Methyl 3-hydroxy-5-phenoxypentanoate | 155638-23-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Methyl 3-hydroxy-5-phenoxypentanoate
• CAS: 155638-23-6
• 化学式: C₁₂H₁₆O₄
• 分子量: 224.257
• InChiKey: PPYOILSQAZIIAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  polyhydroxyalkanoate 生成 Methyl 3-hydroxy-5-phenoxypentanoate 、 3-羟基丁酸甲酯
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Polyhydroxyalkanoate, method for production thereof and microorganisms for use in the same
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20040067576A1

  公开（公告）日：2004-04-08

  A polyhydroxyalkanoate having a monomer unit composition represented by General Formula (1): A m B (1−m) (1) wherein A is represented by General Formula (2), B is at least one selected from the group consisting of monomer units represented by General Formula (3) or (4), and m has a value of 0.01 or larger and smaller than 1: 1 wherein n has a value of 0 to 10, k has a value of 3 or 5, and R is at least one group selected from the group consisting of groups represented by General Formulae (5) to (7): 2 in Formula (5) R1 is a group selected from the group consisting of a hydrogen atom (H), halogen atoms, —CN, —NO 2 , —CF 3 , —C 2 F 5 . and —C 3 F 7 ; and q is an integer selected from 1 to 8; in Formula (6) R2 is a group selected from the group consisting of a hydrogen atom (H), halogen atoms, —CN, —NO 2 , —CF 3 , —C 2 F 5 and —C 3 F 7 ; and r is an integer selected from 1 to 8; in Formula (7) R3 is a group selected from the group consisting of a hydrogen atom (H), halogen atoms, —CN, —NO 2 , —CF 3 , —C 2 F 5 and —C 3 F 7 ; and s is an integer selected from 1 to 8. The efficient production methods are also provided.

  一种聚羟基脂肪酸酯，其单体单元组成由通式（1）表示：AmB（1-m）（1）其中，A由通式（2）表示，B至少选自通式（3）或（4）表示的单体单元组成的群体，m的值大于或等于0.01且小于1:1。其中n的值为0到10，k的值为3或5，R至少选自通式（5）到（7）表示的群体中的一种：2在公式（5）中，R1选自氢原子（H）、卤素原子、—CN、—NO2、—CF3、—C2F5和—C3F7组成的群体，q为1到8之间的整数；在公式（6）中，R2选自氢原子（H）、卤素原子、—CN、— 、— 、— 和— 组成的群体，r为1到8之间的整数；在公式（7）中，R3选自氢原子（H）、卤素原子、—CN、— 、— 、— 和— 组成的群体，s为1到8之间的整数。同时还提供了高效的生产方法。
• Polyhydroxyalkanoate and manufacturing method thereof
  申请人：——

  公开号：US20020160467A1

  公开（公告）日：2002-10-31

  To provide a novel polyhydroxyalkanoate and a mnaufacturing method by a microorganism capable of substantially reducing unintended inonomer units and obtaining the polyhydroxaykanoate in a high yield. A microorganism capable of synthesizing a novel polyhydroxyalkanoate having 3-hydroxy-substituted benzoylalkanoic acid as a monomer unit using a substituted benzoylalkanoic acid as a material is cultured in tha medium containing a substituted benzoylalkanoic acid, then the polyhydroxyalkanoate produced in the cultured bacteria is extracted and recovered.

  提供一种新型聚羟基脂肪酸酯及其制造方法，通过使用一种微生物，能够显著减少不必要的异构体单元，并以高产率获得聚羟基脂肪酸酯。将一种能够使用取代苯甲酰基脂肪酸作为原料，合成具有3-羟基取代苯甲酰基脂肪酸单体的新型聚羟基脂肪酸酯的微生物培养在含有取代苯甲酰基脂肪酸的培养基中，然后提取和回收培养细菌中产生的聚羟基脂肪酸酯。
• Method for manufacturing a polyhydroxyalkanoate
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20040092702A1

  公开（公告）日：2004-05-13

  A method for producing a polyhydroxyalkanoate using a microorganism capable of substantially reducing unintended monomer units and obtaining the polyhydroxyalkanoate in a high yield. A microorganism capable of synthesizing a novel polyhydroxyalkanoate having 3-hydroxy-substituted benzoylalkanoic acid as a monomer unit, using a substituted benzoylalkanoic acid as a material, is cultured in a medium containing a substituted benzoylalkanoic acid. Then, the polyhydroxyalkanoate produced in the cultured bacteria is extracted and recovered.

  一种利用微生物生产聚羟基烷酸酯的方法，该微生物能够大量减少非预期的单体单元，并以高产率获得聚羟基烷酸酯。以取代苯甲酰烷酸为原料，在含有取代苯甲酰烷酸的培养基中培养一种能够合成以 3-羟基取代苯甲酰烷酸为单体单元的新型聚羟基烷酸酯的微生物。然后，提取并回收培养细菌中产生的聚羟基烷酸。
• Polyhydroxyalkanoate
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP1113033B1

  公开（公告）日：2008-11-26
• US6586562B2
  申请人：——

  公开号：US6586562B2

  公开（公告）日：2003-07-01