2,7-dibromo-9,10-di(p-tolyl)-phenanthrene | 1010812-12-0

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 2,7-dibromo-9,10-di(p-tolyl)-phenanthrene
• 英文别名: 2,7-Dibromo-9,10-bis(4-methylphenyl)phenanthrene
• CAS: 1010812-12-0
• 化学式: C₂₈H₂₀Br₂
• 分子量: 516.275
• InChiKey: QRXGOTGTAWHTAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,7-dibromo-9,10-di(p-tolyl)-phenanthrene 在 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 四氯化碳 为溶剂， 反应 4.0h， 以61.2%的产率得到2,7-dibromo-9,10-di(4-bromomethylphenyl)-phenanthrene
  参考文献：
  名称：

  Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s

  摘要：

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

  DOI：

  10.1021/ol702873z
• 作为产物：
  描述：

  2,7-dibromo-9,10-di(p-tolyl)-9,10-dihydro-phenanthrene-9,10-diol 在 盐酸 、 溶剂黄146 、 锌 作用下， 以 水 为溶剂， 以75.7%的产率得到2,7-dibromo-9,10-di(p-tolyl)-phenanthrene
  参考文献：
  名称：

  Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s

  摘要：

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.

  DOI：

  10.1021/ol702873z

文献信息

• Facile Synthesis of 9,10-Diarylphenanthrenes and Poly(9,10-diarylphenanthrene)s
  作者：Bo He、Hongkun Tian、Yanhou Geng、Fosong Wang、Klaus Müllen

  DOI：10.1021/ol702873z

  日期：2008.3.1

  One-pot reduction of 9,10-diaryl-9,10-dihydrophenanthrene-9,10-diols to 9,10-diarylphenanthrenes was achieved with Zn/H+ in acetic acid. Accordingly, various novel phenanthrenes and polyphenanthrenes with efficient blue emission were easily synthesized.