(Z)-1-(1H-benzo[d][1,2,3]triazol-1-yl)octadec-9-en-1-one

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 英文名称: (Z)-1-(1H-benzo[d][1,2,3]triazol-1-yl)octadec-9-en-1-one
• 英文别名: (Z)-1-(benzotriazol-1-yl)octadec-9-en-1-one
• 化学式: C₂₄H₃₇N₃O
• 分子量: 383.577
• InChiKey: YFSYFAJGRGDWQT-KTKRTIGZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  28
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  47.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (S)-4-(tert-butoxy)-2-hydroxy-4-oxobutanoic acid 、 (Z)-1-(1H-benzo[d][1,2,3]triazol-1-yl)octadec-9-en-1-one 在 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 48.0h， 以850 mg的产率得到(S,Z)-4-(tert-butoxy)-2-(oleoyloxy)-4-oxobutanoic acid
  参考文献：
  名称：

  METHODS AND COMPOSITIONS FOR PREVENTING OPIOID ABUSE

  摘要：

  提供了耐滥用的阿片类化合物、药物输送系统、含有阿片类药物与化学基团共价结合的制药组合物。还提供了将活性成分输送给受试者的方法以及预防阿片类药物滥用的方法。

  公开号：

  US20160326182A1
• 作为产物：
  描述：

  T406石油添加剂 、 油酸 在 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 生成 (Z)-1-(1H-benzo[d][1,2,3]triazol-1-yl)octadec-9-en-1-one
  参考文献：
  名称：

  METHODS AND COMPOSITIONS FOR PREVENTING OPIOID ABUSE

  摘要：

  提供了耐滥用的阿片类化合物、药物输送系统、含有阿片类药物与化学基团共价结合的制药组合物。还提供了将活性成分输送给受试者的方法以及预防阿片类药物滥用的方法。

  公开号：

  US20160326182A1

文献信息

• METHOD FOR PRODUCING METAL PARTICLE DISPERSION, CONDUCTIVE INK USING METAL PARTICLE DISPERSION PRODUCED BY SUCH METHOD, AND CONDUCTIVE COATING FILM
  申请人：Toyo Ink Mfg. Co., Ltd

  公开号：EP1952918A1

  公开（公告）日：2008-08-06

  Disclosed is a method for producing a metal particle dispersion wherein a metal compound is reduced by using carbodihydrazide represented by the formula (1) below or a polybasic acid polyhydrazide represented by the formula (2) below (wherein R represents an n-valent polybasic acid residue) in a liquid medium. By reducing the metal compound in the presence of a compound having a function preventing discoloration of the metal, there can be obtained a metal particle dispersion having excellent discoloration preventing properties. Metal particles produced by such methods have a uniform particle diameter and are excellent in dispersion stability. By using a conductive resin composition or conductive ink containing a metal particle dispersion obtained by such production methods, there can be formed a conductive coating film, such as a conductive circuit or an electromagnetic layer, having good characteristics.

  本发明公开了一种生产金属颗粒分散液的方法，该方法通过在液体介质中使用下式 (1) 所代表的碳二酰肼或下式 (2) 所代表的多基酸多酰肼（其中 R 代表正价多基酸残基）还原金属化合物。通过在具有防止金属褪色功能的化合物存在下还原金属化合物，可获得具有优异防褪色性能的金属颗粒分散液。通过这种方法制得的金属颗粒具有均匀的颗粒直径和出色的分散稳定性。使用含有通过这种生产方法获得的金属颗粒分散体的导电树脂组合物或导电墨水，可以形成具有良好特性的导电涂膜，例如导电电路或电磁层。
• COLORED METALLIC PIGMENT, PROCESS FOR PRODUCING THE SAME, AND COATING COMPOSITION AND COSMETIC PREPARATION COMPRISING SAID COLORED METALLIC PIGMENT
  申请人：TOYO ALUMINIUM KABUSHIKI KAISHA

  公开号：EP1990377A1

  公开（公告）日：2008-11-12

  This invention provides a colored metallic pigment, which can develop a variety of colors and varied interference colors while maintaining good lightfastness, weatherfastness and hiding power, a process for producing the same, a coating composition containing the colored metallic pigment and capable of providing a coating film having excellent finished appearance, and a cosmetic preparation containing the colored metallic pigment, having excellent hiding power, and capable of providing sharp hue. The colored metallic pigment comprises at least a metallic pigment, an amorphous silicon oxide film layer provided on the surface of the metallic pigment, a metal layer provided on the surface of the amorphous silicon oxide film layer, and metallic particles provided on the surface of the metal layer. The metallic particles are provided so as to directly cover a part of the surface of the metal layer. In the colored metallic pigment, the metal layer preferably comprises at least one metal selected from Sn, Pd, Pt and Au. The metallic particle preferably comprises at least one metal selected from Cu, Ni and Ag.

