N-benzyl-4-nitro-N-phenylbenzamide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-benzyl-4-nitro-N-phenylbenzamide
• 英文别名: 4-nitro-benzoic acid-(N-benzyl-anilide)；4-Nitro-benzoesaeure-(N-benzyl-anilid)
• 化学式: C₂₀H₁₆N₂O₃
• 分子量: 332.359
• InChiKey: QFYBLCAEBPADFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  66.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-benzyl-4-nitro-N-phenylbenzamide 在 tin(II) chloride dihdyrate 作用下， 以 乙酸乙酯 为溶剂， 以91%的产率得到4-amino-N-benzyl-N-phenylbenzamide
  参考文献：
  名称：

  Conformational studies of tertiary oligo-m-benzanilides and oligo-p-benzanilides in solution

  摘要：

  A series of oligo-m- and p-benzanilides were made and their conformations in solution were studied by NMR. In most cases, conformational mixtures were observed as soon as three or more monomers were incorporated into the oligomer. Some crystal structures were obtained, which indicated that helical conformations were adopted in the solid state. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.06.037
• 作为产物：
  描述：

  苯甲基苯胺 在 potassium permanganate 、 potassium carbonate 作用下， 生成 N-benzyl-4-nitro-N-phenylbenzamide
  参考文献：
  名称：

  Forrest et al., Journal of the Chemical Society, 1951, p. 303

  摘要：

  DOI：

文献信息

• Conformational studies of tertiary oligo-m-benzanilides and oligo-p-benzanilides in solution
  作者：Laurent Chabaud、Jonathan Clayden、Madeleine Helliwell、Abigail Page、James Raftery、Lluís Vallverdú

  DOI：10.1016/j.tet.2010.06.037

  日期：2010.8

  A series of oligo-m- and p-benzanilides were made and their conformations in solution were studied by NMR. In most cases, conformational mixtures were observed as soon as three or more monomers were incorporated into the oligomer. Some crystal structures were obtained, which indicated that helical conformations were adopted in the solid state. (C) 2010 Elsevier Ltd. All rights reserved.
• Forrest et al., Journal of the Chemical Society, 1951, p. 303
  作者：Forrest et al.

  DOI：——

  日期：——