potassium 4-(2-pyridyl)pyrimidine-2-thiolate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: potassium 4-(2-pyridyl)pyrimidine-2-thiolate
• 英文别名: 4-(pyridin-2-yl)pyrimidine-2-thiolate potassium；potassium 4-(pyridin-2-yl)pyrimidine-2-thiolate；potassium;4-pyridin-2-ylpyrimidine-2-thiolate
• 化学式: C₉H₆N₃S*K
• 分子量: 227.331
• InChiKey: AHAJLWHAQRJELD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.55
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  39.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  7,11,15,28-tetrakis(bromomethyl)-1,21,23,25-tetramethyl-2,20:3,19-dimetheno-1H,21H,23H,25H-bis<1,3>dioxocino<5,4-i:5',4'-i'>benzo<1,2-d:5,4-d'>bis<1,3>benzodioxocin 、 potassium 4-(2-pyridyl)pyrimidine-2-thiolate 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 以90%的产率得到
  参考文献：
  名称：

  A family of polyoxometalate-resorcin[4]arene-based metal–organic materials: Assemblies, structures and lithium ion battery properties

  摘要：

  DOI：

  10.1016/j.jallcom.2021.159009
• 作为产物：
  描述：

  2-乙酰基吡啶 在 氢氧化钾 作用下， 以 乙醇 为溶剂， 反应 5.0h， 生成 potassium 4-(2-pyridyl)pyrimidine-2-thiolate
  参考文献：
  名称：

  A convenient set of bidentate pyridine ligands for combinatorial synthesis

  摘要：

  Synthesis is reported of five pyridine-containing bidentate ligands bearing nucleophilic groups at different positions. Their efficient solid-phase alkylation was demonstrated in the synthesis of a small library. These ligands are attractive building blocks for the construction of libraries of metal-binding compounds for various purposes. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00885-0

文献信息

• A family of polyoxometalate-resorcin[4]arene-based metal–organic materials: Assemblies, structures and lithium ion battery properties
  作者：Ming-Yue Yu、Jin-Hua Liu、Jin Yang、Jian-Fang Ma

  DOI：10.1016/j.jallcom.2021.159009

  日期：2021.7
• A convenient set of bidentate pyridine ligands for combinatorial synthesis
  作者：Fen Wang、Alan W. Schwabacher

  DOI：10.1016/s0040-4039(99)00885-0

  日期：1999.6

  Synthesis is reported of five pyridine-containing bidentate ligands bearing nucleophilic groups at different positions. Their efficient solid-phase alkylation was demonstrated in the synthesis of a small library. These ligands are attractive building blocks for the construction of libraries of metal-binding compounds for various purposes. (C) 1999 Elsevier Science Ltd. All rights reserved.

表征谱图