dibromopalladium;N-[(E)-pyridin-2-ylmethylideneamino]benzamide | 1112360-50-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dibromopalladium;N-[(E)-pyridin-2-ylmethylideneamino]benzamide
• CAS: 1112360-50-5
• 化学式: C₁₃H₁₁Br₂N₃OPd
• 分子量: 491.478
• InChiKey: KGUULSXNYHMRGD-RJQKUYQSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.53
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-(pyridine-2-carboxaldehyde)benzhydrazone 、 bis(acetonitrile)palladium(II) bromide 以 二氯甲烷 为溶剂， 以52%的产率得到dibromopalladium;N-[(E)-pyridin-2-ylmethylideneamino]benzamide
  参考文献：
  名称：

  Synthesis of palladium(II) pyridyl acylhydrazone complexes and application to homo- and copolymerization of cyclic olefins

  摘要：

  A series of new palladium(II)/pyridyl acylhydrazone complexes were synthesized through the reaction of PdBr2(NCMe)(2) and pyridyl acylhydrazone. The X-ray crystallographic analysis revealed that the palladium center is coordinated by two bromide atoms and two nitrogen atoms of pyridyl acylhydrazone ligand. This coordination mode of pyridyl acylhydrazone ligand forms a striking contrast to the corresponding nikel(II)/pyridyl acylhydrazone complexes. These new palladium complexes showed high catalytic activity for homopolymerization of cyclic olefins such as norbornene and tetracyclododecene, and for copolymerization of tetracyclododecene with norbornene in the presence of MAO. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.11.024

文献信息

• Synthesis of palladium(II) pyridyl acylhydrazone complexes and application to homo- and copolymerization of cyclic olefins
  作者：Kenichi Ogata、Atsuo Watanabe、Tomoshige Yunokuchi、Akinori Toyota

  DOI：10.1016/j.inoche.2007.11.024

  日期：2008.2

  A series of new palladium(II)/pyridyl acylhydrazone complexes were synthesized through the reaction of PdBr2(NCMe)(2) and pyridyl acylhydrazone. The X-ray crystallographic analysis revealed that the palladium center is coordinated by two bromide atoms and two nitrogen atoms of pyridyl acylhydrazone ligand. This coordination mode of pyridyl acylhydrazone ligand forms a striking contrast to the corresponding nikel(II)/pyridyl acylhydrazone complexes. These new palladium complexes showed high catalytic activity for homopolymerization of cyclic olefins such as norbornene and tetracyclododecene, and for copolymerization of tetracyclododecene with norbornene in the presence of MAO. (C) 2007 Elsevier B.V. All rights reserved.