乙酸乙氧基甲酯 | 32665-19-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 乙酸乙氧基甲酯
• 英文名称: ethoxymethyl acetate
• CAS: 32665-19-3
• 化学式: C₅H₁₀O₃
• 分子量: 118.133
• InChiKey: NDMXSCGMYOVVJE-UHFFFAOYSA-N

物化性质

• 沸点：
  123.2±23.0 °C(Predicted)
• 密度：
  0.976±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.4
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  乙酸乙氧基甲酯 、 苯胺 反应 6.0h， 生成 N-乙酰苯胺
  参考文献：
  名称：

  Grapov, A. F.; Remizov, A. S., Journal of general chemistry of the USSR, 1983, vol. 53, # 7, p. 1390 - 1392

  摘要：

  DOI：
• 作为产物：
  描述：

  sodium acetate 、 氯甲基乙醚 以95%的产率得到乙酸乙氧基甲酯
  参考文献：
  名称：

  Pihlaja, Kalevi; Lampi, Aija, Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1986, vol. 40, # 3, p. 196 - 199

  摘要：

  DOI：

文献信息

• METHOD OF OBTAINING POLYOXYGENATED ORGANIC COMPOUNDS
  申请人：CONSEJO SUPERIOR DE INVESTIGACIONES CIENT FICAS

  公开号：EP1767515A1

  公开（公告）日：2007-03-28

  The invention relates to a method of obtaining polyoxygenated organic compounds. The inventive method is characterized in that it comprises the oxidation reaction of a diether, preferably an acetal, with an oxygen source, in the presence of: one or more radical initiating agents, one or more additives that generate a basic reaction medium, and one or more catalysts.

  本发明涉及一种获取多氧化有机化合物的方法。该方法的特点在于，它包括在一个或多个引发自由基反应的剂、一个或多个生成碱性反应介质的添加剂和一个或多个催化剂的存在下，将二元醚，优选为缩醛醚，与氧源进行氧化反应。
• Farren et al., Journal of the American Chemical Society, 1925, vol. 47, p. 2422
  作者：Farren et al.

  DOI：——

  日期：——
• Baker, Journal of the American Chemical Society, 1938, vol. 60, p. 2674
  作者：Baker

  DOI：——

  日期：——
• Kinetic Studies on the Reactions of Hydroxyl Radicals with a Series of Alkoxy Esters
  作者：S. M. O'Donnel、H. W. Sidebottom、J. C. Wenger、A. Mellouki、G. Le Bras

  DOI：10.1021/jp048782w

  日期：2004.9.1

  Rate coefficients for the gas-phase reactions of hydroxyl radicals with a series of alkoxy esters of structure RC(O)O(CH2)(n)OR', where R = H, CH3, R' = CH3, C2H5, and n = 1-2, have been determined with use of relative and absolute rate methods. Relative rate measurements were performed in a Teflon reaction chamber at 298 +/- 2 K and atmospheric pressure. Absolute rate measurements were made with pulsed laser photolysislaser induced fluorescence over the temperature range 263-372 K at pressures of similar to100 Torr. The kinetic data are used to derive Arrhenius expressions for the reactions and tropospheric lifetimes for the alkoxy esters. The reactivity of the alkoxy esters is discussed in light of the current understanding of the atmospheric chemistry of oxygenated organic compounds.
• Salomaa, Acta Chemica Scandinavica (1947), 1957, vol. 11, p. 239,240,243
  作者：Salomaa

  DOI：——

  日期：——