N,N'-bis{3-(2-nitrobenzoyl)aminopropyl}oxamide

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N,N'-bis{3-(2-nitrobenzoyl)aminopropyl}oxamide
• 英文别名: N,N'-bis[3-[(2-nitrobenzoyl)amino]propyl]oxamide
• 化学式: C₂₂H₂₄N₆O₈
• 分子量: 500.468
• InChiKey: OTQPOFPKOQISOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  36
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  208
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  N¹,N²-bis(3-aminopropyl)oxalamide 、 邻硝基苯甲酸 在 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以68%的产率得到N,N'-bis{3-(2-nitrobenzoyl)aminopropyl}oxamide
  参考文献：
  名称：

  Amide-nitrophenyl based colorimetric receptors for selective sensing of fluoride ions

  摘要：

  New chromogenic receptors containing 2-nitroplienyl or 3,5-dinitrophenyl groups appended to the amide or ill secondary airline positions have been synthesized and characterized. Upon addition of fluoride to two of the receptors ill acetonitrile, the solution acquired a yellow colour. The third receptor showed an intense purple colour with fluoride in acetonitrile and the appearance of the purple colour can be detected by the naked eye at parts per million level. The addition of chloride, bromide and iodide to the receptors did not induce any colour. Thus the receptors can act as fluoride ion sensors even in the presence of other halide ions. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.08.045

文献信息

• Amide-nitrophenyl based colorimetric receptors for selective sensing of fluoride ions
  作者：Duraisamy Saravanakumar、Nallathambi Sengottuvelan、Muthusamy Kandaswamy、Paduthapillai Gopal Aravindan、Devadoss Velmurugan

  DOI：10.1016/j.tetlet.2005.08.045

  日期：2005.10

  New chromogenic receptors containing 2-nitroplienyl or 3,5-dinitrophenyl groups appended to the amide or ill secondary airline positions have been synthesized and characterized. Upon addition of fluoride to two of the receptors ill acetonitrile, the solution acquired a yellow colour. The third receptor showed an intense purple colour with fluoride in acetonitrile and the appearance of the purple colour can be detected by the naked eye at parts per million level. The addition of chloride, bromide and iodide to the receptors did not induce any colour. Thus the receptors can act as fluoride ion sensors even in the presence of other halide ions. (c) 2005 Elsevier Ltd. All rights reserved.