N-phenyltrifluoromethanesulfonimide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-phenyltrifluoromethanesulfonimide
• 英文别名: Phenyl-bis(trifluoromethylsulfonyl)phosphane；phenyl-bis(trifluoromethylsulfonyl)phosphane
• 化学式: C₈H₅F₆O₄PS₂
• 分子量: 374.221
• InChiKey: GJMAOMLJUIHWLA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  85
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  象牙酮宁 、 N-phenyltrifluoromethanesulfonimide 在 lithium hexamethyldisilazane 、 六甲基磷酰三胺 作用下， 以 四氢呋喃 为溶剂， 反应 17.5h， 以71%的产率得到
  参考文献：
  名称：

  依苯那莫宁、藻茶碱和 16'-表白茶碱的对映选择性合成

  摘要：

  本文公开了异二聚双吲哚生物碱无色翠啶的合成方法。通过钯催化的不对称烯丙基烷基化合成的对映体富集的内酰胺结构单元，作为两个半球的前体。依苯那莫宁衍生的片段是通过 Bischler-Napieralski/氢化方法合成的，而绿茶碱衍生的片段是通过 Friedländer 喹啉合成和两个连续的 C−H 官能化步骤合成的。收敛的 Stille 偶联和苯酚定向氢化将两个单体片段结合起来，通过 21 个步骤从商业材料中得到 16'-表-无色翠啶。

  DOI：

  10.1002/anie.202106184

文献信息

• A CATALYST FOR HOMOPOLYMERIZING AND COPOLYMERIZING PROPYLENE AND ITS PREPARATION AND USE
  申请人：Petrochina Company Limited

  公开号：EP2345675A1

  公开（公告）日：2011-07-20

  A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl2.nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl2.nROH is 0.01-1, based on the amount of MgCl2.nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl2.nROH is 1-200. The catalyst has high activity high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.

  一种用于均聚和共聚丙烯的催化剂及其制备和使用方法。催化剂组分包括含有至少一个钛卤键的钛化合物和至少两种支撑在 MgCl2.nROH 加合物上的电子供体化合物 A 和 B，其中电子供体化合物 A 为式（I）化合物，电子供体化合物 B 为酯或醚化合物；化合物 A 和化合物 B 的摩尔比为 0.1-5；以MgCl2.nROH的量计，两种电子供体与MgCl2.nROH总量的摩尔比为0.01-1；含Ti-卤素键的钛化合物与MgCl2.nROH的摩尔比为1-200。该催化剂具有高活性、高立体特异性和良好的共聚性能。此外，由此获得的聚合物的形态也很好。
• Breining, Tibor; Schmidt, Cirill; Polos, Katalin, Synthetic Communications, 1987, vol. 17, # 1, p. 85 - 88
  作者：Breining, Tibor、Schmidt, Cirill、Polos, Katalin

  DOI：——

  日期：——
• CATALYST FOR HOMOPOLYMERIZING AND COPOLYMERIZING PROPYLENE AND ITS PREPARATION AND USE
  申请人：Yi Jianjun

  公开号：US20110207900A1

  公开（公告）日：2011-08-25

  A catalyst for homopolymerizing and copolymerizing propylene and its preparation and use. The catalyst component includes titanium compound containing at least one Ti-halogen bond and at least two kinds of electron donor compounds A and B supported on MgCl 2 .nROH adduct, wherein the electron donor compound A is a compound of formula (I), the electron donor compound B is ester or ether compound; the molar ratio between compound A and compound B is 0.1-5; the molar ratio between the total amounts of the two kinds of electron donors and MgCl 2 .nROH is 0.01-1, based on the amount of MgCl 2 .nROH; and the molar ration between the titanium compound containing Ti-halogen bond and MgCl 2 .nROH is 1-200. The catalyst has high activity, high stereospecificity and good copolymerization performance. In addition, the morphology of the polymer obtained therefrom is good.
• US8470941B2
  申请人：——

  公开号：US8470941B2

  公开（公告）日：2013-06-25
• The Enantioselective Synthesis of Eburnamonine, Eucophylline, and 16′‐ <i>epi</i> ‐Leucophyllidine
  作者：Christopher E. Reimann、Aurapat Ngamnithiporn、Kohei Hayashida、Daisuke Saito、Katerina M. Korch、Brian M. Stoltz

  DOI：10.1002/anie.202106184

  日期：2021.8.9

  hemispheres. The eburnamonine-derived fragment was synthesized through a Bischler–Napieralski/hydrogenation approach, while the eucophylline-derived fragment was synthesized by Friedländer quinoline synthesis and two sequential C−H functionalization steps. A convergent Stille coupling and phenol-directed hydrogenation united the two monomeric fragments to afford 16′-epi-leucophyllidine in 21 steps from

  本文公开了异二聚双吲哚生物碱无色翠啶的合成方法。通过钯催化的不对称烯丙基烷基化合成的对映体富集的内酰胺结构单元，作为两个半球的前体。依苯那莫宁衍生的片段是通过 Bischler-Napieralski/氢化方法合成的，而绿茶碱衍生的片段是通过 Friedländer 喹啉合成和两个连续的 C−H 官能化步骤合成的。收敛的 Stille 偶联和苯酚定向氢化将两个单体片段结合起来，通过 21 个步骤从商业材料中得到 16'-表-无色翠啶。