1,4-bis(2,3,4,5-tetrachloro-2,4-cyclopentadien-1-ylidene)-2-butene

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,4-bis(2,3,4,5-tetrachloro-2,4-cyclopentadien-1-ylidene)-2-butene
• 英文别名: 1,2,3,4-tetrachloro-5-[(E)-4-(2,3,4,5-tetrachlorocyclopenta-2,4-dien-1-ylidene)but-2-enylidene]cyclopenta-1,3-diene
• 化学式: C₁₄H₄Cl₈
• 分子量: 455.81
• InChiKey: AEFJVYGOFSJBLU-OWOJBTEDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  反-1,1,4,4-四甲氧基-2-丁烯 、 1,2,3,4-四氯-1,3-环戊二烯 在 哌啶 作用下， 以 溶剂黄146 为溶剂， 反应 0.5h， 以62%的产率得到1,4-bis(2,3,4,5-tetrachloro-2,4-cyclopentadien-1-ylidene)-2-butene
  参考文献：
  名称：

  Base-catalyzed condensation of cyclopentadiene derivatives. Synthesis of fulvalene analogues: strong proaromatic electron acceptors

  摘要：

  A series of proaromatic electron acceptors derived from fulvenes were synthesized from tetrachlorocyclopentadiene and previously unknown 1,4-dicyano- and 1,4-dialkoxycarbonyl-2,3-dimethoxy cyclopentadienes. Two reversible one-electron reductions steps observed for fulvalenes coalesce into one two-electron reduction step upon increasing the length of the conjugating bridge. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(03)00877-9

文献信息

• Base-catalyzed condensation of cyclopentadiene derivatives. Synthesis of fulvalene analogues: strong proaromatic electron acceptors
  作者：Emad Aqad、Philippe Leriche、Gilles Mabon、Alain Gorgues、Magali Allain、Amédée Riou、Arkady Ellern、Vladimir Khodorkovsky

  DOI：10.1016/s0040-4020(03)00877-9

  日期：2003.7

  A series of proaromatic electron acceptors derived from fulvenes were synthesized from tetrachlorocyclopentadiene and previously unknown 1,4-dicyano- and 1,4-dialkoxycarbonyl-2,3-dimethoxy cyclopentadienes. Two reversible one-electron reductions steps observed for fulvalenes coalesce into one two-electron reduction step upon increasing the length of the conjugating bridge. (C) 2003 Elsevier Ltd. All rights reserved.