2-trifluoromethyl acrylic acid 2-methoxyethyl ester

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-trifluoromethyl acrylic acid 2-methoxyethyl ester
• 英文别名: 2-Methoxyethyl 2-(trifluoromethyl)prop-2-enoate；2-methoxyethyl 2-(trifluoromethyl)prop-2-enoate
• 化学式: C₇H₉F₃O₃
• 分子量: 198.142
• InChiKey: OFLQKXVVGGZNDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  乙二醇甲醚 、 1,2-二溴-3,3,3-三氟丙烷 、 一氧化碳 在 bis-triphenylphosphine-palladium(II) chloride 三乙胺 作用下， 以 甲苯 为溶剂， 120.0 ℃ 、1.0 MPa 条件下， 反应 5.0h， 以68.6%的产率得到2-trifluoromethyl acrylic acid 2-methoxyethyl ester
  参考文献：
  名称：

  EP1637514

  摘要：

  公开号：

文献信息

• METHOD FOR PRODUCING FLUORINE-CONTAINING ACRYLATE
  申请人：Tosoh F-Tech, Inc.

  公开号：EP1637514A1

  公开（公告）日：2006-03-22

  A process for producing a fluorine-containing acrylic acid ester represented by CH2=C(Rf) (COOR) characterized in that 1-bromo-1-perfluoroalkylethene represented by CH2=CBr-Rf, or 1,2-dibromo-1-perfluoroalkylethane represented by CH2CBr-CHBr-Rf is allowed to react with an alcohol represented by ROH in the presence of a palladium catalyst, carbon monoxide, and two or more kinds of bases. The fluorine-containing acrylic acid ester is a useful compound having wide applications in materials for pharmaceuticals and functional polymers.

  一种以 CH2=C(Rf) (COOR) 为代表的含氟丙烯酸酯的生产工艺，其特征在于以 CH2=CBr-Rf 为代表的 1-溴-1-全氟烷基乙烯或以 CH2CBr-CHBr-Rf 为代表的 1,2-二溴-1-全氟烷基乙烷在钯催化剂、一氧化碳和两种或两种以上碱的存在下与以 ROH 为代表的醇反应。这种含氟丙烯酸酯是一种有用的化合物，在药物材料和功能聚合物中有着广泛的应用。
• Polymerizable compound and optically anisotropic body
  申请人：DIC Corporation

  公开号：US10723952B2

  公开（公告）日：2020-07-28

  The present invention provides a polymerizable compound that reduces, for example, the likelihood of crystals precipitating in a polymerizable composition including the polymerizable compound and enables the polymerizable composition to have high preservation stability and a polymerizable composition including the polymerizable compound which reduces the likelihood of inconsistencies being formed in a film-like polymer produced by polymerizing the polymerizable composition. Also provided are a polymer produced by polymerizing the polymerizable composition and an optically anisotropic body including the polymer. The present invention provides the compound represented by General Formula (I), a composition including the compound, a polymer produced by polymerizing the composition, and an optically anisotropic body including the polymer.

  本发明提供了一种可聚合化合物，该化合物可降低包括该可聚合化合物的可聚合组合物中晶体析出的可能性等，并使该可聚合组合物具有较高的保存稳定性；还提供了一种包括该可聚合化合物的可聚合组合物，该组合物可降低通过聚合该可聚合组合物生产的膜状聚合物中形成不一致性的可能性。本发明还提供了通过聚合该可聚合组合物生产的聚合物和包括该聚合物的光学各向异性体。本发明提供通式（I）代表的化合物、包括该化合物的组合物、通过聚合该组合物生产的聚合物以及包括该聚合物的光学各向异性体。
• Solid electrolyte composition, solid electrolyte-containing sheet, all-solid state secondary battery, and methods for manufacturing solid electrolyte composition, solid electrolyte-containing sheet, all-solid state secondary battery
  申请人：FUJIFILM Corporation

  公开号：US10833351B2

  公开（公告）日：2020-11-10

  Provided are a solid electrolyte composition containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and a compound having an anionic polymerizable functional group, a solid electrolyte-containing sheet containing an inorganic solid electrolyte having a conductivity for ions of metals belonging to Group I or II of the periodic table and an anionic polymer which bonds to the inorganic solid electrolyte, and an all-solid state secondary battery, and methods for manufacturing the solid electrolyte composition, the solid electrolyte-containing sheet, and the all-solid state secondary battery.

  本发明提供了一种固体电解质组合物，该组合物含有对属于元素周期表第 I 组或第 II 组的金属离子具有导电性的无机固体电解质和具有阴离子可聚合官能团的化合物、一种含固体电解质的薄片，其中含有对属于元素周期表第I或第II族的金属离子具有导电性的无机固体电解质和一种与无机固体电解质结合的阴离子聚合物，以及一种全固态二次电池，以及制造该固体电解质组合物、含固体电解质的薄片和全固态二次电池的方法。
• Method for producing fluorine-containing acrylate
  申请人：Fuchikami Takamasa

  公开号：US20060122423A1

  公开（公告）日：2006-06-08

  A process for producing a fluorine-containing acrylic acid ester represented by CH 2 ═C(Rf)(COOR) characterized in that 1-bromo-1-perfluoroalkylethene represented by CH 2 ═CBr—Rf, or 1,2-dibromo-1-perfluoroalkylethane represented by CH 2 CBr—CHBr—Rf is allowed to react with an alcohol represented by ROH in the presence of a palladium catalyst, carbon monoxide, and two or more kinds of bases. The fluorine-containing acrylic acid ester is a useful compound having wide applications in materials for pharmaceuticals and functional polymers.

  一种生产以 CH 2 ═C(Rf)(COOR)为代表的含氟丙烯酸酯的工艺，其特征在于以CH 2 ═CBr-Rf，或 1,2-二溴-1-全氟烷基乙烷，其代表符号为 CH 2 在钯催化剂、一氧化碳和两种或两种以上碱的存在下，CBr-CHBr-Rf 与 ROH 所代表的醇发生反应。这种含氟丙烯酸酯是一种有用的化合物，在药物材料和功能聚合物中有着广泛的应用。
• EP1637514B1
  申请人：——

  公开号：EP1637514B1

  公开（公告）日：2014-05-07