sorbitol monodecanoate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: sorbitol monodecanoate
• 英文别名: sorbitol monocaprate；[(2S,3R,4R,5R)-2,3,4,5,6-pentahydroxyhexyl] decanoate
• 化学式: C₁₆H₃₂O₇
• 分子量: 336.426
• InChiKey: IMJOJMQZCFMNPL-OCVGTWLNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  23
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  127
• 氢给体数：
  5
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  山梨醇 、 正癸酸 在 lipase Candida sp. 99–125 作用下， 以 水 、 叔丁醇 为溶剂， 生成 [(2R,3R,4R,5S)-2,3,4,5,6-pentahydroxyhexyl] decanoate 、 sorbitol monodecanoate
  参考文献：
  名称：

  Enzymatic production and functional characterization of d-sorbitol monoesters with various fatty acids

  摘要：

  Sugar fatty acid esters are surfactants that are widely used in food, cosmetics, and pharmaceutical industries. In this study, enzymatic production of o-sorbitol monoesters with various fatty acids (C10-C18) was assessed. Reactions were performed in tert-butanol at 40 degrees C, catalyzed by Candida sp. 99-125 lipase. Dissolution of the substrates was found to be the limiting step of the reaction, and hence preheating was performed to increase the solubility of D-sorbitol. Thus, the yield of D-sorbitol palmitate was increased from 734 to 31.6 mM. The results demonstrated that the specific lipase preferred long-chain fatty acids. The surface-active properties. of the products were also determined. (C) 2015 Published by Elsevier B.V.

  DOI：

  10.1016/j.catcom.2015.09.010

文献信息

• Polyol ester insecticides
  申请人：——

  公开号：US20020192257A1

  公开（公告）日：2002-12-19

  The present invention relates to an environmentally acceptable synthesis method of polyol esters that produces no toxic by-products methods during the synthesis and the resultant esters are environmentally friendly insecticides. The present invention also provides for the use of these esters in a mixture as safe effective insecticides.

  本发明涉及一种环境友好的聚醇酯合成方法，该方法在合成过程中不产生有毒副产物，所得酯类是环保的杀虫剂。本发明还提供了将这些酯类作为安全有效杀虫剂混合使用的方法。
• METHODS FOR USING SUCROSE OCTANOATE TO CONTROL PESTS
  申请人：S.C. Johnson & Son, Inc.

  公开号：EP1622449B1

  公开（公告）日：2007-10-17
• EP1622449A1
  申请人：——

  公开号：EP1622449A1

  公开（公告）日：2006-02-08
• SURFACTANT COMPOSITION
  申请人：Imperial Chemical Industries Plc.

  公开号：EP1755545A1

  公开（公告）日：2007-02-28
• WIDE SPECTRUM INSECTICIDE AND MITICIDE COMPOSITION COMPRISING A SPINOSYN AND AT LEAST ONE FUTHER INSECTICIDE OR MITICIDE
  申请人：W. NEUDORFF GmbH KG

  公开号：EP1940227A2

  公开（公告）日：2008-07-09