alpha,alpha-二氢全氟庚基异丁烯酸酯 | 48076-44-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: alpha,alpha-二氢全氟庚基异丁烯酸酯
• 英文名称: 1H,1H-tridecafluoroheptyl methacrylate
• 英文别名: 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoroheptyl methacrylate；2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoroheptyl 2-methylprop-2-enoate
• CAS: 48076-44-4
• 化学式: C₁₁H₇F₁₃O₂
• 分子量: 418.155
• InChiKey: OGTUUPXNYCOCKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  15

安全信息

• 海关编码：
  2916140000

反应信息

• 作为反应物：
  描述：

  alpha,alpha-二氢全氟庚基异丁烯酸酯 在 sodium disulfite 、 对苯二酚 作用下， 以 乙醇 为溶剂， 反应 18.0h， 生成 Sodium; 2-(2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-heptyloxycarbonyl)-propane-1-sulfonate
  参考文献：
  名称：

  Gol'din, G. S.; Averbakh, K. O.; Nekrasova, L. A., Journal of applied chemistry of the USSR, 1984, vol. 57, # 7, p. 1463 - 1467

  摘要：

  DOI：
• 作为产物：
  描述：

  全氟-1-庚醇 、 甲基丙烯酰氯 在 sulfonated coal 、 硫酸 、 对苯二酚 作用下， 以 甲苯 为溶剂， 反应 6.0h， 生成 alpha,alpha-二氢全氟庚基异丁烯酸酯
  参考文献：
  名称：

  Gol'din, G. S.; Averbakh, K. O.; Nekrasova, L. A., Journal of applied chemistry of the USSR, 1984, vol. 57, # 7, p. 1463 - 1467

  摘要：

  DOI：

文献信息

• Optical Element for Correcting Color Blindness
  申请人：Harding Brett T.

  公开号：US20130032758A1

  公开（公告）日：2013-02-07

  Described herein are devices, compositions, and methods for improving color discernment.

  本文描述了用于改善色彩辨识的设备、组合物和方法。
• FLUORORESIN FILM AND FLUORORESIN-LAMINATED ACRYLIC RESIN FILM
  申请人：Kaneka Corporation

  公开号：EP2292692A1

  公开（公告）日：2011-03-09

  An object of the present invention is to provide a novel monolayer and multilayer film that can be employed also for use in interior and exterior members of vehicles, and that have excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin film formed with (C) a fluororesin comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component; and a fuororesin-laminated acrylic resin film, wherein the fluororesin film layer is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型单层和多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和耐污性，例如耐乳酸性和耐晒性。本发明涉及一种由(C)氟树脂形成的氟树脂薄膜，该氟树脂包含(B)含氟(甲基)丙烯酸烷基酯聚合物成分的含氟(甲基)丙烯酸树脂；以及一种氟树脂层压丙烯酸树脂薄膜，其中氟树脂薄膜层层压在包含(A)丙烯酸树脂的薄膜层的至少一个面上。
• Fluororesin-laminated acrylic resin film
  申请人：KANEKA CORPORATION

  公开号：EP2325005A2

  公开（公告）日：2011-05-25

  An object of the present invention is to provide a novel multilayer film that can be employed also for use in interior and exterior members of vehicles, and that has excellent transparency, surface hardness, chemical resistance, and stain resistance such as lactic acid resistance and sunscreen resistance. The present invention is directed to a fluororesin-laminated acrylic resin film, wherein a fluororesin film layer comprising (B) a fluorinated (meth)acrylic resin that contains a fluorine-containing alkyl (meth)acrylate polymer component is laminated on at least one face of a film layer comprising (A) an acrylic resin.

  本发明的目的是提供一种新型多层薄膜，这种薄膜也可用于车辆的内部和外部构件，并具有优异的透明度、表面硬度、耐化学性和抗污性，例如抗乳酸和抗防晒性。本发明涉及一种氟树脂层压丙烯酸树脂薄膜，其中，在由丙烯酸树脂（A）组成的薄膜层的至少一个面上，层压了由含有含氟烷基（甲基）丙烯酸酯聚合物成分的氟化（甲基）丙烯酸树脂（B）组成的氟树脂薄膜层。
• FLUORINE-CONTAINING (METH)ACRYLIC (CO)POLYMER AND MOLDED BODY FILMS THEREOF
  申请人：Kaneka Corporation

  公开号：EP2537869A1

  公开（公告）日：2012-12-26

  Provided are a fluorine-containing (meth)acrylic (co)polymer that scarcely generates gas when subjected to molding process, and is capable of supplying a molded body excellent in external appearance and transparency; a fluorine-containing (meth)acrylic resin film thereof; and a fluororesin laminated resin film having the same properties. The (co)polymer is a fluorine-containing (meth)acrylic (co)polymer obtained by polymerizing a monomer component including 100 to 70% by weight of a fluoroalkyl (meth)acrylate monomer, and 0 to 30% by weight of a different monomer copolymerizable therewith by effect of a radical polymerization initiator having a solubility in water of 0.1% or less by weight at 25°C, and having 8 to 14 carbon atoms.

  本发明提供了一种含氟（甲基）丙烯酸（共）聚合物，该聚合物在进行成型加工时几乎不产生气体，并且能够提供外观和透明度极佳的成型体；一种含氟（甲基）丙烯酸树脂薄膜；以及一种具有相同性能的氟树脂层压薄膜。该（共）聚合物是一种含氟（甲基）丙烯酸（共）聚合物，通过聚合单体组分获得，该单体组分包括 100 至 70% （重量百分比）的氟烷基（甲基）丙烯酸酯单体和 0 至 30% （重量百分比）的可与之共聚的不同单体，这些单体通过自由基聚合引发剂作用而聚合，自由基聚合引发剂在 25°C 时的水溶解度为 0.1% 或以下（重量百分比），且具有 8 至 14 个碳原子。
• Hybrid coating and method to obtain such coating
  申请人：Centre de Recherche Public Henri Tudor

  公开号：EP2762226A1

  公开（公告）日：2014-08-06

  The present invention relates to a method for producing a colloidal suspension of nanoparticles, said method comprising the steps of providing a solid target submerged in a liquid media being a coating forming material, submitted said solid target to pulsed Laser irradiation, and to a method for producing hybrid coating on a substrate comprising the steps of generating a plasma, introducing into the plasma a colloidal suspension of nanoparticles and exposing at least a part of a surface of the substrate to the plasma comprising the colloidal suspension of nanoparticles.

  本发明涉及一种生产纳米颗粒胶体悬浮液的方法，所述方法包括以下步骤：提供浸没在作为涂层形成材料的液体介质中的固体靶材，将所述固体靶材置于脉冲激光照射下，以及在基材上生产混合涂层的方法，所述方法包括以下步骤：产生等离子体，将纳米颗粒胶体悬浮液引入等离子体，以及将基材表面的至少一部分暴露于包含纳米颗粒胶体悬浮液的等离子体中。