2,7-di([1,1′:3′,1′′-terphenyl]-5′-yl)spiro[fluorene-9,15′-indeno[2,1-g]chrysene]

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 2,7-di([1,1′:3′,1′′-terphenyl]-5′-yl)spiro[fluorene-9,15′-indeno[2,1-g]chrysene]
• 英文别名: 2,7-Bis(3,5-diphenylphenyl)spiro[fluorene-9,3'-hexacyclo[15.8.0.02,10.04,9.011,16.020,25]pentacosa-1(17),2(10),4,6,8,11,13,15,18,20,22,24-dodecaene]；2,7-bis(3,5-diphenylphenyl)spiro[fluorene-9,3'-hexacyclo[15.8.0.02,10.04,9.011,16.020,25]pentacosa-1(17),2(10),4,6,8,11,13,15,18,20,22,24-dodecaene]
• 化学式: C₇₃H₄₆
• 分子量: 923.168
• InChiKey: BHPVCIKXEUQPGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.9
• 重原子数：
  73
• 可旋转键数：
  6
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.01
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  6-溴屈 在 四(三苯基膦)钯 、 正丁基锂 、 palladium diacetate 、 四乙基氢氧化铵 、 potassium carbonate 、 三环己基膦 作用下， 以 四氢呋喃 、 乙醇 、 水 、 甲苯 为溶剂， 反应 4.67h， 生成 2,7-di([1,1′:3′,1′′-terphenyl]-5′-yl)spiro[fluorene-9,15′-indeno[2,1-g]chrysene]
  参考文献：
  名称：

  COMPOUNDS FOR ORGANIC OPTOELECTRONIC DEVICE AND ORGANIC OPTOELECTRONIC DEVICE INCLUDING THE SAME

  摘要：

  提供了一种由化学式1表示的有机光电子器件的化合物，以及包括该化合物的有机光电子器件。在化学式1中，R1到R5独立地是氢、氘、—NH2、取代或未取代的C1到C30烷胺基团、取代或未取代的C6到C30芳胺基团、取代或未取代的C1到C30烷基团、取代或未取代的C6到C30芳基团、取代或未取代的C2到C30杂环基团，或它们的组合，R2、R4和R5中至少有一个是取代或未取代的C6到C30芳基团、取代或未取代的C6到C30芳胺基团或取代或未取代的C2到C30杂环基团，a、c、d、e和f中的每个是1到4的整数，b是1或2的整数。

  公开号：

  US20180019403A1

文献信息

• Three-Dimensional Structures Based on the Fusion of Chrysene and Spirobifluorene Chromophores for the Development of Blue OLEDs
  作者：Hayoon Lee、Hyocheol Jung、Seokwoo Kang、Jin Hyuck Heo、Sang Hyuk Im、Jongwook Park

  DOI：10.1021/acs.joc.7b03008

  日期：2018.3.2

  A new deep-blue chromophore containing a three-dimensionally (3D) shaped CS core composed of fused chrysene and spirofluorene units is synthesized. A pair of m-terphenyl (TP) units is also substituted onto the CS core at two different sets of positions to form two additional compounds: CS-TPTP and TP-CS-TP. The TP-CS-TP compound showed the highest efficiency with an external quantum efficiency (EQE) of 3.05% and Commission Internationale de L'Eclairage coordinates (CIE) of (0.148, 0.098) corresponding to the emission of blue light. This approach for forming a new chromophore is expected to lead to the development of functional organic materials with excellent characteristics.
• COMPOUNDS FOR ORGANIC OPTOELECTRONIC DEVICE AND ORGANIC OPTOELECTRONIC DEVICE INCLUDING THE SAME
  申请人：UNIVERSITY-INDUSTRY COOPERATION GROUP OF KYUNG HEE UNIVERSITY

  公开号：US20180019403A1

  公开（公告）日：2018-01-18

  A compound for an organic optoelectronic device represented by Chemical Formula 1 and an organic optoelectronic device including the same are provided. In Chemical Formula 1, R1 to R5 are independently hydrogen, deuterium, —NH2, a substituted or unsubstituted C1 to C30 alkylamine group, a substituted or unsubstituted C6 to C30 arylamine group, a substituted or unsubstituted C1 to C30 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, or a combination thereof, at least one of R2, R4, and R5 is a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C6 to C30 arylamine group, or a substituted or unsubstituted C2 to C30 heteroaryl group, each of a, c, d, e, and f is an integer of 1 to 4, and b is an integer of 1 or 2.

  提供了一种由化学式1表示的有机光电子器件的化合物，以及包括该化合物的有机光电子器件。在化学式1中，R1到R5独立地是氢、氘、—NH2、取代或未取代的C1到C30烷胺基团、取代或未取代的C6到C30芳胺基团、取代或未取代的C1到C30烷基团、取代或未取代的C6到C30芳基团、取代或未取代的C2到C30杂环基团，或它们的组合，R2、R4和R5中至少有一个是取代或未取代的C6到C30芳基团、取代或未取代的C6到C30芳胺基团或取代或未取代的C2到C30杂环基团，a、c、d、e和f中的每个是1到4的整数，b是1或2的整数。