  本发明提供了一种彩色金属颜料，它能在保持良好的耐光性、耐候性和遮盖力的同时，显现出多种颜色和各种干扰色；还提供了一种生产彩色金属颜料的工艺；一种含有该彩色金属颜料并能提供具有良好成品外观的涂膜的涂料组合物；以及一种含有该彩色金属颜料、具有良好遮盖力并能提供鲜明色调的化妆品制剂。彩色金属颜料至少包括金属颜料、设置在金属颜料表面的非晶氧化硅薄膜层、设置在非晶氧化硅薄膜层表面的金属层以及设置在金属层表面的金属颗粒。金属颗粒的设置是为了直接覆盖金属层的部分表面。在有色金属颜料中，金属层最好包括至少一种选自 Sn、Pd、Pt 和 Au 的金属。金属颗粒最好包括至少一种选自铜、镍和银的金属。
• FUNCTIONAL FLUID
  申请人：Chiyoda Chemical Co. Ltd

  公开号：EP2159274A1

  公开（公告）日：2010-03-03

  Provided is a functional fluid including a tetrazole compound (A) and a base oil (B), which may further include a triazole compound (C).

  本发明提供了一种功能性流体，包括四唑化合物（A）和基础油（B），其中可进一步包括三唑化合物（C）。
• CURABLE SILICONE COMPOSITION, AND OPTICAL SEMICONDUCTOR DEVICE
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP3059285A1

  公开（公告）日：2016-08-24

  The present invention provides a curable silicone composition for forming a cured product which inhibits the discoloration of silver electrodes or a silver-plated substrate in an optical semiconductor device due to a sulfur-containing gas, the curable silicone composition comprising: (A) an organopolysiloxane having at least two silicon-bonded alkenyl groups per molecule; (B) an organohydrogenpolysiloxane having at least two silicon-bonded hydrogen atoms per molecule; (C) an organic compound having an organic value of at least 175 in an organic conceptual diagram and having a specific group; and (D) a hydrosilylation reaction catalyst. In addition, the present invention provides an optical semiconductor device in which silver electrodes or a silver-plated substrate of an optical semiconductor device is sealed or covered with a cured product of the composition described above, the optical semiconductor device having excellent reliability after a sulfur resistance test.

  本发明提供了一种可固化的有机硅组合物，用于形成一种固化产品，该固化产品可抑制光学半导体器件中的银电极或镀银基板因含硫气体而变色，该可固化的有机硅组合物包括：(A)有机聚硅氧烷，其每个分子至少具有两个硅键烯基；(B)有机氢聚硅氧烷，其每个分子至少具有两个硅键氢原子；(C)有机化合物，其有机值在有机概念图中至少为175，并具有特定基团；和(D)氢化硅反应催化剂。此外，本发明还提供了一种光半导体器件，在该器件中，光半导体器件的银电极或镀银基板被上述组合物的固化产物密封或覆盖，该光半导体器件在耐硫测试后具有极佳的可靠性。
• CURABLE SILICONE COMPOSITION, CURED OBJECT THEREOF, AND OPTICAL SEMICONDUCTOR DEVICE
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP3103843A1

  公开（公告）日：2016-12-14

  A curable silicone composition comprising: (A) an organopolysiloxane represented by the average unit formula: (R13SiO1/2)a(R22SiO2/2)b(R3SiO3/2)c (R1 are alkyl groups, alkenyl groups, aryl groups, or aralkyl groups; R2 are alkyl groups or alkenyl groups; R3 is an alkyl group, aryl group, or an aralkyl group, provided that, in a molecule, at least 0.5 mol% of R1 to R3 are the alkenyl groups, at least one of R3 is the aryl group or the aralkyl group; and a, b, and c are numbers satisfying: 0.01 ≤ a ≤ 0.5, 0.4 ≤ b ≤ 0.8, 0.01 ≤ c ≤ 0.5, and a + b + c = 1); (B) an organopolysiloxane that is different from component (A); (C) an organopolysiloxane having at least two silicon atom-bonded hydrogen atoms in a molecule; and (D) a hydrosilylation reaction catalyst. A cured product exhibiting excellent dispersibility of phosphor and having high strength and gas barrier properties is formed.

  一种可固化的有机硅组合物，包括： (A) 由平均单元式表示的有机聚硅氧烷：(R13SiO1/2)a(R22SiO2/2)b(R3SiO3/2)c(R1是烷基、烯基、芳基或芳烷基；R2是烷基或烯基；R3是烷基、芳基或芳烷基，条件是在一个分子中，至少0.5 mol%的R1至R3是烯基，R3中至少有一个是芳基或芳烷基；a、b和c是满足以下条件的数字：0.01≤a≤0.5，0.4≤b≤0.8，0.01≤c≤0.5，且a＋b＋c＝1）；(B)不同于组分(A)的有机聚硅氧烷；(C)分子中至少有两个硅原子键合氢原子的有机聚硅氧烷；以及(D)加氢硅烷化反应催化剂。这样就形成了一种具有优异的荧光粉分散性、高强度和气体阻隔性的固化产品。