三硝基苯胺 | 26952-42-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 三硝基苯胺
• 英文名称: 2,3,4-trinitro-aniline
• 英文别名: 2,3,4-Trinitro-anilin；Trinitroaniline；2,3,4-trinitroaniline
• CAS: 26952-42-1
• 化学式: C₆H₄N₄O₆
• 分子量: 228.121
• InChiKey: IVOMCIOXYNVSEW-UHFFFAOYSA-N

物化性质

• 物理描述：
  2,3,4-trinitroaniline appears as an orange-red crystalline structure. Highly toxic. May explode under exposure to heat or fire. Primary hazard is blast of an instantaneous explosion, not flying projectiles or fragments.

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  164
• 氢给体数：
  1
• 氢受体数：
  7

安全信息

• 危险等级：
  1.1D

反应信息

• 作为反应物：
  描述：

  三硝基苯胺 在 硫酸 、 双氧水 作用下， 反应 24.0h， 以78%的产率得到1,2,3,4-Tetranitrobenzene
  参考文献：
  名称：

  Synthesis of polynitro compounds. Peroxydisulfuric acid oxidation of polynitroarylamines to polynitro aromatics

  摘要：

  DOI：

  10.1021/jo01300a015
• 作为产物：
  描述：

  3,4-二硝基苯胺 在 硫酸 、 硝酸 、 乙酸酐 作用下， 以 溶剂黄146 为溶剂， 反应 17.5h， 生成 三硝基苯胺
  参考文献：
  名称：

  Synthesis of polynitro compounds. Peroxydisulfuric acid oxidation of polynitroarylamines to polynitro aromatics

  摘要：

  DOI：

  10.1021/jo01300a015

文献信息

• Amphiphilic heparin derivative formed by coupling a heparin with a bile acid
  申请人：Hoarau Didier

  公开号：US20070141158A1

  公开（公告）日：2007-06-21

  The invention relates to an amphiphilic heparin derivative formed from at least one type of partially N-desulfated heparin and at least one type of bile acid comprising one or several bile acid molecules grafted on a heparin molecule by an amide bond formed between the terminal carboxylic acid function of a bile acid and a primary heparin amine function which is initially present in the heparin or resulting from the N-desulfation. The inventive derivative is characterized in that the number of grafted bile acid molecules per 100 heparin disaccharide units ranges from 15 to 80 approximately.

  本发明涉及一种两性异相性肝素衍生物，由至少一种部分N-去硫化肝素和至少一种胆汁酸组成，其中通过酰胺键形成胆汁酸末端羧酸功能与肝素末端胺基功能之间的结合，将一个或多个胆汁酸分子嫁接到肝素分子上。该衍生物的特点在于，每100个肝素二糖单位嫁接的胆汁酸分子数约为15至80个。
• N-denitration of N,2,6-trinitroanilines with phase transfer catalysts
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0024503A1

  公开（公告）日：1981-03-11

  A method for the N-denitration of secondary N,2,6- trinitroanilines with phase transfer catalysts selected from quaternary ammonium salts.

  一种利用选自季铵盐的相转移催化剂对仲 N,2,6-三硝基苯胺进行 N-脱硝化的方法。
• Cross-linked polyalkenyl phenol based photoresist compositions
  申请人：International Business Machines Corporation

  公开号：EP0202458A2

  公开（公告）日：1986-11-26

  A film forming, radiation sensitive resist composition having improved thermal stability and a reduced dissolution rate in developer solutions, comprised of a sensitizer and a polyalkenyl phenol such as a polyvinyl phenol cross-linked, prior to irradiation, with a polyfunctional cross-linking agent such as dimethylol p-cresol or hexamethylene tetramine and a process for the production of a resist image using said composition is described.

  描述了一种成膜的辐射敏感抗蚀剂组合物，它具有更好的热稳定性和更低的显影溶液溶解率，由感光剂和聚烯基苯酚（如聚乙烯基苯酚）组成，在辐照前与多官能团交联剂（如二羟甲基对甲酚或六亚甲基四胺）交联。
• Adhesive compounds
  申请人：Bridgestone Corporation

  公开号：EP0206170A1

  公开（公告）日：1986-12-30

  Cross-linking type adhesive compounds comprising (A) polymers having a,β-unsaturated carboxylate groups, (B) materials having polymerizable vinyl groups, which contain an acrylic and/or methacrylic acid, (C) thermoplastic resins and (D) catalysts of organic peroxides and/or photosensitizers. The adhesive compounds have good adhesive properties together with an excellent heat aging resistance, and can be applied for adhesion of organic and inorganic substrates.

  交联型粘合剂化合物包括：(A) 具有 a、β-不饱和羧酸基团的聚合物；(B) 具有可聚合乙烯基的材料，其中含有丙烯酸和/或甲基丙烯酸；(C) 热塑性树脂；(D) 有机过氧化物催化剂和/或光敏剂。这些粘合剂化合物具有良好的粘合性能和优异的耐热老化性，可用于粘合有机和无机基材。
• Process for the preparation of integral skin polyurethane steering wheels
  申请人：BASF Corporation

  公开号：EP0297519A1

  公开（公告）日：1989-01-04

  The integral skin polyurethane steering wheel is prepared by reacting (a) a mixture of a graft polymer dispersion in a polyol or a polyol mixture (b) an organic polyisocyanate selected from the group consisting of an isocyanate prepolymer prepared by reacting 4,4′-­diphenylmethane diisocyanate with a mixture of dipropylene glycol and a polyoxypropylene glycol having a molecular weight of about 420, a polymeric polymethylene polyphenylene polyisocyanate containing about 55 weight percent diphenylmethane diisocyanate, a 1:1 mixture of 2,4′- and 4,4′-diphenylmethane diisocyanate and mixtures thereof, (c) a blowing agent, (d) a chain extender, and (e) a catalyst, surfactant and optionally flame retardants, fillers U.V. absorbers and other additives.

  整体蒙皮聚氨酯方向盘是通过以下反应制备的：(a) 接枝聚合物分散在多元醇或多元醇混合物中的混合物；(b) 有机多异氰酸酯，该有机多异氰酸酯选自以下组别：由 4、4′-diphenylmethane diisocyanate with a mixture of dipropylene glycol and a polyoxypropylene glycol having a molecular weight of about 420, a polymeric polymethylene polyphenylene polyisocyanate containing about 55 weight percent diphenylmethane diisocyanate, a 1：2,4′- 和 4,4′- 二苯基甲烷二异氰酸酯的 1:1 混合物及其混合物，(c) 发泡剂，(d) 扩链剂，(e) 催化剂，表面活性剂和可选的阻燃剂，填料 U. V. 吸收剂和其他添加剂。V. 吸收剂和其他添加剂。