3,4'-dibromodiphenyl sulfone

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,4'-dibromodiphenyl sulfone
• 英文别名: 1-Bromo-3-(4-bromophenyl)sulfonylbenzene；1-bromo-3-(4-bromophenyl)sulfonylbenzene
• 化学式: C₁₂H₈Br₂O₂S
• 分子量: 376.068
• InChiKey: CNTNTQGIIBFUKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,6-二叔丁基咔唑 、 3,4'-dibromodiphenyl sulfone 在 N,N-二甲基丙烯基脲 、 18-冠醚-6 、 potassium carbonate 、 copper(l) iodide 作用下， 反应 24.17h， 以68.56%的产率得到3,6-di-tert-butyl-9-(3-(4-(3,6-di-tert-butyl-9H-carbazol-9-yl)phenylsulfonyl)phenyl)-9H-carbazole
  参考文献：
  名称：

  Thermally activated delayed fluorescence materials based on 3,6-di-tert-butyl-9-((phenylsulfonyl)phenyl)-9H-carbazoles

  摘要：

  A series of bipolar materials for thermally activated delayed fluorescence based on 3,6-di-tert-butyl-9-((phenylsulfonyl)phenyl)-9H-carbazoles, is synthesized by Ulmann coupling reactions. In these materials, the 3,6-di-tert-butylcarbazole group is linked at the 3-, 4- position or 3'-, 4'- position of diphenyl sulfone. The effects of the conjugation connectivity on the electronic, photophysical and electrochemical properties of these materials, are studied by extensive UV-vis, fluorescence spectroscopic measurements, cyclic voltammetry and theoretical calculations as well as X-ray crystallographic analysis. The energy gap between singlet and triplet in these materials is tuned from 0.39 eV to 0.22 eV by manipulation of conjugation of the electron donor units. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.06.008
• 作为产物：
  描述：

  1-溴-3-碘苯 在 双氧水 、 邻菲罗啉 、 potassium carbonate 、 溶剂黄146 作用下， 以 二甲基亚砜 为溶剂， 反应 48.17h， 生成 3,4'-dibromodiphenyl sulfone
  参考文献：
  名称：

  Thermally activated delayed fluorescence materials based on 3,6-di-tert-butyl-9-((phenylsulfonyl)phenyl)-9H-carbazoles

  摘要：

  A series of bipolar materials for thermally activated delayed fluorescence based on 3,6-di-tert-butyl-9-((phenylsulfonyl)phenyl)-9H-carbazoles, is synthesized by Ulmann coupling reactions. In these materials, the 3,6-di-tert-butylcarbazole group is linked at the 3-, 4- position or 3'-, 4'- position of diphenyl sulfone. The effects of the conjugation connectivity on the electronic, photophysical and electrochemical properties of these materials, are studied by extensive UV-vis, fluorescence spectroscopic measurements, cyclic voltammetry and theoretical calculations as well as X-ray crystallographic analysis. The energy gap between singlet and triplet in these materials is tuned from 0.39 eV to 0.22 eV by manipulation of conjugation of the electron donor units. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.06.008

文献信息

• [EN] NEW CYCLOADDUCT PRECURSORS OF DIHALODIPHENYLSULFONES AND PREPARATIONS THEREOF<br/>[FR] NOUVEAUX PRÉCURSEURS DE CYCLOADDITION DE DIHALOGÉNODIPHÉNYLSULFONES ET LEURS PRÉPARATIONS
  申请人：RHODIA OPERATIONS

  公开号：WO2019030184A1

  公开（公告）日：2019-02-14

  The invention relates to new compounds of formula (I) wherein X represents a halogen atom selected from the group consisting of fluorine, chlorine, bromine and iodine, which are useful for the preparation of 4,4'dihalodiphenylsulfones of formula (III) wherein X is as defined above.

  这项发明涉及公式（I）中的新化合物，其中X代表从氟、氯、溴和碘组成的卤素原子，这些化合物可用于制备公式（III）中的4,4'-二卤二苯砜，其中X如上定义。
• Fine-tuning the photophysical properties of thermally activated delayed fluorescent emitters using torsion angles: high performance sky-blue OLEDs
  作者：Lisi Zhan、Yepeng Xiang、Zhanxiang Chen、Kailong Wu、Shaolong Gong、Guohua Xie、Chuluo Yang

  DOI：10.1039/c9tc04804a

  日期：——

  (TADF) and aggregation-induced emission (AIE) characteristics on account of the highly twisted D–A structure. Their photophysical and electroluminescent properties can be well regulated through this isomeric strategy. Owing to its proper torsion angles and high photoluminescence quantum yields (PLQYs), the 3,4′ACSO2 based device achieves a maximum external quantum efficiency of 20.5% with sky blue emission

  异构策略由于其对物理性质的深远影响而在分子设计中具有重要意义。这里，三种同分异构分子，2,3'ACSO 2，2,4'ACSO 2，和3,4'ACSO 2通过不对称连接方法将两个电子给体（D）的idine啶单元连接至电子受体（A）的二苯砜单元而设计。由于高度扭曲的D–A结构，这三种化合物均具有独特的热激活延迟荧光（TADF）和聚集诱导发射（AIE）特性。通过这种异构策略可以很好地调节它们的光物理和电致发光性质。3,4'ACSO 2由于具有适当的扭转角和高的光致发光量子产率（PLQYs），基于天蓝色发射的器件可实现20.5％的最大外部量子效率。这些结果表明，扭转角的异构策略微调是一种优化光物理和电致发光性质的实用方法。
• ——
  作者：A. V. Kutchin、S. A. Rubtsova、I. V. Loginova

  DOI：10.1023/a:1011348804933

  日期：——

  A novel method for the selective oxidation of various types of sulfides to sulfoxides using chlorine dioxide as the oxidant is proposed.
• COMPATIBILIZED COMPOSITION, METHOD FOR THE FORMATION THEREOF, AND ARTICLE COMPRISING SAME
  申请人：SABIC Innovative Plastics IP B.V.

  公开号：EP2822998A1

  公开（公告）日：2015-01-14
• NEW CYCLOADDUCT PRECURSORS OF DIHALODIPHENYLSULFONES AND PREPARATIONS THEREOF
  申请人：RHODIA OPERATIONS

  公开号：EP3441393B1

  公开（公告）日：2020-03-18