丁基环己-3-烯-1-羧酸酯 | 37981-14-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 丁基环己-3-烯-1-羧酸酯
• 英文名称: n-butyl 4-cyclohexenecarboxylate
• 英文别名: 3-cyclohexenecarboxylic acid butyl ester；butyl cyclohex-3-ene-1-carboxylate；Cyclohex-3-en-carbonsaeure-butylester
• CAS: 37981-14-9
• 化学式: C₁₁H₁₈O₂
• 分子量: 182.263
• InChiKey: QEMXXENZTVUGPT-UHFFFAOYSA-N

物化性质

• LogP：
  3.480 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916209090

反应信息

• 作为反应物：
  描述：

  丁基环己-3-烯-1-羧酸酯 在 wild-type cyclohexenecarboxylate ester hydrolase 作用下， 以 aq. buffer 为溶剂， 以19%的产率得到
  参考文献：
  名称：

  CYCLOHEXENECARBOXYLATE ESTER HYDROLASE, AND MUTANT, CODING GENE, EXPRESSION VECTOR, RECOMBINANT BACTERIUM AND USE THEREOF

  摘要：

  The present invention discloses a cyclohexenecarboxylate ester hydrolase, and a mutant, a coding gene, an expression vector, recombinant bacterium and use thereof. The cyclohexenecarboxylate ester hydrolase AcEst1 and its mutant of the present invention have the function of enantioselectively resolving methyl 3-cyclohexene-1-carboxylate with high efficiency to prepare optically active (S)-3-cyclohexene-1-carboxylic acid. When the substrate concentration is as high as 2000 mM (about 280 g/L), the optical purity of the product is higher than 99%, and the substrate/catalyst is as high as 3500 g/g. As compared with other preparation methods, the product prepared by the method of the present invention has high concentration and high optical purity, the catalytic efficiency is high, the reaction conditions are mild. Furthermore, the method is environmentally friendly, simple in operation and easy for industrial scale-up, thus has a good prospect of application in industry.

  公开号：

  US20220396781A1
• 作为产物：
  描述：

  3-环己烯甲醛 、 正丁醇 在 potassium iodide 作用下， 以 环己烷 为溶剂， 以75%的产率得到丁基环己-3-烯-1-羧酸酯
  参考文献：
  名称：

  Electroorganic chemistry. 94. Electrooxidative transformation of aldehydes to esters using mediators

  摘要：

  DOI：

  10.1021/jo00224a065

文献信息

• Seal swell agents for lubrication compositions
  申请人：The Lubrizol Corporation

  公开号：US10669504B2

  公开（公告）日：2020-06-02

  The invention relates to a seal swell agent which is a substituted sulfonyldibenzene compound, and lubricating compositions containing the seal swell agent. The substituents on the benzene rings may be hydrocarbyl groups of 4 to 20 carbon atoms or alkylene groups of 1-2 carbon atoms with further functional groups.

  本发明涉及一种密封膨胀剂，该膨胀剂是一种取代的磺酰基二苯化合物，并且包含密封膨胀剂的润滑组合物。苯环上的取代基可以是4至20个碳原子的烃基或1-2个碳原子的烷基，还可以带有进一步的功能基团。
• Additive compositions for lubricants and functional fluids
  申请人：The Lubrizol Corporation

  公开号：EP0764715A1

  公开（公告）日：1997-03-26

  This invention relates to a composition, comprising: (A) a compound represented by the formula wherein in Formula (A-1), G1 and G2 are independently R, OR, SR or NRR wherein each R is independently a hydrocarbyl group, X1 and X2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a phosphorus compound. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.

  本发明涉及一种组合物，包括： (A) 由式（A-1）表示的化合物 其中在式 (A-1) 中，G1 和 G2 独立地为 R、OR、SR 或 NRR，其中每个 R 独立地为烃基，X1 和 X2 独立地为 O 或 S，且 n 为 0 至 3；以及 (B) 具有至少 10 个脂肪族碳原子取代基的酰化含氮化合物。在一个实施方案中，本发明组合物还包括 (C) 磷化合物。在一个实施方案中，本发明组合物进一步包含 (D) 有机硫酸、羧酸或苯酚的碱金属或碱土金属盐。在一个实施方案中，本发明组合物还包括 (E) 硫代氨基甲酸酯。这些组合物有助于提供具有更强抗磨损特性的润滑组合物和功能性液体。
• An oil composition for improving fuel economy in internal combustion engines
  申请人：The Lubrizol Corporation

  公开号：EP0864634A1

  公开（公告）日：1998-09-16

  This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula wherein in Formula (A-I), R1, R2, R3 and R4 are independently hydrocarbyl groups, X1 and X2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and fractional fluids with enhanced fuel efficiency properties.

  本发明涉及用于提高内燃机燃油效率的组合物。该组合物包括具有润滑粘度的润滑油和 (A) 由式表示的化合物 其中，在式 (A-I)中，R1、R2、R3 和 R4 独立地为烃基，X1 和 X2 独立地为 O 或 S，且 n 为 0 至 3；以及 (B) 具有至少 10 个脂肪族碳原子取代基的酰化含氮化合物。在一个实施方案中，本发明组合物进一步包含(C)除(A)之外的第二种磷化合物，所述第二种磷化合物为磷酸、磷酸酯、磷酸盐或其衍生物。在一个实施方案中，本发明组合物还包括 (D) 有机硫酸、羧酸或苯酚的碱金属或碱土金属盐。在一个实施方案中，本发明组合物还包括 (E) 硫代氨基甲酸酯。这些组合物有助于提供具有更高燃油效率特性的润滑组合物和馏分油。
• Lubricating composition containing ashfree antiwear agent based on hydroxypolycarboxylic acid derivative and a molybdenum compound
  申请人：The Lubrizol Corporation

  公开号：EP2463358A1

  公开（公告）日：2012-06-13

  The invention provides a lubricating composition containing an oil of lubricating viscosity, an oil soluble molybdenum compound, and an ashless antiwear agent. The invention further provides for a new antioxidant. The lubricating composition is suitable for lubricating an internal combustion engine.

  本发明提供了一种润滑组合物，其中含有一种具有润滑粘度的油、一种油溶性钼化合物和一种无灰抗磨剂。本发明还提供了一种新型抗氧化剂。该润滑组合物适用于润滑内燃机。
• Mixed phosphorus esters for lubricant applications
  申请人：The Lubrizol Corporation

  公开号：US10793802B2

  公开（公告）日：2020-10-06

  A lubricant composition of an oil of lubricating viscosity and a phosphite ester reaction product of a monomeric phosphorous acid or an ester thereof with a first alkylene diol having two hydroxy groups in a 1,4 or 1,5 or 1,6 relationship and a second, alkyl-substituted, diol being a substituted 1,3-propylene diol, exhibits good wear and frictional performance.

  一种由具有润滑粘度的油和亚磷酸酯组成的润滑剂组合物，亚磷酸酯是一种单体磷酸或其酯类与第一烷基二元醇的反应产物，第一烷基二元醇具有两个羟基，呈 1,4 或 1,5 或 1,6 关系，第二烷基取代的二元醇是取代的 1,3 丙二醇，具有良好的磨损和摩擦性能。