α，ω-双（联苯基-4-基）-对噻吩 | 256342-43-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: α，ω-双（联苯基-4-基）-对噻吩
• 英文名称: 5,5"-bis(4-biphenylyl)-2,2':5',2"-terthiophene
• 英文别名: 5,5''-bis(biphenyl-4-yl)-2,2':5',2''-terthiophene；BP3T；2,2':5',2''-Terthiophene, 5,5''-bis([1,1'-biphenyl]-4-yl)-；2,5-bis[5-(4-phenylphenyl)thiophen-2-yl]thiophene
• CAS: 256342-43-5
• 化学式: C₃₆H₂₄S₃
• 分子量: 552.785
• InChiKey: ADQTZWZDPZWFPP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  39
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  84.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  5,5''-diiodo-2,2':5',2''-terthiophene 、 4-联苯硼酸 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 various solvent(s) 为溶剂， 以46%的产率得到α，ω-双（联苯基-4-基）-对噻吩
  参考文献：
  名称：

  噻吩/亚苯基共聚体的合成。II [1]。嵌段和交替共聚低聚物

  摘要：

  我们报告了基于Suzuki偶联反应或Grignard反应的嵌段和交替噻吩/亚苯基共聚体的合成。这些反应方案使我们能够以相当高的收率获得目标化合物。通过固态13 C nmr和傅里叶变换ir以及1 H nmr对所得材料进行了充分表征。其中，固态13 C nmr和ir对于表征较高分子量的材料特别有用，因为这些材料难以溶解在有机溶剂中。

  DOI：

  10.1002/jhet.5570370210

文献信息

• Molecular compound, luminous material using the same, and luminous element
  申请人：Japan Chemical Innovation Institute

  公开号：US20020114973A1

  公开（公告）日：2002-08-22

  Provided is a new molecular compound excellent in luminous property, which has a molecular structure wherein a thiophene ring and a benzene (or naphthalene) ring are directly bonded to each other, as a molecular compound making it possible to control its luminous color relatively easily and realize highly efficient and bright luminescence. In this compound, its color tone of emitted light can be variously changed by altering the number of the thiophenering and the benzene (or naphthalene)-ring and the bonding order of the rings. Thus, if this molecular compound is used as a luminous material, it is possible to easily cope with both control of its luminous color and realization of highly efficient and bright luminescence. Use of a luminous material using this molecular compound makes it possible to realize luminescence having wide colors from violet to red highly efficiently.

  提供的是一种新的分子化合物，具有出色的发光性能，其分子结构中，噻吩环和苯环（或萘环）直接连接在一起，作为一种分子化合物，可以相对容易地控制其发光颜色，并实现高效亮度的发光。在这种化合物中，通过改变噻吩环和苯环（或萘环）的数量和环的连接顺序，可以各种改变其发射光的颜色调子。因此，如果将这种分子化合物用作发光材料，就可以轻松应对发光颜色的控制和实现高效亮度的发光。使用这种分子化合物制成的发光材料，可以实现从紫色到红色的广泛颜色的高效发光。
• INDUCING LAYER MATERIALS FOR WEAK EPITAXIAL FILMS OF NON-PLANAR METAL PHTHALOCYANINE
  申请人：YAN Donghang

  公开号：US20110152541A1

  公开（公告）日：2011-06-23

  The present invention relates to inducing layer materials for the preparation of weak epitaxial films of non-planar metal phthalocyanine. The characteristics of the inducing layer materials lies in that the said inducing layer materials replace benzene rings of sexiphenyl by conjugated aromatic group and to replace the hydrogen atoms of benzene rings at the two ends of sexiphenyl by fluorine atoms, thus the regulation of molecular interaction is finally realized by changing the size or the linearity degree of the conjugated aromatic groups, as well as by changing the polarity of the benzene ring at the two ends, consequently, the cell parameters of ( 001 ) crystal face of the new materials are different from that of sexiphenyl and to achieve a effect of inducing the weak epitaxy growth of non-planar metal-phthalocyanine.

  本发明涉及用于制备非平面金属酞菁弱外延薄膜的诱导层材料。该诱导层材料的特点在于，所述诱导层材料通过共轭芳香基团替换六苯基的苯环，并通过将六苯基两端的氢原子替换为氟原子，从而最终通过改变共轭芳香基团的大小或直线度以及改变两端苯环的极性来实现分子相互作用的调节，因此，新材料的（001）晶面的晶胞参数不同于六苯基，并实现诱导非平面金属酞菁的弱外延生长效果。
• INDUCED LAYER MATERIAL FOR PREPARING NON-PLANAR METAL PHTHALOCYANINE WEAK EPITAXY GROWTH THIN FILM
  申请人：Shanghai Casail Display Technology Ltd.

  公开号：EP2518075A1

  公开（公告）日：2012-10-31

  The present invention relates to inducing layer materials for the preparation of weak epitaxial films of non-planar metal phthalocyanine. The characteristics of the inducing layer materials lies in that the said inducing layer materials replace benzene rings of sexiphenyl by conjugated aromatic group and to replace the hydrogen atoms of benzene rings at the two ends of sexiphenyl by fluorine atoms , thus the regulation of molecular interaction is finally realized by changing the size or the linearity degree of the conjugated aromatic groups, as well as by changing the polarity of the benzene ring at the two ends, consequently, the cell parameters of (001) crystal face of the new materials are different from that of sexiphenyl and to achieve a effect of inducing the weak epitaxy growth of non-planar metal-phthalocyanine.

  本发明涉及用于制备非平面金属酞菁弱外延膜的诱导层材料。该诱导层材料的特点在于，用共轭芳香基团取代六联苯的苯环，并用氟原子取代六联苯两端苯环的氢原子，从而通过改变共轭芳香基团的大小或线性度来调节分子间的相互作用、以及改变两端苯环的极性，从而使新材料（001）晶面的晶胞参数与六联苯不同，达到诱导非平面金属酞菁弱外延生长的效果。
• US6355365B1
  申请人：——

  公开号：US6355365B1

  公开（公告）日：2002-03-12