三苯并[fg,ij,rst]戊芬 | 190-81-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 中文名称: 三苯并[fg,ij,rst]戊芬
• 英文名称: tribenzoperylene
• 英文别名: Tribenzoperylen；tribenzo[fg,ij,rst]pentaphene；Tribenzo[e,ghi,k]perylene；tribenzo[b,n,pqr]perylene；tribenzo[fg,ij,rst]pentaphene；Tribenzo[fg,ij,rst]pentaphen；Tribenzo(b,n,pqr)perylene；octacyclo[16.12.0.02,15.03,8.04,29.09,14.019,24.025,30]triaconta-1(18),2(15),3(8),4,6,9,11,13,16,19,21,23,25(30),26,28-pentadecaene
• CAS: 190-81-8
• 化学式: C₃₀H₁₆
• 分子量: 376.457
• InChiKey: OCHHCTQLQKUZDD-UHFFFAOYSA-N

物化性质

• 沸点：
  653.8±22.0 °C(Predicted)
• 密度：
  1.401±0.06 g/cm3(Predicted)
• 熔点：
  380 °C

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  30
• 可旋转键数：
  0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,4-Diphenyl-triphenylen 在 三氯化铝 、 sodium chloride 作用下， 生成 三苯并[fg,ij,rst]戊芬
  参考文献：
  名称：

  Reimlinger; Overstraeten, Chemische Berichte, 1958, vol. 91, p. 2151,2155

  摘要：

  DOI：

文献信息

• Modular metal-free catalytic radical annulation of cyclic diaryliodoniums to access π-extended arenes
  作者：Daqian Zhu、Hui Peng、Yameng Sun、Zhouming Wu、Yun Wang、Bingling Luo、Tiantian Yu、Yumin Hu、Peng Huang、Shijun Wen

  DOI：10.1039/d0gc04183a

  日期：——

  Tert-butylamine-catalyzed free radical annulations with cyclic diaryliodoniums occur in environmentally friendly ethyl acetate and do not require transition metal, providing diversified polycyclic aromatic hydrocarbons by modulating substituents.

  叔丁胺催化的自由基环化反应与环状二芳基碘嗡盐在环保的乙酸乙酯中进行，无需过渡金属，通过调节取代基可提供多样化的多环芳烃。

• The Rolling-Up of Oligophenylenes to Nanographenes by a HF-Zipping Approach
  作者：Ann-Kristin Steiner、Konstantin Y. Amsharov

  DOI：10.1002/anie.201707272

  日期：2017.11.13

  nature of oligophenylene‐based precursors efficient regioselective zipping to the target nanostructures was achieved. We show that fluorine positions in the precursor structure unambiguously dictate the “running of the zipping‐program” which results in rolling‐up of linear oligophenylene chains around phenyl moieties yielding target nanographenes. The high efficiency of zipping makes this approach attractive

  分子内芳基-芳基偶联是合理合成纳米石墨烯和纳米带的关键转变。在这方面，CF键活化被证明是一种通用的替代方法，可以合成几种独特的基于碳的纳米结构。在本文中，我们描述了前所未有的具有挑战性的转变，表明氧化铝对CF键的活化作用可形成高度有效的多米诺骨状C-C键。尽管基于低聚亚苯基的前体具有柔韧性，但仍实现了对目标纳米结构的有效区域选择性拉链。我们表明，前体结构中的氟位置明确决定了“拉链程序的运行”，这导致围绕苯基部分的线性低聚亚苯基链的卷曲，从而产生了目标纳米石墨烯。
• Systematic investigations on fused π-system compounds of seven benzene rings prepared by photocyclization of diphenanthrylethenes
  作者：Shota Fujino、Minoru Yamaji、Hideki Okamoto、Toshiki Mutai、Isao Yoshikawa、Hirohiko Houjou、Fumito Tani

  DOI：10.1039/c7pp00040e

  日期：2017.6

  (nEm; n, m = 1, 3 and 9) for understanding photocyclization patterns based on NMR spectroscopy. The crystal structures of the photoproducts were analyzed by X-ray crystallography, and the photophysical features of the photocyclized molecules were investigated based on emission and transient absorption measurements. Phenanthrene derivatives substituted at the 1- and 3-positions were prepared for synthesizing

