ε-己内酯、二甘油醇的共聚物 | 36890-68-3

• 物质功能分类: 催化剂及助剂 - 聚合物
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: ε-己内酯、二甘油醇的共聚物
• 中文别名: 聚(已内酯)；环状-1,2-乙二基乙缩醛与2,2’-氧代双[乙醇]的聚合物；聚己內醯胺酮二醇；聚己内酯二醇
• 英文名称: 2-[2-(6-hydroxyhexanoyloxy)ethoxy]ethyl 6-hydroxyhexanoate
• CAS: 36890-68-3；50327-24-7
• 化学式: C₁₆H₃₀O₇
• 分子量: 334.4
• InChiKey: NZUNWRVHLLQLSX-UHFFFAOYSA-N

物化性质

• 密度：
  1.073 g/mL at 25 °C
• LogP：
  1.8 at 25℃

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  23
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  102
• 氢给体数：
  2
• 氢受体数：
  7

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S24/25,S26
• 危险类别码：
  R36
• WGK Germany：
  3
• 海关编码：
  39079999

制备方法与用途

性质

聚己内酯又称聚ε-己内酯，是通过ε-己内酯单体在金属阴离子络合催化剂催化下开环聚合而成的高分子有机聚合物。通过控制聚合条件，可以获得不同的分子量。其外观为白色固体粉末，无毒且不溶于水，易溶于多种极性有机溶剂。

应用

聚(己内酯)具有良好的生物相容性、有机高聚物相容性和生物降解性，可用作细胞生长支持材料，并可与多种常规塑料互相兼容。在自然环境下，6-12个月内即可完全降解。此外，它还具备良好的形状记忆温控性质，广泛应用于药物载体、增塑剂、可降解塑料、纳米纤维纺丝和塑形材料的生产与加工等领域。

材料性能

聚(己内酯)又称聚己内酯二元醇，被广泛应用于聚氨酯弹性体、涂料、胶黏剂等领域。以聚己内酯二元醇制备的聚氨酯制品通常具有较好的柔韧性，经过适度交联后，其拉伸强度、模量、耐溶剂性及耐高温性能等均能得到显著提高。

此外，聚己内酯多元醇同样被广泛应用于上述领域。由该原料制备的弹性体展现出优异的水解稳定性和高、低温性能，并且比传统的聚醚型和普通聚醚型聚氨酯拥有更均衡的性能特点。

文献信息

• ISOTACTIC POLYETHERS AND BIMETALLIC CATALYSTS, METHODS OF MAKING SAME, AND USES THEREOF
  申请人：CORNELL UNIVERSITY

  公开号：US20170335061A1

  公开（公告）日：2017-11-23

  Provided are compositions comprising isotactic polyethers. Methods of making isotactic polyethers, and uses thereof are also disclosed. Also provided are bimetallic complexes that can be used as catalyst. Methods of making isotactic polyethers and bimetallic complexes and uses thereof are also disclosed. For example, a racemic bimetallic (salalen)CrCl polymerization catalyst was prepared and used alkyl diol, PO-oligomer triols, and aPPO and PCL diols as CSAs in order to produce α,ω-hydroxy telechelic iPPO. These telechelic polymers have controlled molecular weights and are semicrystalline. Amorphous α,ω-hydroxy telechelic PPO can also be produced by increasing the reaction temperature in conjunction with the use of CSAs.

  提供了包含同构聚醚的组合物。还公开了制备同构聚醚的方法以及它们的用途。还提供了可用作催化剂的双金属配合物。还公开了制备同构聚醚和双金属配合物以及它们的用途的方法。例如，制备了一个消旋双金属（salalen）CrCl聚合催化剂，并使用烷基二醇、PO寡聚三醇以及aPPO和PCL二醇作为CSA，以生产α,ω-羟基末端的iPPO。这些末端羟基聚合物具有可控的分子量，并且是半结晶的。通过增加反应温度并结合使用CSA，还可以生产无定形的α,ω-羟基末端PPO。
• Readily shapeable xerogels having controllably delayed swelling properties
  申请人：Huh Moo Kang

  公开号：US20070031499A1

  公开（公告）日：2007-02-08

  Hydrogels are described which have delayed swelling properties. A hydrogel is formed by reacting a hydrophilic monomer, a first crosslinker, and a second crosslinker. The first crosslinker defines the volume expansion of the hydrogel in an aqueous environment, and the second crosslinker, which is biodegradable, can modulate the swelling rate of the hydrogel in aqueous solution. In its dry state, the hydrogel (xerogel) is flexible and elastic. It can also be cut with a knife or scissors, or molded or shaped by hand. The ready shapeability of the xerogel by trimming or compression affords a superior hydrogel for medical applications.

