1-acryloyloxy-5-hydroxyhexane

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-acryloyloxy-5-hydroxyhexane
• 英文别名: 5-Hydroxyhexyl prop-2-enoate
• 化学式: C₉H₁₆O₃
• 分子量: 172.224
• InChiKey: AYVBEDWUCJCQOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,5-己二醇 、 丙烯酸乙烯酯 在 双(二丁基氯基锡(四))氧化物 作用下， 反应 45.0h， 以96%的产率得到1-acryloyloxy-5-hydroxyhexane
  参考文献：
  名称：

  在双锡氧烷催化下将醇与酯或乙酸酐轻度和实用地酰化

  摘要：

  二锡氧烷催化剂通过酯和乙酸酐的作用实现醇的酰化。特别地，使用烯醇酯提供了非常有用的方法。伯醇优先于仲醇和苯酚被酰化。对酸和碱敏感的官能团均保持完整。尤其独特的是在当前反应条件下完全耐受的硫官能团的鉴别。由于操作非常简单，因此该方法非常实用。无需纯化即可使用酯类和溶剂，并且不需要惰性气氛。可以简单地通过柱色谱法或蒸馏来分离产物，而无需进行水后处理。

  DOI：

  10.1016/s0040-4020(99)00072-1

文献信息

• MOISTURE-STABLE HOLOGRAPHIC MEDIA
  申请人：Covestro Deutschland AG

  公开号：US20170362165A1

  公开（公告）日：2017-12-21

  The invention relates to novel compounds which are especially suitable for use as writing monomers in holographic media. The invention further provides a photopolymer and a holographic medium comprising the inventive compounds, and an optical display, a security document and a holographic optical element comprising an inventive holographic medium.

  该发明涉及新型化合物，特别适用于作为全息媒介中的写入单体。该发明还提供了一种光聚合物和一种包括该发明化合物的全息媒介，以及一种光学显示器、安全文件和包括该发明全息媒介的全息光学元件。
• Polyphosphazene polymers containing substituents of acrylate functionality and process for preparing same
  申请人：THE FIRESTONE TIRE & RUBBER COMPANY

  公开号：EP0008794A1

  公开（公告）日：1980-03-19

  Polyphosphazene polymers are prepared which contain repeating units represented by the formulas: wherein X and X' are the same or different and are represented bv: wherein R1 is selected from the group consisting of hydrogen and a methyl group; R2 and R3 are independently selected for each carbon atom from a group consisting of hydrogen and alkyl radical containing from 1 to 6 carbon atoms; 2 < m < 20; X' can additionally be selected from the group consisting of substituted and unsubstituted alkoxy, aryloxy, amino and mercapto radicals, and mixtures thereof, which are compatible with an alkoxy acrylate substituent and are known in the state of the art of polyphosphazene technology; and 20 < (w + y + z) < 50,000 per polymer. The polymers of the invention can be utilized to form protective films and can also be utilized in applications such as for molding, coatings, foams and the like.

  所制备的聚磷苯聚合物包含由以下公式表示的重复单元： 其中 X 和 X'相同或不同，并由下列式子表示 其中 R1 选自氢和甲基组成的组；R2 和 R3 每个碳原子独立地选自氢和含 1 至 6 个碳原子的烷基组成的组；2 < m < 20；X'可另外选自由取代和未取代的烷氧基、芳氧基、氨基和巯基及其混合物组成的组，它们与丙烯酸烷氧基取代基相容，并且在聚磷酸盐技术领域是已知的；以及 20 < (w + y + z) < 50,000 个/聚合物。 本发明的聚合物可用于形成保护膜，也可用于模塑、涂层、泡沫等应用。
• Coated resin molded-article
  申请人：IDEMITSU PETROCHEMICAL COMPANY LIMITED

  公开号：EP0307861A2

  公开（公告）日：1989-03-22

  Provided herein is a coated resin molded-article which comprises a polyester resin substrate and a cured coating formed thereon which contains a curable phosphazene compound. The molded article will find use as film sheet, and container which have improved abrasion resistance, weather resistance, heat resistance, heat shock resistance, hot water resistance, moisture resistance, alkali resistance, impact resistance, cloud resistance, transparency, oil resistance, surface gloss, and air barrier properties, while keeping the good properties of the resin.

  本文提供了一种涂覆树脂模塑件，它包括聚酯树脂基材和在其上形成的含有可固化磷苯化合物的固化涂层。这种成型品可用作薄膜片材和容器，在保持树脂良好性能的同时，还具有更好的耐磨性、耐候性、耐热性、耐热冲击性、耐热水性、耐湿性、耐碱性、耐冲击性、耐云雾性、透明度、耐油性、表面光泽度和空气阻隔性。
• Curable resin composition
  申请人：IDEMITSU PETROCHEMICAL CO. LTD.

  公开号：EP0557943A2

  公开（公告）日：1993-09-01

  Disclosed herein is a curable resin composition comprising (A) a curable phosphazene compound, (B) a multifunctional (meth)acrylate-based compound such as dipentaerythritol hexaacrylate and (C) a crosslinkable compound having a cure shrinkage of 6% or less such as (meth)acrylate modified polymer which is a product modified by epoxy. This resin composition provides a cured resin film having a high rate of cure, tractable to coat in a great thickness and further excellent in surface hardness, transparency and weathering resistance.

  本发明公开了一种可固化树脂组合物，该组合物包括：(A) 一种可固化的磷氮化合物；(B) 一种多功能（甲基）丙烯酸酯基化合物，如二季戊四醇六丙烯酸酯；(C) 一种可交联化合物，其固化收缩率在 6% 或以下，如（甲基）丙烯酸酯改性聚合物，它是一种环氧改性产品。这种树脂组合物提供的固化树脂膜具有较高的固化率，可涂覆很厚的涂层，而且表面硬度、透明度和耐候性极佳。
• Resin composition, thermal transfer-receiving sheet, and method for making thermal transfer-receiving sheet
  申请人：Sony Corporation

  公开号：EP2287008A2

  公开（公告）日：2011-02-23

  A resin composition used to form a dye-receiving layer of a thermal transfer-receiving sheet in which the dye-receiving layer is formed on at least one surface of a substrate contains a core/shell-type latex including a core containing (A) and a shell containing (B) and a cross-linking agent that reacts with a carboxyl group contained in the shell. (A) is an acrylic resin at least containing, as one of its monomers, a substituted or unsubstituted phenoxyalkyl (meth)acrylate and/or a substituted or unsubstituted phenoxy polyalkylene glycol (meth)acrylate. (B) is a urethane resin containing a carboxyl group.

  一种用于形成热转印接收片材的染料接收层的树脂组合物，其中染料接收层至少形成在基材的一个表面上，该树脂组合物含有芯/壳型胶乳，该胶乳包括含有(A)的芯和含有(B)的壳以及与壳中所含羧基反应的交联剂。(A) 是一种丙烯酸树脂，作为其单体之一，至少含有取代或未取代的苯氧基烷基（甲基）丙烯酸酯和/或取代或未取代的苯氧基聚亚烷基二醇（甲基）丙烯酸酯。(B) 是含有羧基的聚氨酯树脂。