tris[4-(furanyl)phenyl]amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris[4-(furanyl)phenyl]amine
• 英文别名: tris[4-(2-furyl)phenyl]amine；4-(furan-2-yl)-N,N-bis[4-(furan-2-yl)phenyl]aniline
• 化学式: C₃₀H₂₁NO₃
• 分子量: 443.502
• InChiKey: AWPFMNVPTUQBMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  34
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  42.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-bromo-N-hexyl-phthalimide 、 tris[4-(furanyl)phenyl]amine 在 potassium carbonate 、 三甲基乙酸 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以58%的产率得到5,5',5''-(5,5',5''-(nitrilotris(benzene-4,1-diyl))tris(furan-5,2-diyl))tris(2-octylisoindoline-1,3-dione)
  参考文献：
  名称：

  Development of simple hole-transporting materials for perovskite solar cells

  摘要：

  基于三苯胺核心和高性能给体分子7,7′-[4,4-双(2-乙基己基)-4H-硅杂[3,2-b:4,5-b′]噻吩-2,6-二基]双[6-氟-4-(5′-己基-[2,2′-联噻吩]-5-基)苯并[c][1,2,5]噻二唑] (DTS(FBTTh₂)₂) 为基础的三种低成本螺旋桨状小分子被研究作为钙钛矿太阳能电池中的传孔材料。每种传孔材料均设计有高度模块化的侧臂，可实现不同的带隙和薄膜性能，同时保持最高占据分子轨道的一致结合能，以促进从钙钛矿活性层中提取空穴。使用每种基于三苯胺的传孔材料和DTS(FBTTh₂)₂制备了钙钛矿太阳能电池器件，并与具有2,2′,7,7′-四(对-甲氧基苯胺基)-9,9′-螺联苯芴 (spiro-OMeTAD) 传孔层的器件进行了比较。我们的每种三苯胺传孔材料和DTS(FBTTh₂)₂显示出明显比spiro-OMeTAD更粗糙的表面形态，这可能导致器件性能较低。研究发现，在DTS(FBTTh₂)₂中使用惰性、绝缘聚合物作为添加剂可减少表面粗糙度，从而产生具有更高光电流的器件。

  DOI：

  10.1139/cjc-2015-0427
• 作为产物：
  描述：

  呋喃 、 三(4-碘苯)胺 在 正丁基锂 、 zinc(II) chloride 、 SPhos 、 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 2.0h， 以28.9%的产率得到tris[4-(furanyl)phenyl]amine
  参考文献：
  名称：

  光和氧化还原活性苯并呋喃附加三苯胺及其自由基阳离子的近红外吸收

  摘要：

  设计并成功制备了带有三个苯并呋喃环的三芳基胺，产率为 64%。它在 385 nm 处表现出吸收，在 440 nm 附近显示出蓝色发射，荧光量子...

  DOI：

  10.1246/cl.200161

文献信息

• ORGANIC ELECTROLUMINESCENT DEVICE AND DISPLAY APPARATUS
  申请人：Matsunami Shigeyuki

  公开号：US20080164809A1

  公开（公告）日：2008-07-10

  An organic electroluminescent device for emitting red light is disclosed. The device includes: an anode; a cathode; and an organic layer including a light-emitting layer, wherein the light-emitting layer contains a red light-emitting guest material and a host material composed of a polycyclic aromatic hydrocarbon compound having a skeleton with 4 to 7 membered rings, and a photosensitizing layer containing a light-emitting guest material generating green light is provided adjacent to the light-emitting layer.
• ORGANIC EL DISPLAY UNIT, METHOD OF MANUFACTURING THE SAME, AND SOLUTION USED IN METHOD
  申请人：Matsumoto Toshiki

  公开号：US20110248247A1

  公开（公告）日：2011-10-13

  An organic electroluminescence display unit includes: a lower electrode for each device; a first hole injection/transport layer provided on the lower electrode for each device; a second organic light emitting layer of the first color provided on the first hole injection/transport layer for the second organic electroluminescence device; a second hole injection/transport layer provided on the entire surfaces of the second organic light emitting layer and the first hole injection/transport layer for the first organic electroluminescence device, and being made of a low molecular material; a blue first organic light emitting layer provided on the entire surface of the second hole injection/transport layer; and an electron injection/transport layer having at least one of electron injection characteristics and electron transport characteristics, and an upper electrode that are provided in sequence on the entire surface of first organic light emitting layer.
• ORGANIC EL DISPLAY AND METHOD OF MANUFACTURING THE SAME
  申请人：Yoshinaga Tadahiko

  公开号：US20110315963A1

  公开（公告）日：2011-12-29

  An organic EL display includes: lower electrodes arranged on a substrate to correspond to first organic EL elements of blue and second organic EL elements of any other color, respectively; hole injection/transport layers arranged on the lower electrodes; second organic light-emitting layers of the other color arranged on the hole injection/transport layers for the second organic EL elements; a first organic light-emitting layer of blue arranged on whole surfaces of the second organic light-emitting layers and the hole injection/transport layers for the first organic EL elements; an electron injection/transport layer arranged on a whole surface of the first light-emitting layer, the electron injection/transport layer made of a nitrogen-containing heterocyclic compound with an electron mobility of 1.0×10 −6 cm 2 /Vs to 1.0×10 −1 cm 2 /Vs both inclusive and having one or both of electron injection properties and electron transport properties; and an upper electrode arranged on the electron injection/transport layer.
• OFFSET PRINTING BLANKET CLEANING LIQUID, METHOD OF CLEANING OFFSET PRINTING BLANKET, METHOD OF MANUFACTURING DISPLAY UNIT, METHOD OF MANUFACTURING PRINTED MATERIAL, AND INK COMPOSITION AND PRINTING METHOD USING THE SAME
  申请人：SONY CORPORATION

  公开号：US20130220159A1

  公开（公告）日：2013-08-29

  An offset printing blanket cleaning liquid includes: a solvent having a dipole moment of about 1.7 or more but less than about 4.1 and having a π covalent bond in a molecular skeleton thereof. Moreover, an ink composition includes: an organic material; and a solvent having a dipole moment of about 1.3 to about 3.0 both inclusive and having a π covalent bond in a molecular skeleton thereof.
• US8405100B2
  申请人：——

  公开号：US8405100B2

  公开（公告）日：2013-03-26