9-phenyl-9-phosphabicyclononane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 9-phenyl-9-phosphabicyclononane
• 英文别名: 2-cyclononyl-1-phenylphosphonane
• 化学式: C₂₃H₃₇P
• 分子量: 344.521
• InChiKey: BCRBRGOICPXZGO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.74
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,5-环辛二烯 、 苯基膦 、 二叔丁基过氧化物 、 十一烷 、 、 在 氩 、 9-phenyl-9-phosphabicyclo<4.2.1>nonane 、 9-phenyl-9-phosphabicyclo<3.3.1>nonane 、 氮气 作用下， 反应 19.0h， 生成 9-phenyl-9-phosphabicyclononane
  参考文献：
  名称：

  Process for production of biodegradable surfactants and compositions

  摘要：

  本发明涉及制备可生物降解表面活性剂的方法。该方法包括若干步骤，其中包括一个可选步骤。第一步是将烯烃与ZSM-23催化剂反应，以形成具有公式（C.sub.3）.sub.x，（C.sub.4）.sub.x或其混合物的寡聚物。第二步是将寡聚物羰基化反应，以形成饱和醇，例如十三醇。接下来，饱和醇进行乙氧基化反应。然后恢复非离子生物降解表面活性剂。该表面活性剂可用于洗涤剂配方中。还教授了一种制备酯类的方法，可用作润滑剂或增塑剂。还教授了一种使用改性钴羰基催化剂的特定羰基化反应过程。还教授了一种特定的乙氧基化过程。还教授了根据后两种过程形成的产品及其用途。

  公开号：

  US05112519A1

文献信息

• Process for production of biodegradable esters
  申请人：Mobil Oil Corporation

  公开号：US05245072A1

  公开（公告）日：1993-09-14

  This invention relates to processes for making biodegradable surfactant. The process comprises several steps including an optional step. The first step is directed to reacting olefins with ZSM-23 catalyst to form oligomers having the formula -(C.sub.3).sub.x, (C.sub.4).sub.x or mixtures thereof. Second, the oligomer is hydroformylated to form a saturated alcohol, for example, tridecanol. Next, the saturated alcohol is ethoxylated. Thereafter a nonionic biodegradable surfactant is recovered. This surfactant can be used in detergent formulations. A process is also taught for making esters which can be used as lubricants or plasticizers. A specific hydroformylation process is taught which utilizes modified cobalt carbonyl catalyst. Also, a specific ethoxylation process is taught. Products formed according to the latter two processes as well as their uses are also taught.

  本发明涉及制备可生物降解表面活性剂的过程。该过程包括多个步骤，包括一个可选步骤。第一步是将烯烃与ZSM-23催化剂反应，形成具有式-(C.sub.3).sub.x，(C.sub.4).sub.x或其混合物的寡聚体。其次，对寡聚体进行氢甲酰化反应，形成饱和醇，例如十三醇。接下来，对饱和醇进行乙氧基化反应。然后，回收非离子型可生物降解表面活性剂。该表面活性剂可用于洗涤剂配方中。还教授了一种制备酯类的方法，可用作润滑剂或增塑剂。还教授了一种利用改性钴羰基催化剂的特定氢甲酰化反应过程。还教授了一种特定的乙氧基化反应过程。还教授了根据后两种过程形成的产品及其用途。
• Process for production of biodegradable surfactants and compositions
  申请人：Mobil Oil Corporation

  公开号：US05112519A1

  公开（公告）日：1992-05-12

  This invention relates to processes for making biodegradable surfactant. The process comprises several steps including an optional step. The first step is directed to reacting olefins with ZSM-23 catalyst to form oligomers having the formula (C.sub.3).sub.x, (C.sub.4).sub.x or mixtures thereof. Second, the oligomer is hydroformylated to form a saturated alcohol, for example, tridecanol. Next, the saturated alcohol is ethoxylated. Thereafter a nonionic biodegradable surfactant is recovered. This surfactant can be used in detergent formulations. A process is also taught for making esters which can be used as lubricants or plasticizers. A specific hydroformylation process is taught which utilizes modified cobalt carbonyl catalyst. Also, a specific ethoxylation process is taught. Products formed according to the latter two processes as well as their uses are also taught.

  本发明涉及制备可生物降解表面活性剂的方法。该方法包括若干步骤，其中包括一个可选步骤。第一步是将烯烃与ZSM-23催化剂反应，以形成具有公式（C.sub.3）.sub.x，（C.sub.4）.sub.x或其混合物的寡聚物。第二步是将寡聚物羰基化反应，以形成饱和醇，例如十三醇。接下来，饱和醇进行乙氧基化反应。然后恢复非离子生物降解表面活性剂。该表面活性剂可用于洗涤剂配方中。还教授了一种制备酯类的方法，可用作润滑剂或增塑剂。还教授了一种使用改性钴羰基催化剂的特定羰基化反应过程。还教授了一种特定的乙氧基化过程。还教授了根据后两种过程形成的产品及其用途。
• Processes for the preparation of saturated alcohol derivatives and their use in detergent: plasticizer: and synthetic lubricant formulations
  申请人：MOBIL OIL CORPORATION

  公开号：EP0402051A2

  公开（公告）日：1990-12-12

  This invention relates to processes for making biodegradable surfactant. The process comprises several steps including an optional step. The first step is directed to reacting olefins with ZSM-23 catalyst to form oligomers having the formula (C₃)x, (C₄)x or mixtures thereof. Second, the oligomer is hydroformylated to form a saturated alcohol, for example, tridecanol. Next, the saturated alcohol is ethoxylated. Thereafter a nonionic biodegradable surfactant is recovered. This surfactant can be used in detergent formulations. A process is also taught for making esters which can be used as lubricants or plasticizers. A specific hydroformylation process is taught which utilizes modified cobalt carbonyl catalyst. Also, a specific ethoxylation process is taught. Products formed according to the latter two processes as well as their uses are also taught.

  本发明涉及可生物降解表面活性剂的制造工艺。该工艺包括几个步骤，其中包括一个可选步骤。第一步是将烯烃与 ZSM-23 催化剂反应，形成式为 (C₃x、(C₄x) 或其混合物的低聚物。其次，将低聚物进行氢甲酰化，形成饱和醇，例如十三醇。接着，饱和醇被乙氧基化。然后回收非离子型可生物降解表面活性剂。这种表面活性剂可用于洗涤剂配方。此外，还介绍了一种制造酯的工艺，这种酯可用作润滑剂或增塑剂。该工艺采用改性羰基钴催化剂。此外，还介绍了一种特殊的乙氧基化工艺。还介绍了根据后两种工艺形成的产品及其用途。
• BRANCHED CHAIN COMPOUNDS AND THEIR USE
  申请人：ALBEMARLE CORPORATION

  公开号：EP0846094B1

  公开（公告）日：2001-04-25
• PROCESS FOR THE CARBONYLATION OF AN ACETYLENICALLY UNSATURATED COMPOUND
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0733034B1

  公开（公告）日：1998-09-02