丁基6-羟基己酸酯 | 15545-98-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 丁基6-羟基己酸酯
• 英文名称: 6-hydroxy-hexanoic acid butyl ester
• 英文别名: 6-Hydroxy-hexansaeure-butylester；butyl 6-hydroxycaproate；Butyl 6-hydroxyhexanoate
• CAS: 15545-98-9
• 化学式: C₁₀H₂₀O₃
• 分子量: 188.267
• InChiKey: CEQMDSFVFKDZCR-UHFFFAOYSA-N

物化性质

• 沸点：
  258.2±23.0 °C(Predicted)
• 密度：
  0.967±0.06 g/cm3(Predicted)
• 溶解度：
  可溶于氯仿（少许）、甲醇（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  环己烷 、 正丁醇 在 air 作用下， 生成 丁基6-羟基己酸酯 、 己二酸二丁酯
  参考文献：
  名称：

  DE965903

  摘要：

  公开号：

文献信息

• METHOD FOR PRODUCING 1,6-HEXANEDIOL AND CAPROLACTONE
  申请人：Pinkos Rolf

  公开号：US20120010419A1

  公开（公告）日：2012-01-12

  The invention relates to a process for preparing 1,6-hexanediol and caprolactone, preferably with at least 99.5% purity, which are especially virtually free of 1,4-cyclohexanediols, from a carboxylic acid mixture which is obtained as a by-product of the catalytic oxidation of cyclohexane to cyclohexanone/cyclohexanol with oxygen or oxygen-comprising gases and by water extraction of the reaction mixture, by hydrogenating the carboxylic acid mixture, esterifying and hydrogenating a substream to hexanediol and cyclizing 6-hydroxycaproic ester, the 1,4-cyclohexanediols being removed either in the course of fractionation of the esterification mixture or last from the caprolactone.

  该发明涉及一种制备1,6-己二醇和己内酯的过程，优选至少具有99.5%纯度，这些产品特别几乎不含1,4-环己二醇，从羧酸混合物中获得，该混合物是环己烷催化氧化制备环己酮/环己醇的副产物，通过水提取反应混合物，通过加氢羧酸混合物，酯化和加氢亚流向己二醇和环化6-羟基己酸酯，1,4-环己二醇可以在酯化混合物的分馏过程中或最后从己内酯中除去。
• [EN] ORGANIC COMPOUNDS<br/>[FR] COMPOSES ORGANIQUES
  申请人：SPEEDEL EXPERIMENTA AG

  公开号：WO2005061457A1

  公开（公告）日：2005-07-07

  Novel substituted piperidines of the general formulae (I) and (II) with the substituent definitions as explained in detail in the description are described. The compounds are suitable in particular as renin inhibitors and are highly potent.

  描述了一种具有一般式(I)和(II)的新型替代哌啶化合物，其中详细说明了取代基定义。这些化合物特别适用作为肾素抑制剂，并且具有很高的效力。
• Rheology control agents
  申请人：Lenges Peter Christian

  公开号：US20060155146A1

  公开（公告）日：2006-07-13

  The present invention provides for a rheology control agent that includes a following compound represented by the following formula: wherein A, B, C and D equal CH 2 , CHR, NH, or O, and A, B, C and D may be the same or different and at least one of A and B equals NH and at least one of C and D equals NH; and wherein R 1 , R 2 , and R 3 may be the same or different and represent a linear, branched, hyper-branched, or dendritic ether, polyether or hydrocarbon based chain, optionally forming at least one carbon-based ring, being saturated or unsaturated and R 2 represents linear or branched alkylenes, ethers, polyethers, or polyester linkages and at least one of R 1 , R 2 , and R 3 comprises an ester group or an amide group which is branched off from the main chain; excluded from Formula (1) is a compound wherein R 2 is CH 2 —CH 2 —CH 2 —CH 2 —CH(C(O)OCH 3 ), A, B, C, and D are equal to NH and R 1 and R 3 are both equal to a linear octyl hydrocarbon chain; the rheology control agent is suitable for solvent-borne and water-borne coating composition having improved rheology control useful for OEM refinishing or repainting the exterior of automobile and truck bodies and parts thereof.

  本发明提供了一种流变控制剂，包括下式所示的化合物：其中A、B、C和D等于CH2、CHR、NH或O，A、B、C和D可以相同也可以不同，且至少有一个A和B等于NH，至少有一个C和D等于NH；R1、R2和R3可以相同也可以不同，表示线性、支链、超支链或树枝状醚、聚醚或碳氢基链，可选地形成至少一个碳基环，饱和或不饱和，其中R2表示线性或支链烷基、醚、聚醚或聚酯键合，且R1、R2和R3中至少有一个包括从主链上分支出的酯基或酰胺基；式（1）中不包括R2为CH2—CH2—CH2—CH2—CH(C(O)OCH3)、A、B、C和D均等于NH，且R1和R3均等于线性辛基碳氢链的化合物；该流变控制剂适用于改善流变控制的溶剂型和水性涂料组合物，可用于汽车和卡车车身及其零部件的OEM翻新或重新涂装。
• Synergistic UV absorber combination
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1308084A1

  公开（公告）日：2003-05-07

  A stabilizer composition comprising (A) a compound of the formula I wherein R is (CH2-CH2-O-)n-R2; -CH2-CH(OH)-CH2-O-R2; or -CH(R3)-CO-O-R4; n is 0 or 1; R2 is C1-C13alkyl or C2-C20alkenyl or C6-C12aryl or CO-C1-C18alkyl; R3 is H or C1-C8alkyl; R4 is C1-C12alkyl or C2-C12alkenyl or C5-C6cycloalkyl; and (B) one or more compounds selected from (i) to (xlv) as defined in claim 1 is especially effective towards stabilizing organic materials against degradation induced by light, heat or oxidation.

  一种稳定剂组合物，包括（A）式I的化合物，其中R为（CH2-CH2-O-）n-R2；-CH2-CH（OH）-CH2-O-R2；或-CH（R3）-CO-O-R4；n为0或1；R2为C1-C13烷基或C2-C20烯基或C6-C12芳基或CO-C1-C18烷基；R3为H或C1-C8烷基；R4为C1-C12烷基或C2-C12烯基或C5-C6环烷基；以及（B）根据权利要求1所定义的（i）至（xlv）中的一种或多种化合物，对于稳定有机材料抵抗光、热或氧化引起的降解特别有效。
• THE USE OF 2-(2-HYDROXYPHENYL)BENZOTRIAZOLE COMPOUNDS AS AN UV ABSORBING AGENT IN COATINGS
  申请人：BASF SE

  公开号：US20160215151A1

  公开（公告）日：2016-07-28

  The present invention relates the use of a 2-(2-hydroxyphenyl)benzotriazole compound of the formula R(QUV) n as an UV absorbing agent in coatings.

  本发明涉及在涂层中使用式R（QUV）的2-（2-羟基苯基）苯并三唑化合物作为紫外线吸收剂。