通过一个亚甲基团或者可选地替代氢原子的烃基的甲烷基团相结合的二异氰酸酯（a2）反应而得到的，相对于单体组合物中（甲）丙烯酰基团的总数，脲基丙烯酸酯化合物（A）中存在的丙烯酰基团的比例为10%至90%。
• Saccharide-measuring fluorescent monomer, saccharide-measuring fluorescent sensor substance, and implantable, saccharide-measuring sensor
  申请人：Ochiai Shouji

  公开号：US20060020182A1

  公开（公告）日：2006-01-26

  A fluorescent monomer compound represented by the following formula (1) is provided: wherein Q, Q′ and D 3 may be the same or different, may be combined together into a fused ring, and are each a substituent selected from the group consisting of a hydrogen atom, a halogen atom, a hydroxyl group, and substituted or unsubstituted alkyl, acyl, oxyalkyl, carboxyl, carboxylate ester, carboxamido, cyano, nitro, amino and aminoalkyl groups; and D 1 , D 2 and D 4 each represent a substituent, wherein at least one of D 1 , D 2 and D 4 is a substituent group comprising a vinyl group at an end thereof, and wherein the substituent group comprising a vinyl group at an end thereof enables the fluorescent monomer compound to be soluble in water.

  提供以下式（1）所代表的荧光单体化合物：其中Q、Q'和D3可以相同也可以不同，可以结合成融合环，并且每个都是从氢原子、卤素原子、羟基以及取代或未取代的烷基、酰基、氧烷基、羧基、羧酯、羧胺、氰基、硝基、氨基和氨基烷基等基团中选择的取代基；D1、D2和D4各代表一个取代基，其中D1、D2和D4中至少有一个是在其末端包含乙烯基的取代基团，且在末端包含乙烯基的取代基团使得该荧光单体化合物可溶于水。
• NOVEL COMPOUND, COMPOSITION COMPRISING THE COMPOUND AND CURED PRODUCT
  申请人：NARUSE Hiroshi

  公开号：US20120296061A1

  公开（公告）日：2012-11-22

  The present invention provides a novel compound and a composition including the compound that exhibit small polymerization shrinkage particularly during curing and are producible at low cost on the industrial scale. The compound of the present invention is represented by Formula ( 1 ):

  本发明提供了一种新型化合物和包括该化合物的组合物，特别是在固化过程中表现出小的聚合收缩，并且可以在工业规模下以低成本生产。本发明的化合物由式（1）表示：
• DENTAL MATERIAL, DENTAL MATERIAL COMPOSITION, DENTAL RESTORATIVE MATERIAL, AND CURED PRODUCT
  申请人：NARUSE Hiroshi

  公开号：US20120296003A1

  公开（公告）日：2012-11-22

  The present invention provides a dental material, a dental material composition and a dental restorative material that exhibit small polymerization shrinkage particularly during curing and are producible at low cost on the industrial scale. The dental material of the present invention includes a specific urethane (meth)acrylic compound represented by Formula (1) described below.

  本发明提供了一种牙科材料、牙科材料组合物和一种在固化过程中特别具有小聚合收缩并且可以在工业规模下低成本生产的牙科修复材料。本发明的牙科材料包括下面描述的由式（1）表示的特定脲（甲）丙烯酸酯化合物。
• Composition for polymerization, method for producing same, composition for a coating containing composition for polymerization, method for producing composition for a coating using composition for polymerization, and method for producing coating
  申请人：FUJIFILM Corporation

  公开号：US10428168B2

  公开（公告）日：2019-10-01

  A composition for polymerization, which can improve the storage stability in a high-temperature environment when a specific sulfobetaine monomer is stored as powder and can inhibit the discoloration of a cured film when the monomer is made into a cured film, and a method for producing the composition for polymerization; a composition for a coating containing the composition for polymerization, a method for producing the composition for a coating using the composition for polymerization, and a method for producing a coating; the composition for polymerization contains a monomer represented by formula (I) and water, in which the moisture content is equal to or higher than 3% by mass and less than 10% by mass

  一种聚合物化合物，可在特定磺基丙氨酸盐单体作为粉末储存时提高高温环境下的储存稳定性，并且当单体制成固化膜时可以抑制固化膜的变色，以及制备该聚合物化合物的方法；一种含有该聚合物化合物的涂层组合物，使用该聚合物化合物制备涂层组合物的方法以及制备涂层的方法；该聚合物化合物包含式（I）所表示的单体和水，其中水分含量等于或高于3%且低于10%的质量。