三十三氟十八烷醇丙烯酸酯 | 65150-93-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 三十三氟十八烷醇丙烯酸酯
• 英文名称: C16F33CH2CH2OCOCH=CH2
• 英文别名: 1,1,2,2-Tetrahydroperfluorooctadecyl acrylate；3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-tritriacontafluorooctadecyl prop-2-enoate
• CAS: 65150-93-8
• 化学式: C₂₁H₇F₃₃O₂
• 分子量: 918.233
• InChiKey: UNWCENHMZWUSOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.2
• 重原子数：
  56
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  35

反应信息

• 作为产物：
  描述：

  三十三氟-1-十八烷醇 、 丙烯酸 生成 三十三氟十八烷醇丙烯酸酯
  参考文献：
  名称：

  MARUYAMA, TOSIKI;JOKOO, XIDEHDZIRO

  摘要：

  DOI：

文献信息

• Transition metal compound, polymerization-initiator system comprising the same, and process for producing polymer
  申请人：Uemura Makoto

  公开号：US20070270521A1

  公开（公告）日：2007-11-22

  A transition metal compound represented by the formula, [(CpR 1 m )(CO) 2 M 1 ][M 2 (CO) 2 (CpR 2 n )], wherein Cp is a cyclopentadienyl ring, R 1 and R 2 are independently of each other a hydrocarbyl group having 1 to 20 carbon atoms, and each of at least one R 1 and at least one R 2 is a hydrocarbyl group having 5 to 20 carbon atoms, m and n are independently of each other an integer of 1 to 5, and M 1 and M 2 are independently of each other a transition metal atom of the group 8 in the periodic table of elements; a polymerization-initiator system comprising said transition metal compound; and a process for producing a polymer in the presence of the polymerization-initiator system.

  一个由该公式表示的过渡金属化合物，[(CpR1m)(CO)2M1][M2(CO)2(CpR2n)]，其中Cp是一个环戊二烯环，R1和R2是独立的烃基团，含有1至20个碳原子，至少一个R1和至少一个R2是含有5至20个碳原子的烃基团，m和n是独立的1至5的整数，M1和M2是元素周期表中8族的过渡金属原子；包括所述过渡金属化合物的聚合物化引发剂系统；以及在聚合物化引发剂系统存在的情况下生产聚合物的过程。
• ELASTOMER COMPOSITION AND THERMOPLASTIC RESIN COMPOSITION CONTAINING THE SAME
  申请人：KANEKA CORPORATION

  公开号：EP1179566A1

  公开（公告）日：2002-02-13

  There is provided an elastomer composition for an impact modifier and a thermoplastic resin composition having improved impact resistance using the same. An elastomer composition comprises a block copolymer (a) containing a methacrylate polymer and a siloxane polymer, and a graft copolymer (b) containing a polymer component having a glass transition temperature of lower than 25°C. And the composition is mixed with a thermoplastic resin (c).

  本发明提供了一种用于抗冲改性剂的弹性体组合物，以及使用该组合物可提高抗冲击性的热塑性树脂组合物。弹性体组合物包括含有甲基丙烯酸酯聚合物和硅氧烷聚合物的嵌段共聚物（a），以及含有玻璃化转变温度低于 25°C 的聚合物成分的接枝共聚物（b）。该组合物与热塑性树脂 (c) 混合。
• THERMOPLASTIC RESIN COMPOSITION
  申请人：Kaneka Corporation

  公开号：EP1398353A1

  公开（公告）日：2004-03-17

  A thermoplastic resin composition comprising a thermoplastic resin (a) and a block copolymer (b) containing a methacrylic polymer block (A) and an acrylic polymer block (B).

  一种热塑性树脂组合物，由热塑性树脂（a）和嵌段共聚物（b）组成，嵌段共聚物含有甲基丙烯酸聚合物嵌段（A）和丙烯酸聚合物嵌段（B）。
• BLOCK COPOLYMER
  申请人：KANEKA CORPORATION

  公开号：EP1475397A1

  公开（公告）日：2004-11-10

  The present invention relates to a block copolymer (A) including a (meth)acrylic polymer block (a) and an acrylic polymer block (b). The (meth)acrylic polymer block (a) is preferably copolymerized with a monomer having a functional group having high cohesive force, such as a carboxyl group, so that the 5%-weight-loss temperature is 300°C or more or the tensile strength is 3 MPa or more, and the hardness measured by a type A durometer according to JIS K6253 is 50 or less, and a compression set measured after 22 hours at 70°C is 45% or less. The block copolymer (A) exhibits excellent thermal decomposition resistance and low compression set at high temperatures. The block copolymer (A) can be used as a soft material for automobile, and has low hardness, high adhesion, high oil resistance, high weather resistance, high heat resistance, high recycling property, high tensile properties; and high wax remover resistance.

  本发明涉及一种嵌段共聚物（A），包括（甲基）丙烯酸聚合物嵌段（a）和丙烯酸聚合物嵌段（b）。(甲基)丙烯酸聚合物嵌段(a)最好与具有高内聚力官能团（如羧基）的单体共聚，从而使 5%失重温度为 300°C 或以上，或拉伸强度为 3 MPa 或以上，且根据 JIS K6253 用 A 型硬度计测量的硬度为 50 或以下，在 70°C 下 22 小时后测量的压缩永久变形为 45% 或以下。嵌段共聚物（A）具有优异的抗热分解性能，高温下的压缩永久变形小。嵌段共聚物（A）可用作汽车软质材料，具有低硬度、高附着力、高耐油性、高耐候性、高耐热性、高回收性、高拉伸性和高抗脱蜡性。
• ACRYLIC BLOCK COPOLYMER AND THERMOPLASTIC RESIN COMPOSITION
  申请人：KANEKA CORPORATION

  公开号：EP1541595A1

  公开（公告）日：2005-06-15

  The present invention provides a novel acrylic block copolymer rich in flexibility and excellent in mechanical strength, moldability, oil resistance, heat resistance, thermal decomposition resistance, weather resistance, and compression set, and further rich in reactivity. The present invention also provides compositions, seal products, and automobile, electric, and electronic parts, all of which include the acrylic block copolymer. The acrylic block copolymer includes a methacrylic polymer block (a) and an acrylic polymer block (b), at least one of the polymer blocks containing, in its main chain, at least one acid anhydride group (c) represented by formula (1): (wherein R1s each represent hydrogen or a methyl group and may be the same or different, n represents an integer of 0 to 3, and m represents an integer of 0 or 1).

  本发明提供了一种新型丙烯酸嵌段共聚物，它具有丰富的柔韧性和优异的机械强度、成型性、耐油性、耐热性、耐热分解性、耐候性和压缩永久变形性，而且还具有丰富的反应活性。本发明还提供了包括丙烯酸嵌段共聚物的组合物、密封产品以及汽车、电气和电子零件。丙烯酸嵌段共聚物包括甲基丙烯酸聚合物嵌段（a）和丙烯酸聚合物嵌段（b），其中至少一个聚合物嵌段的主链中含有至少一个酸酐基团（c），由式（1）表示： (其中 R1s 分别代表氢或甲基，可以相同或不同，n 代表 0 至 3 的整数，m 代表 0 或 1 的整数）。