dimethyl(4-phenyl-(1E,3E)-butadien-1-yl)silane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dimethyl(4-phenyl-(1E,3E)-butadien-1-yl)silane
• 化学式: C₁₂H₁₆Si
• 分子量: 188.345
• InChiKey: BKKVAVKNEBFOGO-JMQWPVDRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.28
• 重原子数：
  13.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  2-styryl-1,3-dithiolane 在 bis(triphenylphosphine)nickel(II) chloride 、 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 、 苯 为溶剂， 反应 34.0h， 生成 dimethyl(4-phenyl-(1E,3E)-butadien-1-yl)silane
  参考文献：
  名称：

  A general synthesis of vinylic silyl hydrides using nickel catalysis. Applications to the syntheses of silylene-tethered conjugated polymers

  摘要：

  Treatment of benzylic or allylic dithioacetals with Me-2((PrO)-Pr-i)SiCH2MgCl in the presence of NiCl2(PPh3)(2) catalyst yielded the corresponding i-propoxy(vinyl)silanes which are reduced with LIAlH4, to afford vinylic silyl hydrides. These hydrides serve as the precursors for the syntheses of silylene-tethered sigma,pi-conjugated copolymers. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(97)10218-6

文献信息

• A general synthesis of vinylic silyl hydrides using nickel catalysis. Applications to the syntheses of silylene-tethered conjugated polymers
  作者：Ruey-Min Chen、Tien-Yau Luh

  DOI：10.1016/s0040-4020(97)10218-6

  日期：1998.2

  Treatment of benzylic or allylic dithioacetals with Me-2((PrO)-Pr-i)SiCH2MgCl in the presence of NiCl2(PPh3)(2) catalyst yielded the corresponding i-propoxy(vinyl)silanes which are reduced with LIAlH4, to afford vinylic silyl hydrides. These hydrides serve as the precursors for the syntheses of silylene-tethered sigma,pi-conjugated copolymers. (C) 1998 Elsevier Science Ltd. All rights reserved.