辛基苯基磷酸氢酯 | 10581-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 辛基苯基磷酸氢酯
• 中文别名: 磷酸氢辛酯苯酯
• 英文名称: mono-octyl phenyl phosphoric acid
• 英文别名: Octyl Phenyl Phosphoric Acid；Octyl phenyl hydrogen phosphate
• CAS: 10581-14-3
• 化学式: C₁₄H₂₃O₄P
• 分子量: 286.308
• InChiKey: SDWUQIDETLBAIU-UHFFFAOYSA-N

物化性质

• 沸点：
  383.5±25.0 °C(Predicted)
• 密度：
  1.114±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  19
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• 海关编码：
  2919900090

反应信息

• 作为产物：
  描述：

  磷酸二苯酯 、 辛醇 、 ethyl (2E)-3-(furan-2-yl)acrylate 在 potassium carbonate 作用下， 以 十二烷 为溶剂， 反应 3.0h， 生成 二苯基辛基磷酸酯 、 辛基3-(呋喃-2-基)丙烯酸酯 、 辛基苯基磷酸氢酯 、 diphenyl 3-(2-furyl) acrylyl phosphate
  参考文献：
  名称：

  wittig-horner等的酯交换反应在活化过程中阴离子活化反应CH和OH异构碳酸盐碳酸钾/醇反应

  摘要：

  在多种醇中进行的维蒂希-霍纳反应伴随着所形成的α，β-乙烯酯的烷基的酯交换反应。这两个反应在同一反应介质中的发生受到以下行为的影响：i）醇（溶剂和试剂），ii）碳酸钾（试剂和催化剂）。发现发生两个反应的倾向取决于醇的极性。质子醇加快了Wittig-Horner和随后的酯交换反应的速度。尽管使用了非化学计量的碳酸钾，但两个反应都是定量的。原位再生在这些反应条件下，在非质子介质中观察到的固体碱的含量显着提高。为这两个反应提出的机理包括该再生过程。

  DOI：

  10.1016/s0040-4020(01)90785-9

文献信息

• Salts of triazinic compounds with phosphorus oxyacids, and use of said compounds in self-extinguishing polymeric compositions
  申请人：MINISTERO DELL' UNIVERSITA' E DELLA RICERCA SCIENTIFICA E TECNOLOGICA

  公开号：EP0537837A1

  公开（公告）日：1993-04-21

  Salts of triazinic compounds with phosphorus oxyacids, having the general formula (I): obtained by salifying oligomeric derivatives of 2,4, 6-triamino-1,3,5-triazine with a phosphorus-containing acid. The compounds with general formula (I) find use in particular as flame-retardant additives.

  三嗪化合物与含磷氧酸盐的盐，其一般式为(I)：通过用含磷酸盐对2,4,6-三氨基-1,3,5-三嗪的寡聚衍生物进行盐化而获得。具有一般式(I)的化合物特别用作阻燃添加剂。
• POLYCARBONATE RESIN COMPOSITION AND PROCESS FOR PRODUCING THE SAME
  申请人：Souma Minoru

  公开号：US20100256270A1

  公开（公告）日：2010-10-07

  There is provided a polycarbonate resin composition containing aluminum oxide nanoparticles and being capable of showing good moldability and retention heat stability and combining high transparency and dimensional stability with excellent mechanical properties. The polycarbonate resin composition is characterized by containing an organic acid and aluminum oxide and in that: the resin composition has a melt mass flow rate of 11 g/10 min or higher as measured according to JIS K 7210 under the conditions of a temperature of 280° C., a nominal load of 2.16 Kg and a nozzle dimension UD of 8/2; and a No.2 dumbbell-shaped specimen according to JIS K 7113 formed by heat-press molding the resin composition into a film of 0.2 mm in thickness and cutting the film has a breaking stress of 8 MPa or higher as measured under the conditions of a temperature of 23° C., a humidity of 50% RH and a tensile rate of 50 min/min. The organic acid is preferably an organic sulfonic acid having a carbon number of 8 or greater, more preferably the one containing an aromatic ring in the molecule.

