丁烷-1,4-二基二氨基甲酸酯 | 7119-55-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 丁烷-1,4-二基二氨基甲酸酯
• 英文名称: 1,4-Bis-carbamoyloxy-butan
• 英文别名: 1,4-Butanediol, dicarbamate；4-carbamoyloxybutyl carbamate
• CAS: 7119-55-3
• 化学式: C₆H₁₂N₂O₄
• 分子量: 176.172
• InChiKey: ONWSHWFYPNZPAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  105
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2924199090

反应信息

• 作为产物：
  描述：

  Butandiol-(1,4)-bis- 在 水 、 sodium methylate 作用下， 生成 丁烷-1,4-二基二氨基甲酸酯
  参考文献：
  名称：

  Graf,R., Chemische Berichte, 1963, vol. 96, p. 56 - 67

  摘要：

  DOI：

文献信息

• Zinc monoglycerolate as a catalyst for the conversion of 1,3- and higher diols to diurethanes
  作者：Sanjitha Kulasegaram、Uzma Shaheen、Terence W. Turney、Will P. Gates、Antonio F. Patti

  DOI：10.1039/c5ra05032d

  日期：——

  An efficient approach to the synthesis of diurethanes from 1,3- and higher diols (n ≥ 3) is described.

  一种从1,3-和更高的二醇（n ≥ 3）合成二尿酰胺的高效方法被描述。
• Method of Preparing Cyclic Carbonates, Cyclic Carbamates, Cyclic Ureas, Cyclic Thiocarbonates, Cyclic Thiocarbamates, and Cyclic Dithiocarbonates
  申请人：Hedrick James L.

  公开号：US20100280242A1

  公开（公告）日：2010-11-04

  A method of preparing a cyclic monomer, comprising: forming a first mixture comprising a precursor compound, bis(pentafluorophenyl) carbonate, and a catalyst; wherein the precursor compound has a structure comprising a) two or more carbons, and b) two functional groups selected from the group consisting of primary amine, secondary amine, thiol group, hydroxyl group, and combinations thereof; and agitating the first mixture at a temperature effective to form a second mixture comprising the cyclic monomer, the cyclic monomer selected from the group consisting of a cyclic carbonate, a cyclic carbamate, a cyclic urea, a cyclic thiocarbonate, a cyclic thiocarbamate, and a cyclic dithiocarbonate.

  制备环状单体的方法，包括：形成包括前体化合物、双(五氟苯基)碳酸酯和催化剂的第一混合物；其中前体化合物具有结构，包括a) 两个或更多碳，和b) 从一次胺、二次胺、硫醇基团、羟基团和它们的组合中选择的两个功能基团；并在有效温度下搅拌第一混合物，形成包括所述环状单体的第二混合物，所述环状单体选自环状碳酸酯、环状氨基甲酸酯、环状脲、环状硫代碳酸酯、环状硫代氨基甲酸酯和环状二硫代碳酸酯的组合。
• METHOD FOR PRODUCING STRONGLY ACIDIC ZIRCONIUM PARTICLES, METHOD FOR PRODUCING PROTON CONDUCTING MATERIAL AND PROTON CONDUCTING FILM, PROTON CONDUCTING FILM, ELECTRODE FOR FUEL CELL, FILM-ELECTRODE JOINED BODY, FUEL CELL
  申请人：Tokyo Institute of Technology

  公开号：EP2465863A1

  公开（公告）日：2012-06-20

  The disclosed methods enable zirconium sulfophenyl phosphonate, zirconium sulfate, or zirconia sulfate, which has high performance as a proton conducting material and high catalytic activity, to be produced at low temperature by reaction by adding sulfophenyl phosphonic acid or sulfuric acid to zirconium nanoparticles, the zirconium nanoparticles being a precursor of strongly acidic zirconium particles obtained by reacting zirconium alkoxide with zirconium butoxide as a chelating agent and nitric acid as a catalyst in isopropyl alcohol as a solvent.

  所公开的方法可通过向纳米锆颗粒中添加磺基苯基膦酸或硫酸的反应，在低温下生产出作为质子传导材料具有高性能和高催化活性的磺基苯基膦酸锆、硫酸锆或硫酸氧化锆、纳米锆颗粒是强酸性锆颗粒的前体，它是由烷氧化锆与丁氧化锆作为螯合剂和硝酸作为催化剂在异丙醇作为溶剂中反应得到的。
• Electrolyte film and solid polymer fuel cell using the same
  申请人：Yamaguchi Takeo

  公开号：US20050118479A1

  公开（公告）日：2005-06-02

  An electrolyte membrane having a porous base material having pores filled with a first polymer capable of conducting a proton, wherein the porous base material comprises at least one second polymer selected from the group consisting of polyimides and polyamides; and a fuel cell, particularly a solid polymer fuel cell, more specifically a direct methanol polymer fuel cell, using the electrolyte membrane. The electrolyte membrane is excellent in the inhibition of permeation of methanol, exhibits no or reduced change in its area, and is excellent in proton conductivity.

  一种电解质膜，它具有多孔基底材料，基底材料的孔隙中填充有能够传导质子的第一种聚合物，其中多孔基底材料包括至少一种选自聚酰亚胺和聚酰胺组成的组的第二种聚合物；以及一种使用该电解质膜的燃料电池，特别是固体聚合物燃料电池，更具体地说是直接甲醇聚合物燃料电池。电解质膜在抑制甲醇渗透方面表现优异，其面积无变化或变化较小，质子传导性优异。
• Reppe et al., Justus Liebigs Annalen der Chemie, 1955, vol. 596, p. 65
  作者：Reppe et al.

  DOI：——

  日期：——