  描述了具有延迟膨胀特性的水凝胶。水凝胶是通过反应亲水性单体、第一交联剂和第二交联剂形成的。第一交联剂定义了水凝胶在水环境中的体积膨胀，而第二交联剂，它是可生物降解的，可以调节水溶液中水凝胶的膨胀速率。在干燥状态下，水凝胶（干凝胶）是柔软和有弹性的。它也可以用刀或剪刀切割，或者通过手工塑造或成形。通过修剪或压缩的便捷成形性为医疗应用提供了优越的水凝胶。
• Mesogen containing compounds
  申请人：TRANSITIONS OPTICAL, INC.

  公开号：EP2698412A2

  公开（公告）日：2014-02-19

  Compounds including at least one mesogenic substructure and at least one long flexible segment and methods of synthesizing the same,are disclosed. Formulations which include various embodiments of the mesogen containing compounds and their use in articles of manufacture and ophthalmic devices are also disclosed.

  本发明公开了包含至少一种介源亚基结构和至少一种长柔性段的化合物以及合成方法。此外，还公开了包括含介原化合物的各种实施方案的制剂及其在制造品和眼科设备中的用途。
• POLYVINYL ACETAL FILM WITH OUTSTANDING TRANSPARENCY AND RESISTANCE TO HEAT-CRACKING PHENOMENON
  申请人：Kuraray Co., Ltd.

  公开号：EP3029090A1

  公开（公告）日：2016-06-08

  An object is to provide a polyvinyl acetal film which has excellent transparency and can suppress a thermal cracking phenomenon. The above object is achieved by providing a polyvinyl acetal film in which a ratio between a composite modulus (GPa) of the highest part in a convex part and a composite modulus (GPa) of the lowest part in a concave part on a surface of a film on a side in contact with glass, calculated by a nanoindentation measurement using a scanning probe microscope, is 0.90 or less, when a laminated glass is formed. In addition, the above object is achieved by providing a polyvinyl acetal film in which a ratio between a hardness (GPa) of the highest part in the convex part and a hardness (GPa) of the lowest part in the concave part, calculated by the SPM nanoindentation measurement, is 0.90 or less.

  目的是提供一种聚乙烯醇缩醛薄膜，它具有优异的透明度，并能抑制热裂纹现象。 实现上述目的的方法是提供一种聚乙烯醇缩醛薄膜，当形成层压玻璃时，通过使用扫描探针显微镜进行纳米压痕测量，计算出薄膜与玻璃接触一侧表面上凸部最高部分的复合模量（GPa）与凹部最低部分的复合模量（GPa）之比为 0.90 或以下。此外，通过提供一种聚乙烯醇缩醛薄膜，其中通过 SPM 纳米压痕测量法计算出的凸面部分最高部分的硬度（GPa）与凹面部分最低部分的硬度（GPa）之比为 0.90 或更小，从而达到上述目的。
• LAMINATED GLASS INTERLAYER AND LAMINATED GLASS
  申请人：Kuraray Co., Ltd.

  公开号：EP3459916A1

  公开（公告）日：2019-03-27

  A first object of the invention is to provide an interlayer film for laminated glass, which can brighten the entire room by suppressing reduction of the amount of solar light penetrating through a laminated glass and efficiently diffusing the penetrated light, and a laminated glass using the interlayer film. A second object of the invention is to provide a production method for recycling a trim or an out-of-specification product of an interlayer film for laminated glass, the interlayer film using a polyvinyl acetal resin layer and a thermoplastic elastomer layer, and thereby obtaining an interlayer film for laminated glass having secured light transmission properties and light scattering properties. The invention relates to an interlayer film for laminated glass having layer A containing a polyvinyl acetal resin, in which a thermoplastic elastomer is dispersed in layer A, and in the case of producing a laminated glass using the interlayer film, the laminated glass has a haze of 10% or higher and a total light transmittance of 80% or higher.

  本发明的第一个目的是提供一种夹层玻璃用中间膜，该中间膜可以通过抑制减少穿透夹层玻璃的太阳光量和有效漫射穿透的光线来照亮整个房间，并提供一种使用该中间膜的夹层玻璃。本发明的第二个目的是提供一种生产方法，用于回收夹层玻璃中间膜的边角料或不合规格产品，中间膜使用聚乙烯醇缩醛树脂层和热塑性弹性体层，从而获得具有可靠透光性能和光散射性能的夹层玻璃中间膜。 本发明涉及一种夹层玻璃用中间膜，其 A 层含有聚乙烯醇缩醛树脂，在 A 层中分散有热塑性弹性体，在使用该中间膜生产夹层玻璃的情况下，夹层玻璃的雾度为 10% 或更高，总透光率为 80% 或更高。