neryl methacrylate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: neryl methacrylate
• 英文别名: Neryl methacrylate；[(2Z)-3,7-dimethylocta-2,6-dienyl] 2-methylprop-2-enoate
• 化学式: C₁₄H₂₂O₂
• 分子量: 222.327
• InChiKey: DWJIEXRXQKFNAB-LCYFTJDESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,7-二甲基-2,6-辛二烯-1-醇 、 2,3-Butanedione monooxime methacrylate 在 porcine pancreatic lipase 作用下， 以 异丙醚 为溶剂， 反应 16.0h， 生成 neryl methacrylate 、 geranyl methacrylate
  参考文献：
  名称：

  Lipase-catalyzed synthesis of geranyl methacrylate by transesterification: study of reaction parameters

  摘要：

  The methacrylate ester or geraniol was synthesized using various lipases, such as porcine pancreatic lipase (PPL). Candida rugosu lipase (CRL) and Pseudomonas cepacia lipase (Arnano-PS) as catalysts. The effects of reaction parameters such as type and amount of lipase, solvent. temperature and acylating agent on the conversion of geraniol to geranyl methacrylate was studied. The monomer obtained Could be used in the synthesis of controlled release pet-fume. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)00926-7

文献信息

• Photochromic composition
  申请人：——

  公开号：US20040173782A1

  公开（公告）日：2004-09-09

  A photochromic composition and a coating composition comprising a molecular compound of a chromene compound and an aromatic compound. The photochromic composition provides a photochromic optical material as a cured product and the coating composition is applied to a lens substrate and cured to provide a photochromic optical material. The above molecular compound is also provided.

  一种光致变色组合物和涂层组合物，包括一种色素化合物和一种芳香化合物的分子化合物。光致变色组合物提供一种光致变色光学材料作为固化产品，涂层组合物被应用于镜片基底并固化以提供光致变色光学材料。上述分子化合物也被提供。
• CURABLE COMPOSITION
  申请人：TOKUYAMA CORPORATION

  公开号：EP1130038A1

  公开（公告）日：2001-09-05

  A photochromic cured product exhibiting favorable photochromic properties such as a high color density and a large fading rate, and excellent base member properties such as a high hardness, a high heat resistance and a high impact resistance. A curable composition contains a polymerizable monomer which exhibits the L-scale Rockwell hardness of not larger than 40, a bifunctional polymerizable monomer which exhibits the L-scale Rockwell hardness of not smaller than 60, a polyfunctional polymerizable monomer which exhibits the L-scale Rockwell hardness of not smaller than 60, and a photochromic compound.

  一种光致变色固化产品，具有良好的光致变色特性，如色彩密度高和褪色率大，以及优异的基材特性，如硬度高、耐热性高和抗冲击性高。一种可固化组合物包含一种可聚合单体（其 L 级洛氏硬度不大于 40）、一种双官能团可聚合单体（其 L 级洛氏硬度不小于 60）、一种多官能团可聚合单体（其 L 级洛氏硬度不小于 60）和一种光致变色化合物。
• CURABLE COMPOSITION AND PHOTOCHROMIC CURED ARTICLE
  申请人：TOKUYAMA CORPORATION

  公开号：EP1291388A1

  公开（公告）日：2003-03-12

  A photochromic cured product exhibiting excellent photochromic properties such as a high color density and a high fading rate, as well as excellent base material properties such as a high hardness and a large heat resistance.

  一种光致变色固化产品，具有高色彩密度和高褪色率等优异的光致变色性能，以及高硬度和高耐热性等优异的基材性能。
• CURABLE COMPOSITION COMPRISING PHOTOCHROMIC COMPOUND
  申请人：TOKUYAMA CORPORATION

  公开号：EP1293522A1

  公开（公告）日：2003-03-19

  A photochromic cured product which has excellent photochromism such as high color density and high fading speed, excellent adhesion to a hard coat and high striping work efficiency. This cured product is obtained by polymerizing and curing a curable composition which comprises (A) a polyfunctional polymerizable monomer such as trimethylolpropane trimethacrylate, (B) a silyl monomer such as γ-methacryloyloxypropyl trimethoxysilane, (C) another radically polymerizable monomer and (D) a photochromic compound. As for the contents of the polymerizable monomers, the content of the component (A) is 1 to 50 wt%, the content of the component (B) is 0.5 to 20 wt% and the balance consists of the component (C) based on the total of the components (A), (B) and (C). The photochromic compound (D) is contained in an amount of 0.0001 to 10 parts by weight based on 100 parts by weight of the total of the components (A), (B) and (C).

  一种光致变色固化产品，具有优异的光致变色性能，如色彩密度高、褪色速度快、对硬涂层的附着力优异以及剥离工作效率高。这种固化产品是通过聚合固化一种可固化组合物获得的，该组合物包括：（A）一种多官能团可聚合单体，如三羟甲基丙烷三甲基丙烯酸酯；（B）一种硅基单体，如γ-甲基丙烯酰氧基丙基三甲氧基硅烷；（C）另一种可辐射聚合单体；（D）一种光致变色化合物。至于可聚合单体的含量，组分（A）的含量为 1 至 50 wt%，组分（B）的含量为 0.5 至 20 wt%，余量为组分（C），即组分（A）、（B）和（C）的总和。光致变色化合物 (D) 的含量为 0.0001 至 10 重量份（以 100 重量份的组分 (A)、(B) 和 (C) 的总和为基准）。
• PHOTOCHROMIC COMPOSITION
  申请人：Tokuyama Corporation

  公开号：EP1535980A1

  公开（公告）日：2005-06-01

  A photochromic composition and a coating composition comprising a molecular compound of a chromene compound and an aromatic compound. The photochromic composition provides a photochromic optical material as a cured product and the coating composition is applied to a lens substrate and cured to provide a photochromic optical material. The above molecular compound is also provided.

  一种光致变色组合物和一种涂层组合物，其中包含一种铬化合物和一种芳香族化合物的分子化合物。光致变色组合物以固化产品的形式提供光致变色光学材料，涂层组合物涂在镜片基底上并固化以提供光致变色光学材料。还提供了上述分子化合物。