ethyl 2,2-dibromo-2-(phenylsulfonyl)acetate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: ethyl 2,2-dibromo-2-(phenylsulfonyl)acetate
• 英文别名: Ethyl 2-(benzenesulfonyl)-2,2-dibromoacetate
• 化学式: C₁₀H₁₀Br₂O₄S
• 分子量: 386.061
• InChiKey: ADBPLKIUPSACOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  68.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ethyl 2,2-dibromo-2-(phenylsulfonyl)acetate 在 N,N-二异丙基乙胺 作用下， 以 乙腈 为溶剂， 反应 2.0h， 以92%的产率得到ethyl 2-bromo-2-(phenylsulfonyl)acetate
  参考文献：
  名称：

  卤代烷通过可见光介导的脱卤作用。

  摘要：

  可以通过简单的全卤化/脱卤序列以通常高收率进行活化的CH键的净选择性溴化和氯化。光化学还原不需要光催化剂，而是依赖于底物和还原剂的电子给体-受体复合物的形成，或者自动光催化。尽管有任何明显的光子吸收，但仍会发生一些反应，这是涉及胺类的其他光化学反应的警惕故事。机械实验为这种观察提供了解释。

  DOI：

  10.1021/acs.orglett.9b03848
• 作为产物：
  描述：

  苯砜乙酸乙酯 在 三乙胺 、 溴 作用下， 以 二氯甲烷 为溶剂， 反应 17.33h， 以93%的产率得到ethyl 2,2-dibromo-2-(phenylsulfonyl)acetate
  参考文献：
  名称：

  卤代烷通过可见光介导的脱卤作用。

  摘要：

  可以通过简单的全卤化/脱卤序列以通常高收率进行活化的CH键的净选择性溴化和氯化。光化学还原不需要光催化剂，而是依赖于底物和还原剂的电子给体-受体复合物的形成，或者自动光催化。尽管有任何明显的光子吸收，但仍会发生一些反应，这是涉及胺类的其他光化学反应的警惕故事。机械实验为这种观察提供了解释。

  DOI：

  10.1021/acs.orglett.9b03848

文献信息

• PLANOGRAPHIC PRINTING PLATE MATERIAL, AND CYCLIC UREIDE MOIETY-CONTAINING PHENOLIC RESIN AND ITS SYNTHETIC PROCESS
  申请人：MIYOSHI Masaki

  公开号：US20090075201A1

  公开（公告）日：2009-03-19

  Disclosed is a planographic printing plate material comprising an aluminum support and provided thereon, an image formation layer containing a cyclic ureide moiety-containing phenolic resin in which a phenolic resin has a cyclic ureide moiety through a linkage group, the cyclic ureide moiety being derived from a cyclic ureide and the linkage group being derived from a linkage compound having both a monohalogenated alkyl group and one selected from a vinyl group, a carbonyl group, an ester group and a sulfonic acid ester group.
• ETHYLENICALLY UNSATURATED COMPOUND, LIGHT SENSITIVE COMPOSITION, LIGHT SENSITIVE PLANOGRAPHIC PRINTING PLATE MATERIAL AND PRINTING PROCESS EMPLOYING THE SAME
  申请人：Kuroki Takaaki

  公开号：US20090263744A1

  公开（公告）日：2009-10-22

  The present invention provides a novel ethylenically unsaturated compound which is highly sensitive to scanning exposure due to an ultraviolet to near-infrared laser and is cured to give good physical properties; a light sensitive composition providing good developability and high sensitivity and forming a high strength layer; a planographic printing plate material having advantages that good developability, high sensitivity and high strength layer are obtained, particularly a planographic printing plate material requiring no developing machine which are mounted on a printing press without any development, followed by printing and which provides excellent developability on a printing press and printing durability; and a printing process. The ethylenically unsaturated compound has in the molecule a photo-oxidation group and a polymerizable ethylenically unsaturated bond, and has a predetermined solubility in water or an aqueous alkali solution. The planographic printing plate material is characterized in that it comprises a support and provided thereon, a light sensitive layer containing the ethylenically unsaturated compound, a polyhalogen compound as a photopolymerization initiator, a water-soluble polymer binder as a polymer binder and an infrared absorbing agent.
• Alkyl Halides via Visible Light Mediated Dehalogenation
  作者：Manjula D. Rathnayake、Jimmie D. Weaver

  DOI：10.1021/acs.orglett.9b03848

  日期：2019.12.6

  Net selective bromination and chlorination of activated C-H bonds can be effected in generally high yield via a simple perhalogenation/dehalogenation sequence. The photochemical reductions require no photocatalyst, relying instead on the formation of an electron donor-acceptor complex of the substrate and reductant, or alternatively autophotocatalysis. Some reactions proceed despite any apparent photon

  可以通过简单的全卤化/脱卤序列以通常高收率进行活化的CH键的净选择性溴化和氯化。光化学还原不需要光催化剂，而是依赖于底物和还原剂的电子给体-受体复合物的形成，或者自动光催化。尽管有任何明显的光子吸收，但仍会发生一些反应，这是涉及胺类的其他光化学反应的警惕故事。机械实验为这种观察提供了解释。