decyl hypochlorite

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: decyl hypochlorite
• 英文别名: Decyl hypochlorite
• 化学式: C₁₀H₂₁ClO
• 分子量: 192.729
• InChiKey: DNQKSXCXTNTRPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  癸醇 在 ruthenium(IV) oxide sodium hypochlorite 作用下， 以 四氯化碳 、 水 为溶剂， 以2.5%的产率得到decyl hypochlorite
  参考文献：
  名称：

  Oxidation of primary alcohols to aldehydes catalyzed by ruthenium compounds

  摘要：

  The RuCl3 and RuO2.nH2O catalyzed oxidation of alkanes, aromatic fatty acids, alcohols, citronellol, and hydroxycitronellol by NaOCl was studied in the diphase system CCl4-aqueous NaOCl at pH 13-13.5. At 60-65-degrees-C, using 1-2 mole % of catalyst and a 1.5-fold molar excess of NaOCl, primary alkanols (hexanol-1, 2-ethylhexanol-1, decanol-1, hexadecanol-1) benzyl and 3-phenyl-propyl alcohols, and hydroxycitronellol are converted to the corresponding aldehydes with a selectivity of 70-90% and a yield of over 75%.

  DOI：

  10.1007/bf00959639

文献信息

• US7462610B2
  申请人：——

  公开号：US7462610B2

  公开（公告）日：2008-12-09
• Oxidation of primary alcohols to aldehydes catalyzed by ruthenium compounds
  作者：Yu. N. Ogibin、A. I. Ilovaiskii、G. I. Nikishin

  DOI：10.1007/bf00959639

  日期：1991.1

  The RuCl3 and RuO2.nH2O catalyzed oxidation of alkanes, aromatic fatty acids, alcohols, citronellol, and hydroxycitronellol by NaOCl was studied in the diphase system CCl4-aqueous NaOCl at pH 13-13.5. At 60-65-degrees-C, using 1-2 mole % of catalyst and a 1.5-fold molar excess of NaOCl, primary alkanols (hexanol-1, 2-ethylhexanol-1, decanol-1, hexadecanol-1) benzyl and 3-phenyl-propyl alcohols, and hydroxycitronellol are converted to the corresponding aldehydes with a selectivity of 70-90% and a yield of over 75%.