  提供了一种聚碳酸酯树脂组合物，其中含有氧化铝纳米颗粒，能够展示良好的可成型性和保持热稳定性，并将高透明度和尺寸稳定性与优异的机械性能相结合。该聚碳酸酯树脂组合物的特征在于含有有机酸和氧化铝，并且：根据JIS K 7210的条件，在温度为280℃、名义负荷为2.16千克和喷嘴尺寸UD为8/2的条件下测量，该树脂组合物具有11克/10分钟或更高的熔体质量流动速率；根据JIS K 7113形成的第2号哑铃形试样，通过将树脂组合物热压成厚度为0.2毫米的薄膜并切割薄膜，在温度为23℃、湿度为50% RH和拉伸速率为50 min/min的条件下测量，其断裂应力为8兆帕或更高。有机酸最好是具有8个或更多碳原子的有机磺酸，更好的是分子中含有芳香环的有机磺酸。
• Thick suspension bait
  申请人：PACE NATIONAL CORPORATION

  公开号：EP0115664A1

  公开（公告）日：1984-08-15

  A semiliquid suspension bait has the texture and consistency of thin pudding so that it can be readily consumed by vermin, such as insects, rats, slugs and snails. The bait is a thick mud including a hydrophobic oleaginous base, an emulsifier, a thickener and an attractant, and is easily extruded from a plastic squeeze bottle or tube but is minimally absorbable by porous soil and resists erosion by rainwater and irrigation water. The thickener may include a combination of starch thickener and nonstarch thickener. The bait has a viscosity of between about 5,500 cp and 20,000 cp and when poured from an open mouthed container plops in gobs that string in parting, and when deposited in a mound onto a generally horizontal surface slumps sluggishly into a flattish blob.

  半液体悬浮诱饵具有稀布丁的质地和稠度，因此很容易被昆虫、老鼠、蛞蝓和蜗牛等害虫食用。饵料是一种稠泥，包括疏水性油基、乳化剂、增稠剂和引诱剂，很容易从塑料挤压瓶或管中挤出，但被多孔土壤吸收的可能性很小，并能抵抗雨水和灌溉水的侵蚀。增稠剂可包括淀粉增稠剂和非淀粉增稠剂的组合。饵料的粘度在 5,500 cp 到 20,000 cp 之间，从敞口容器中倒入时，饵料会 "噗噗 "作响，在分开时会串成一串，而堆放在大致水平的表面上时，则会缓慢地坍塌成扁平状。
• Water borne metallic coating composition
  申请人：NIPPON PAINT CO., LTD.

  公开号：EP0393579A1

  公开（公告）日：1990-10-24

  The present invention provides a water borne metallic coating composition which stably disperses a metallic pigment and provides good metallic appearance independently of coating conditions. The water borne coating composition of the present invention comprises a specific film forming polymer (I), a specific fluorine containing compound (II), a metallic pigment (III), a crosslinking agent (IV), a compound (V) selected from the group consisting of a phosphorus containing titanate coupling agent and a phosphoric mono- or di-ester of a C₁₁ - C₂₄ organic compound.

  本发明提供了一种水性金属涂料组合物，它能稳定地分散金属颜料，并提供良好的金属外观，不受涂覆条件的影响。本发明的水性涂料组合物包括特定成膜聚合物 (I)、特定含氟化合物 (II)、金属颜料 (III)、交联剂 (IV)、选自含磷钛酸酯偶联剂和 C₁₁ - C₂₄ 有机化合物的含磷单酯或双酯组的化合物 (V)。
• Self-extinguishing polymeric compositions
  申请人：MINISTERO DELL' UNIVERSITA' E DELLA RICERCA SCIENTIFICA E TECNOLOGICA

  公开号：EP0451807A2

  公开（公告）日：1991-10-16

  Described are self-extinguishing polymeric compositions comprising: a) from 90 to 40 parts by weight of thermoplastic polymer, or of polymer having elastomeric properties; b) from 10 to 60 parts by weight of one or more derivatives of 2,4,6-triamino-1,3,5-triazine which derivatives are salified and have the general formula (I): wherein the radicals R and R₁ to R₅ are as defined in claim 1. Optionally, said polymeric compositions may also comprise minor quantities of ammonium phosphates and/or amine phosphates.

  所述自熄灭聚合物组合物包括 a) 90 至 40 份（按重量计）热塑性聚合物或具有弹性特性的聚合物； b) 10 至 60 份（按重量计）2,4,6-三氨基-1,3,5-三嗪的一种或多种衍生物，这些衍生物经过盐析，具有通式 (I)： 其中 基 R 和 R₁ 至 R₅ 如权利要求 1 所定义。 可选地，所述聚合物组合物还可包含少量磷化铵和/或磷化胺。