  我们研究了1-（n-菲基）-2-（m-菲基）乙烯的光产物（n E m；n，m = 1、3和9），以了解基于NMR光谱的光环化模式。通过X射线晶体学分析光产物的晶体结构，并基于发射和瞬态吸收测量来研究光环化分子的光物理特征。制备了在1-位和3-位取代的菲衍生物，用于通过二苯乙烯衍生物的光环化合成n E m。我们获得了四种主要的光产品（n @ m）从相应的n E m。通过X射线晶体学测定，发现其中两个在单晶中具有外消旋分子结构。除了主要的光产物外，还分离出两种类型的次要光产物（n @ m PP）。在溶液中测定了获得的光产物的荧光量子产率和寿命，而在粉末中获得了确定的荧光量子产率。通过激光光解技术观察溶液中的三重态-三重态吸收光谱表明，跨系统进入三重态的过程与荧光过程竞争。
• Zur Kenntnis des Coronens. 2. Mitteilung. Dien-Anlagerungen in der Perylen- und Benzperylenreihe
  作者：H. Hopff、H. R. Schweizer

  DOI：10.1002/hlca.19590420704

  日期：——

  The addition of maleic anhydride to perylene and other kata- and peri-condensed aromatic compounds in the presence of a dehydrogenating agent is studied. The para- localisation energies PD for the positions involved are calculated for a number of compounds with an approximate method outlined by DEWAR and are compared with the experimental data as well as with the values PB obtained by BROWN.The divergencies

  研究了在脱氢剂存在下将马来酸酐添加到per和其他经kata-和per-condensed的芳族化合物中。用DEWAR概述的近似方法计算了许多化合物的所涉及位置的准局域能P D，并将其与实验数据以及BROWN获得的P B值进行了比较。讨论过。
• Charge-transfer Complexes, Gas-liquid Chromatographic and Photochemical Characteristics, and Solvent Adducts of Polyphenylenes and Related Linear Polyphenylsls
  作者：Yasuhiro Fujioka

  DOI：10.1246/bcsj.58.481

  日期：1985.2

  The absorption spectra of the charge-transfer (CT) complexes formed by two acceptors (tetracyanoethylene and 2,3-dichloro-5,6-dicyano-p-benzoquinone) with thirteen macrocyclic polyphenylenes and with thirty-eight linear polyphenyls were measured in dichloromethane. A linear relationship existing between the first transitions of the CT-complexes and those of the uncomplexed donor hydrocarbons made it possible to predict the CT-bands of new polyphenylenes and polyphenyls. By the gas-liquid chromatography using a glass capillary column, forty-nine polyphenyls and polyphenylenes, containing a large number of isomers, were successfully analyzed. The relationship between the retention times and the structure of linear polyphenyls was expressed by means of a simple empirical equation, and the equation was also applicable to the polyphenylenes by adding a correction factor. These equations are extremely useful for the estimation of the retention time and elution order and the structure of unknown polyphenyls and polyphenylenes. The reductive irradiation of m,m,o,p,o-pentaphenylene provided the bridged annulene compound. For six polyphenylenes and the related compounds, the criteria for the occurrence of the intramolecular photocoupling reaction were discussed. Among the examined polyphenylenes, m,o,o,m,o,o-hexaphenylene and o,p,p,o,p,p,o,p,p-nonaphenylene formed the adducts with several solvents.

  在二氯甲烷中测量了由两个受体（四氰乙烯和2,3-二氯-5,6-二氰基-对苯醌）与13种大环聚苯和38种线型聚苯形成的电荷转移（CT）复合物的吸收光谱。由于CT复合物的第一级跃迁与未复合的供体烃的第一级跃迁之间存在线性关系，因此可以预测新聚苯和聚苯的CT带。通过玻璃毛细管柱的气液色谱法，成功分析了49种含有大量异构体的聚苯和聚苯。通过简单的经验方程式表示了线型聚苯的保留时间和结构之间的关系，通过添加校正因子，该方程式也适用于聚苯。这些方程式对于未知聚苯和聚苯的保留时间、洗脱顺序和结构的估计非常有用。m,m,o,p,o-五苯的还原照射提供了桥联环烯化合物。对于6种聚苯和相关化合物，讨论了分子内光偶联反应发生的标准。在所研究的聚苯中，m,o,o,m,o,o-六苯和o,p,p,o,p,p,o,p,p-九苯与几种溶剂形成了加合物。

表征谱图