乙基紫精二高氯酸盐 | 36305-51-8

• 物质功能分类: 医药中间体 - 杂环化合物 - 吡啶类化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 乙基紫精二高氯酸盐
• 中文别名: 1,1'-二乙基-4,4'-联吡啶二高氯酸盐
• 英文名称: Ethyl viologen diperchlorate
• 英文别名: 1-ethyl-4-(1-ethylpyridin-1-ium-4-yl)pyridin-1-ium;diperchlorate
• CAS: 36305-51-8
• 化学式: C14H18Cl2N2O8
• 分子量: 413.2
• InChiKey: HTNDMKDAPWJPEX-UHFFFAOYSA-L

物化性质

• 熔点：
  270 °C (dec.)(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  -7.54
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  156
• 氢给体数：
  0
• 氢受体数：
  8

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S27,S36,S36/39
• 危险类别码：
  R20/21/22
• WGK Germany：
  3
• 海关编码：
  29349990

文献信息

• DYNAMIC RESPONSE COMPONENTS WITH AESTHETIC PROPERTIES
  申请人：Fundacion Cidetec

  公开号：EP3395927A1

  公开（公告）日：2018-10-31

  The composition comprises: (a) a compound of formula (I), (b) a polymeric matrix comprising a crosslinked polymer, the matrix having a viscosity value comprised from 1 x 10-3 to 1 x 1012 Pa·s, (c) a redox pair, and (d) a solvent, the compound of formula (I) and the redox pair being embedded in the polymeric matrix; and wherein: R1 and R2 are selected from: a (C1-C20)alkyl; (C1-C20)alkyl substituted; a 2 to 20-member heteroalkyl; a 2 to 20-member heteroalkyl substituted; (C2-C20)alkenyl; (C2-C20)alkenyl substituted; (C2-C20)alkynyl; (C2-C20)alkynyl substituted; and a known ring system; R3 to R10 are selected from hydrogen; (C1-C20)alkyl; (C1-C20)alkyl substituted; and nitro; and X is a monocharged anion. The present invention also relates to processes for its preparation and to devices comprising it. The multichromic composition shows a short switching time and low transmission in the most visible range, which makes it effective in blocking the whole visible radiation in smart windows.

  该组合物包括：(a)式(I)化合物，(b)由交联聚合物组成的聚合物基质，该基质的粘度值为 1 x 10-3 至 1 x 1012 Pa-s，(c)氧化还原对，以及(d)溶剂，式(I)化合物和氧化还原对嵌入聚合物基质中；并且其中：R1 和 R2 选自：(C1-C20)烷基；取代的(C1-C20)烷基；2 至 20 个成员的杂烷基；取代的 2 至 20 个成员的杂烷基；(C2-C20)烯基；取代的(C2-C20)烯基；(C2-C20)炔基；取代的(C2-C20)炔基；和已知的环系统；R3 至 R10 选自氢；(C1-C20)烷基；取代的(C1-C20)烷基；和硝基；和 X 是单充阴离子。 本发明还涉及其制备工艺和包含它的装置。 这种多色组合物在大部分可见光范围内的切换时间短、透射率低，因此能有效阻挡智能窗户中的全部可见光辐射。
• SEMI-ELECTROACTIVE MATERIAL CONTAINING ORGANIC COMPOUNDS HAVING POSITIVE OR NEGATIVE REDOX ACTIVITY, PROCESS AND KIT FOR MANUFACTURING THIS MATERIAL, ELECTRICALLY CONTROLLABLE DEVICE AND GLAZING UNITS USING SUCH A SEMI-ELECTROACTIVE MATERIAL
  申请人：Piroux Fabienne

  公开号：US20100172011A1

  公开（公告）日：2010-07-08

  This semi-electroactive material comprises a self-supporting polymer matrix, inserted into which is an electroactive system comprising or constituted by: at least one electroactive organic compound capable of being oxidized and/or of ejecting electrons and cations acting as compensation charges; or at least one electroactive organic compound capable of being reduced and/or of accepting electrons and cations acting as compensation charges; and ionic charges; and also a solubilization liquid for said semi-electroactive system, said liquid not dissolving said self-supporting polymer matrix, the latter being chosen to provide a percolation pathway for ionic charges, this allowing, under the action of a dielectric current, oxidation and reduction reactions of said electroactive organic compounds, which reactions are necessary to obtain a color contrast.
• ELECTROACTIVE MATERIAL CONTAINING ORGANIC COMPOUNDS HAVING POSITIVE AND NEGATIVE REDOX ACTIVITIES RESPECTIVELY, PROCESS AND KIT FOR MANUFACTURING THIS MATERIAL, ELECTRICALLY CONTROLLABLE DEVICE AND GLAZING UNITS USING SUCH AN ELECTROACTIVE MATERIAL
  申请人：Piroux Fabienne

  公开号：US20100208325A1

  公开（公告）日：2010-08-19

  This electroactive material comprises a self-supporting polymer matrix, inserted into which is an electroactive system comprising or constituted by: at least one electroactive organic compound capable of being reduced and/or of accepting electrons and cations acting as compensation charges; at least one electroactive organic compound capable of being oxidized and/or of ejecting electrons and cations acting as compensation charges; at least one of said aforementioned electroactive organic compounds being electrochromic in order to obtain a color contrast, ionic charges; and also a solubilization liquid for said electroactive system, said liquid not dissolving said self-supporting polymer matrix, the latter being chosen to provide a percolation pathway for ionic charges, this allowing, under the action of a dielectric current, oxidation and reduction reactions of said electroactive organic compounds, which reactions are necessary to obtain a color contrast.
• ELECTRICALLY CONTROLLABLE DEVICE HAVING IMPROVED TRANSPORTATION OF THE ELECTRIC CHARGES OF THE ELECTROACTIVE MEDIUM
  申请人：Piroux Fabienne

  公开号：US20110222138A1

  公开（公告）日：2011-09-15

  This device comprises the following stack of layers: a first substrate having a glass function (V 1 ); a first electronically conductive layer (TCC 1 ) with an associated current feed; an electroactive system (EA); a second electronically conductive layer (TCC 2 ) with an associated current feed; and a second substrate having a glass function (V 2 ). Each current feed is constituted by a continuous conductive strip ( 1 - 1 a; 2 - 2 a ) applied to the associated electronically conductive layer, said conductive strip being positioned over the entire perimeter or substantially over the entire perimeter of said layer (TCC 1 ; TCC 2 ) so as to strengthen the conductivity thereof and being connected to the electrical power supply via one of its ends.
• ELECTROACTIVE MATERIAL
  申请人：Solarski Samuel

  公开号：US20120307338A1

  公开（公告）日：2012-12-06

  An electroactive material, in the form of a self-supported layer, comprising: a matrix, which maintains the mechanical strength of the electroactive material; and an electroactive system, which is inserted in the matrix and comprises an electroactive organic compound (ea 1 + ), an electroactive organic compound (ea 2 ), a solubilization liquid (L), and ionic charges present as ionic salt or acid, wherein the electroactive compounds (ea 1 + & ea 2 ) and the ionic charges are in the solubilization liquid (L), wherein the matrix comprises a textile sheet (TS) or on a stack of sheets comprising the textile sheet (TS), and wherein the mineral fibers of the matrix and the solubilization liquid (L) have indices that are substantially equal, with a difference of at most 0.1. In addition, an electrically controllable device having variable optical properties, comprising the electroactive material.