1,3-bis-(1,1,1,3,3,3-hexafluoro-2-hydroxy-2-propyl)-4,6-phenylenediamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,3-bis-(1,1,1,3,3,3-hexafluoro-2-hydroxy-2-propyl)-4,6-phenylenediamine
• 英文别名: 2-[2,4-diamino-5-(2,2,2-trifluoro-1-hydroxy-1-trifluoromethyl-ethyl)-phenyl]-1,1,1,3,3,3-hexafluoro-propan-2-ol；2-[2,4-Diamino-5-(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)phenyl]-1,1,1,3,3,3-hexafluoropropan-2-ol
• 化学式: C₁₂H₈F₁₂N₂O₂
• 分子量: 440.189
• InChiKey: SXNKBMWEBOCYNZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  92.5
• 氢给体数：
  4
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  间苯二胺 、 六氟丙酮 在 六氟异丙醇 、 三氟乙酸 作用下， 反应 24.0h， 以99.2%的产率得到1,3-bis-(1,1,1,3,3,3-hexafluoro-2-hydroxy-2-propyl)-4,6-phenylenediamine
  参考文献：
  名称：

  含フッ素芳香族ジアミンの製造方法

  摘要：

  抑制芳香族二胺中的亚胺类副产物，提供一种高选择性和高收率地制备含氟芳香族二胺的方法，其中将六氟异丙醇基（-C（CF3）2OH）与芳香环中的芳香族二胺结合。通过在1,1,1,3,3,3-六氟-2-丙醇中使芳香族二胺和六氟丙酮反应，得到结合有六氟异丙醇基的含氟芳香族二胺的制备方法。芳香族二胺和含氟芳香族二胺可以是芳香族多环化合物或芳香族单环化合物。

  公开号：

  JP2019199459A

文献信息

• NOVEL FLUORINE-CONTAINING DICARBOXYLIC ACIDS AND THEIR NOVEL POLYMER COMPOUNDS
  申请人：Narizuka Satoru

  公开号：US20090030173A1

  公开（公告）日：2009-01-29

  Disclosed is a fluorine-containing dicarboxylic acid represented by formula (1), wherein n represents an integer of 1-4, and the two carboxylic groups are not adjacent to each other on the aromatic ring. It is possible to obtain a linear polymer compound by reacting the fluorine-containing dicarboxylic acid with a comonomer (e.g., diaminodiol). By thermal cyclization, this linear polymer compound can be converted into another polymer compound having superior characteristics.

  本发明公开了一种含氟的二羧酸，其化学式表示为（1），其中n表示1-4的整数，两个羧基不相邻于芳环上。通过将含氟二羧酸与共聚单体（例如，二氨基二醇）反应，可以获得线性聚合物化合物。通过热环化，这种线性聚合物化合物可以转化为具有优异特性的另一种聚合物化合物。
• Fluorine-containing polymerizable monomer and polymer compound using same
  申请人：Saegusa Hiroshi

  公开号：US20090023886A1

  公开（公告）日：2009-01-22

  Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula [1], a represents an integer of 1-4.) By having a plurality of polymerizable amines in a molecule while containing a hexafluoroisopropyl group, this fluorine-containing polymerizable monomer exhibiting water repellancy, oil repellency, low water absorbency, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties, and the like, and thus can be applied to the field of advanced polymer materials.

  公开了一种含氟可聚合单体，其化学式如下所示：[1]（在化学式[1]中，a代表1-4的整数）。该含氟可聚合单体分子中含有多个可聚合胺基，并含有六氟异丙基基团，因此具有耐水性、耐油性、低吸水性、耐热性、耐候性、耐腐蚀性、透明度、光敏性、低折射率、低介电性等特性，可应用于高级聚合物材料领域。
• Fluorine-Containing Dicarboxylic Acids and Their Novel Polymer Compounds
  申请人：NARIZUKA Satoru

  公开号：US20110282026A1

  公开（公告）日：2011-11-17

  A fluorine-containing dicarboxylic acid represented by formula (1), wherein n represents an integer of 1-4, and the two carboxylic groups are not adjacent to each other on the aromatic ring. It is possible to obtain a linear polymer compound by reacting the fluorine-containing dicarboxylic acid with a comonomer (e.g., diaminodiol). By thermal cyclization, this linear polymer compound can be converted into another polymer compound having superior characteristics.

  公式(1)表示的是含氟二羧酸，其中n代表1-4的整数，且两个羧基不相邻于芳香环上。通过将含氟二羧酸与共聚物（例如二氨基二醇）反应，可以得到线性聚合物化合物。通过热环化，这种线性聚合物化合物可以转化为具有卓越特性的另一种聚合物化合物。
• Fluorinated Dicarboxylic Acid Derivative and Polymer Obtained Therefrom
  申请人：Isono Yoshimi

  公开号：US20110301305A1

  公开（公告）日：2011-12-08

  According to the present invention, a polymer is obtained by polycondensation of a fluorinated dicarboxylic acid derivative of the general formula (M-1) or an acid anhydride of the fluorinated dicarboxylic acid with a polyfunctional compound having two to four reactive groups corresponding in reactivity to carbonyl moieties of the fluorinated dicarboxylic acid derivative or acid anhydride. [Chem. 134] AOCF 2 C-Q-CF 2 COA′  (M-1) In the above formula, Q represents a divalent organic group having a substituted or unsubstituted aromatic ring; and A and A′ each independently represent an organic group. This polymer exhibits a sufficiently low dielectric constant for use as a semiconductor protection film and has the capability of forming a film at a relatively low temperature of 250° C. or lower.

  根据本发明，通过将通式(M-1)的含氟二羧酸衍生物或含氟二羧酸酸酐与具有与含氟二羧酸衍生物或酸酐的羰基部分相对应的两到四个反应性基团的多官能化合物进行聚合缩合反应，可以得到一种聚合物。[Chem. 134]AOCF2C-Q-CF2COA′  (M-1)在上述公式中，Q代表具有取代或未取代芳香环的二价有机基团; A和A'各自独立地表示有机基团。该聚合物表现出足够低的介电常数，可用作半导体保护膜，并具有在相对较低的温度下（250℃或更低）形成膜的能力。
• Fluorine-Containing Polymerizable Monomer and Polymer Compound Using Same
  申请人：SAEGUSA Hiroshi

  公开号：US20100234556A1

  公开（公告）日：2010-09-16

  Polymers made by polymerization or cyclization condensation of a fluorine-containing polymerizable monomer represented by the formula [1] wherein “a” represents an integer from 1 to 4. The monomer contains a plurality of polymerizable amines in the molecule and at the same time one or more hexafluoroisopropyl group(s). With this structure it can be used as an effective polymerizable monomer, which can exhibit water repellency, oil repellency, low water absorptive property, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index property, low dielectric property, etc., and it can be used for advanced polymer material fields.

  由含有氟的可聚合单体通过聚合或环化缩合制备的聚合物，该单体的化学式为[1]，其中“a”表示1到4的整数。该单体分子中含有多个可聚合胺基以及一个或多个六氟异丙基基团。由此结构形成的单体可以作为有效的可聚合单体使用，它可以表现出防水、防油、低吸水性、耐热性、耐候性、耐腐蚀性、透明度、光敏性、低折射率和低介电性等特性，可用于高级聚合物材料领域。