1,3,5-adamantanetricarboxylic acid N,N-diethylamide[1,3,5-tris(N,N-diethylcarbamoyl)adamantane]

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1,3,5-adamantanetricarboxylic acid N,N-diethylamide[1,3,5-tris(N,N-diethylcarbamoyl)adamantane]
• 英文别名: 1,3,5-tris(diethylcarbamoyl)adamantane；1-N,1-N,3-N,3-N,5-N,5-N-hexaethyladamantane-1,3,5-tricarboxamide
• 化学式: C₂₅H₄₃N₃O₃
• 分子量: 433.635
• InChiKey: XRXDSJGEIDQTJM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  31
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  60.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  adamantan-1,3,5-tricarbonyl trichloride 、 二乙胺 在 吡啶 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 2.0h， 以85%的产率得到1,3,5-adamantanetricarboxylic acid N,N-diethylamide[1,3,5-tris(N,N-diethylcarbamoyl)adamantane]
  参考文献：
  名称：

  Adamantanetricarboxylic acid derivatives

  摘要：

  一种超坚酸衍生物由以下式（1）表示：其中X是氢原子或烃基；R1、R2和R3可以相同也可以不同，分别是一个羧基，可能被保护基保护，或者是羰基卤化物基团，其中至少一个是被保护基保护的羧基，或者是羰基卤化物基团。

  公开号：

  US20040242923A1

文献信息

• Dielectric films and materials therefor
  申请人：——

  公开号：US20040175858A1

  公开（公告）日：2004-09-09

  A material for dielectric films is a polymerizable composition containing an organic solvent, and an adamantanepolycarboxylic acid derivative represented by following Formula (1): 1 wherein X is hydrogen atom, a hydrocarbon group or R 4 ; R 1 , R 2 , R 3 and R 4 and are each independently a protected or unprotected carboxyl group, etc.; and Y 1 , Y 2 , Y 3 and Y 4 are each independently a single bond or a bivalent aromatic cyclic group; and an aromatic polyamine derivative represented by following Formula ( 2 ): 2 wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R 5 , R 6 , R 7 and R 8 are each a substituent bound to Ring Z and are each independently a protected or unprotected amino group, etc., dissolved in the organic solvent.

  一种用于制备介电薄膜的材料是一种可聚合的组合物，包含有机溶剂和由以下式子（1）表示的金刚烷多羧酸衍生物：1其中X是氢原子、烃基或R4；R1、R2、R3和R4各自独立地是保护或未保护的羧基等；Y1、Y2、Y3和Y4各自独立地是单键或双价芳香环基团；以及由以下式子（2）表示的芳香族多胺衍生物：2其中环Z是单环或多环芳香环；R5、R6、R7和R8各自是结合在环Z上的取代基，各自独立地是保护或未保护的氨基等，溶解在有机溶剂中。
• Dielectric films and materials thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1462471A1

  公开（公告）日：2004-09-29

  A material for dielectric films is a polymerizable composition containing an organic solvent, and an adamantanepolycarboxylic acid derivative represented by following Formula (1): wherein X is hydrogen atom, a hydrocarbon group or R4; R1, R2, R3 and R4 and are each independently a protected or unprotected carboxyl group, etc.; and Y1, Y2, Y3 and Y4 are each independently a single bond or a bivalent aromatic cyclic group; and an aromatic polyamine derivative represented by following Formula (2): wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R5, R6, R7 and R8 are each a substituent bound to Ring Z and are each independently a protected or unprotected amino group, etc., dissolved in the organic solvent.

  一种用于电介质薄膜的材料是一种可聚合的组合物，其中含有一种有机溶剂和一种金刚烷聚羧酸衍生物，由下式（1）表示： 其中 X 为氢原子、烃基或 R4；R1、R2、R3 和 R4 各自独立地为受保护或未受保护的羧基等；Y1、Y2、Y3 和 Y4 各自独立地为单键或二价芳香环基；以及由下式（2）表示的芳香族多胺衍生物： 其中环 Z 是单环或多环芳香环；R5、R6、R7 和 R8 各自是与环 Z 结合的取代基，且各自独立地是受保护或未受保护的氨基等，溶解在有机溶剂中。
• AROMATIC POLYAMINE DERIVATIVE
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1681284A1

  公开（公告）日：2006-07-19

  Aromatic polyamine derivatives of this invention are represented by following Formula (1): wherein Ring Z represents a monocyclic or polycyclic aromatic ring; Ra, Rb, Rc, and Rd are each a substituent bonded to Ring Z, where Ra and Rb are the same as or different from each other and each represent a protected or unprotected amino group, and Rc and Rd are the same as or different from each other and each represent a protected or unprotected amino group, a protected or unprotected hydroxy group, or a protected or unprotected mercapto group, and wherein at least one of Ra, Rb, Rc, and Rd represents an amino group protected by an alkylidene group.

  本发明的芳香族多胺衍生物由下式（1）表示： 其中环 Z 代表单环或多环芳香环；Ra、Rb、Rc 和 Rd 各自是与环 Z 键合的取代基，其中 Ra 和 Rb 彼此相同或不同，各自代表受保护或未受保护的氨基，Rc 和 Rd 彼此相同或不同，各自代表受保护或未受保护的氨基、受保护或未受保护的羟基或受保护或未受保护的巯基，且其中 Ra、Rb、Rc 和 Rd 中至少有一个代表受亚烷基保护的氨基。
• PREPOLYMER, PREPOLYMER COMPOSITION, HIGH MOLECULAR WEIGHT POLYMER HAVING STRUCTURE CONTAINING HOLE AND ELECTRICALLY INSULATING FILM
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP1683822A1

  公开（公告）日：2006-07-26

  A prepolymer is a reaction product of a compound A and a compound B, in which the compounds A and B each have two or more functional groups or sets of functional groups in one molecule and are capable of undergoing polymerization as a result of binding of the functional groups or sets of functional groups of one compound with the functional groups or sets of functional groups of the other compound to thereby form a high-molecular-weight polymer with a porous structure. The prepolymer has a weight-average molecular weight of about 200 to about 100000. The functional groups or sets of functional groups of the compound A are preferably each a carboxyl group or an amino group, and the functional groups or sets of functional groups of the compound B are preferably two amino groups, an amino group and a hydroxyl group, an amino group and a mercapto group, or two carboxyl groups.

  预聚物是一种化合物 A 和一种化合物 B 的反应产物，其中化合物 A 和 B 在一个分子中各自具有两个或两个以上的官能团或官能团组，并且能够通过一种化合物的官能团或官能团组与另一种化合物的官能团或官能团组的结合而发生聚合，从而形成具有多孔结构的高分子量聚合物。预聚物的重量平均分子量约为 200 至 100000。化合物 A 的官能团或官能团组最好各为一个羧基或一个氨基，化合物 B 的官能团或官能团组最好为两个氨基、一个氨基和一个羟基、一个氨基和一个巯基或两个羧基。
• Aromatic polyamine derivative
  申请人：Nagano Shinya

  公开号：US20070032556A1

  公开（公告）日：2007-02-08

  Aromatic polyamine derivatives of this invention are represented by following Formula (1): wherein Ring Z represents a monocyclic or polycyclic aromatic ring; R a , R b , R c , and R d are each a substituent bonded to Ring Z, where R a and R b are the same as or different from each other and each represent a protected or unprotected amino group, and R c and R d are the same as or different from each other and each represent a protected or unprotected amino group, a protected or unprotected hydroxy group, or a protected or unprotected mercapto group, and wherein at least one of R a , R b , R c , and R d represents an amino group protected by an alkylidene group.