2,3-bis[4-(N-phenylbenzeamino)phenyl]benzo[g]quinoxaline

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,3-bis[4-(N-phenylbenzeamino)phenyl]benzo[g]quinoxaline
• 英文别名: N,N-diphenyl-4-[3-[4-(N-phenylanilino)phenyl]benzo[g]quinoxalin-2-yl]aniline
• 化学式: C₄₈H₃₄N₄
• 分子量: 666.825
• InChiKey: CJHKPIYLMUYQQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.9
• 重原子数：
  52
• 可旋转键数：
  8
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  32.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,3-二氨基萘 在 2-双环己基膦-2',6'-二甲氧基联苯 、 tris-(dibenzylideneacetone)dipalladium(0) 、 溶剂黄146 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 7.0h， 生成 2,3-bis[4-(N-phenylbenzeamino)phenyl]benzo[g]quinoxaline
  参考文献：
  名称：

  Synthesis, Photophysical, Electrochemical and Thermal Studies of Triarylamines based on benzo[g]quinoxalines

  摘要：

  合成了一系列新型的双极性和非平面化合物，这些化合物具有电子受体苯并[g]吡咯嗪和各种电子供体三芳胺单元，产率良好并已完全表征。描述了合成化合物的光物理、 electrochemical 及热性能。合成分子的光致发光特性受外围胺类的影响。这些衍生物具有高斯托克斯位移、低能带隙，其国际照明委员会（CIE）坐标位于色度图的绿-黄区域。离子化势和电子亲和能被发现分别在5.11–5.60 eV和2.77–2.93 eV范围内，且与常用孔导体相当。热研究也显示，这些合成分子具有良好的热稳定性，5%和10%重量损失温度分别在200到355°C和268到442°C之间。

  DOI：

  10.1007/s12039-015-0904-0

文献信息

• Quinoxaline Derivative, and Organic Semiconductor Device, Electric Field Light Emitting Device, and Electronic Device Which Have the Same
  申请人：Shitagaki Satoko

  公开号：US20100069636A1

  公开（公告）日：2010-03-18

  Target is to provide an organic compound material having a bipolar character. A quinoxaline derivative represented by a general formula (1) is provided. In the formula, R 1 -R 12 each independently represents a hydrogen atom, a halogen atom, a lower alkyl group, an alkoxy group, an acyl group, a nitro group, a cyano group, an amino group, a dialkylamino group, a diarylamino group, a vinyl group, an aryl group, or a heterocyclic residue group. R 9 and R 10 , R 10 and R 11 , and R 11 and R 12 are each independent or respectively mutually bonded to form an aromatic ring. Ar 1 -Ar 4 each independently represents an aryl group or a heterocyclic residue group. Ar 1 , Ar 2 , Ar 3 and Ar 4 are each independent or Ar l and Ar 2 , and Ar 3 and Ar 4 are respectively mutually bonded directly, or Ar 1 and Ar 3 , and Ar 3 and Ar 4 are bonded via oxygen (O), sulfur (S) or a carbonyl group.
• Quinoxaline Derivative, and Organic Semiconductor Device, Electric Field Light Emitting Device, and Electronic Device Which have the Same
  申请人：SHITAGAKI Satoko

  公开号：US20120286257A1

  公开（公告）日：2012-11-15

  Target is to provide an organic compound material having a bipolar character. A quinoxaline derivative represented by a general formula (1) is provided. In the formula, R 1 -R 12 each independently represents a hydrogen atom, a halogen atom, a lower alkyl group, an alkoxy group, an acyl group, a nitro group, a cyano group, an amino group, a dialkylamino group, a diarylamino group, a vinyl group, an aryl group, or a heterocyclic residue group. R 9 and R 10 , R 10 and R 11 , and R 11 and R 12 are each independent or respectively mutually bonded to form an aromatic ring. Ar 1 -Ar 4 each independently represents an aryl group or a heterocyclic residue group. Ar 1 , Ar 2 , Ar 3 and Ar 4 are each independent or Ar 1 and Ar 2 , and Ar 3 and Ar 4 are respectively mutually bonded directly, or Ar 1 and Ar 3 , and Ar 3 and Ar 4 are bonded via oxygen (O), sulfur (S) or a carbonyl group.
• US7601435B2
  申请人：——

  公开号：US7601435B2

  公开（公告）日：2009-10-13
• US8231984B2
  申请人：——

  公开号：US8231984B2

  公开（公告）日：2012-07-31
• US8758905B2
  申请人：——

  公开号：US8758905B2

  公开（公告）日：2014-06-24