2-((3-methoxy-4-nitrosophenyl)(methyl)amino)ethanol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-((3-methoxy-4-nitrosophenyl)(methyl)amino)ethanol
• 英文别名: 2-(3-methoxy-N-methyl-4-nitrosoanilino)ethanol
• 化学式: C₁₀H₁₄N₂O₃
• 分子量: 210.233
• InChiKey: AFPNCWYZQZCNQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  62.1
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-((3-methoxy-4-nitrosophenyl)(methyl)amino)ethanol 、 3-羟基-N,N-二乙基苯胺 在 高氯酸 作用下， 以 水 、 异丙醇 为溶剂， 反应 6.0h， 以67.3%的产率得到3-(diethylamino)-7-((2-hydroxyethyl)(methyl)amino)phenoxazin-5-ium perchlorate
  参考文献：
  名称：

  Aggregation induced convertible third-order nonlinear optical absorptions of the phenoxazinium containing films prepared by sol–gel method

  摘要：

  The preparation and optical properties of phenoxazinium dye containing optical films by a sol-gel method are reported. The monomer of the phenoxazinium dye substituted with a hydroxyl group, prepared from 3-methoxyaniline by a five-step sequence, can be directly converted to the sol-gel precursor. The preparation and optical properties of phenoxazinium dye containing optical films are reported by in situ sol-gel spin coating with different mole ratios of the precursor to tetraethylorthosilicate. The U-V visible absorption spectra of the films were recorded and the dye aggregation phenomena were discussed. The third-order nonlinear optical properties of the films were measured by a picosecond Z-Scan method at 532 nm. The results indicate that the third-order nonlinear optical absorptions of the films are turned from the reverse saturation absorption with lower dye doping ratios to saturation absorption with higher doping ratios, which induced by the dye aggregation. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.09.022
• 作为产物：
  描述：

  N-甲基-3-甲氧基苯胺 在 盐酸 、 sodium hydride 、 sodium nitrite 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 51.0h， 生成 2-((3-methoxy-4-nitrosophenyl)(methyl)amino)ethanol
  参考文献：
  名称：

  Aggregation induced convertible third-order nonlinear optical absorptions of the phenoxazinium containing films prepared by sol–gel method

  摘要：

  The preparation and optical properties of phenoxazinium dye containing optical films by a sol-gel method are reported. The monomer of the phenoxazinium dye substituted with a hydroxyl group, prepared from 3-methoxyaniline by a five-step sequence, can be directly converted to the sol-gel precursor. The preparation and optical properties of phenoxazinium dye containing optical films are reported by in situ sol-gel spin coating with different mole ratios of the precursor to tetraethylorthosilicate. The U-V visible absorption spectra of the films were recorded and the dye aggregation phenomena were discussed. The third-order nonlinear optical properties of the films were measured by a picosecond Z-Scan method at 532 nm. The results indicate that the third-order nonlinear optical absorptions of the films are turned from the reverse saturation absorption with lower dye doping ratios to saturation absorption with higher doping ratios, which induced by the dye aggregation. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.09.022

文献信息

• US8008037B2
  申请人：——

  公开号：US8008037B2

  公开（公告）日：2011-08-30
• US9594052B2
  申请人：——

  公开号：US9594052B2

  公开（公告）日：2017-03-14
• Aggregation induced convertible third-order nonlinear optical absorptions of the phenoxazinium containing films prepared by sol–gel method
  作者：Fei Zhang、Jia-Tao Miao、Yu Fang、Ru Sun、Xiao-Zhi Guo、Ying-Lin Song、Jian-Feng Ge

  DOI：10.1016/j.dyepig.2014.09.022

  日期：2015.2

  The preparation and optical properties of phenoxazinium dye containing optical films by a sol-gel method are reported. The monomer of the phenoxazinium dye substituted with a hydroxyl group, prepared from 3-methoxyaniline by a five-step sequence, can be directly converted to the sol-gel precursor. The preparation and optical properties of phenoxazinium dye containing optical films are reported by in situ sol-gel spin coating with different mole ratios of the precursor to tetraethylorthosilicate. The U-V visible absorption spectra of the films were recorded and the dye aggregation phenomena were discussed. The third-order nonlinear optical properties of the films were measured by a picosecond Z-Scan method at 532 nm. The results indicate that the third-order nonlinear optical absorptions of the films are turned from the reverse saturation absorption with lower dye doping ratios to saturation absorption with higher doping ratios, which induced by the dye aggregation. (C) 2014 Elsevier Ltd. All rights reserved.