申请人:JAPAN SYNTHETIC RUBBER CO., LTD.
公开号:EP0388231A2
公开(公告)日:1990-09-19
A thermoplastic resin composition which comprises:
(A) 45-90% by weight of a rubber-modified thermoplastic styrene resin in which the grafting degree is 40-150% by weight based on the weight of the rubbery polymer,
(B) 9.5-54.5% by weight of an aromatic polyester having an intrinsic viscosity of 1.1-2 dl/g as measured at 25°C in o-chlorophenol, and
(C) 0.1-20% by weight of a graft copolymer obtained by graft-copolymerizing a monomer mixture consisting of 60-80% by weight of an aromatic alkenyl compound and 20-40% by weight of an alkenyl cyanide compound on a copolymer consisting essentially of an olefin unit and an epoxy group-containing unsaturated compound unit, and (D) optionally a silicone lubricant in a proportion of 5-20,000 ppm of the total weight of the (A), (B) and
(C) components.
Said thermoplastic resin composition can be prepared by previously mixing a part or the whole of the (B) component, a part or the whole of the (C) component and 0-20% by weight of the (A) component, and then mixing the resulting mixture with the remaining component or components.
一种热塑性树脂组合物,包括
(A) 45-90%(重量百分比)的橡胶改性热塑性苯乙烯树脂,其中接枝度为 40-150%(重量百分比),以橡胶聚合物的重量为基准、
(B) 9.5-54.5%(重量百分比)的芳香族聚酯,该聚酯在 25°C 邻氯苯酚中的固有粘度为 1.1-2 dl/g,以及
(C) 0.1-20%(重量)的接枝共聚物,该接枝共聚物是将 60-80%(重量)的芳香 族烯基化合物和 20-40%(重量)的烯基氰基化合物组成的单体混合物接枝共聚在 主要由烯烃单元和含环氧基团的不饱和化合物单元组成的共聚物上而得,以及 (D) 可选的有机硅润滑剂,其比例为(A)、(B)和(C)组分总重量的 5-20,000 ppm。
(C)组分总重量的 5-20 000 ppm。
制备所述热塑性树脂组合物时,可先将部分或全部(B)组分、部分或全部(C)组分和 0-20% (按重量计)的(A)组分混合,然后将所得混合物与其余组分混合。