2,8,14,20-tetraoctyl-4,6,10,12,16,18,22,24-octa[3-(dimethoxyphosphoryl)-2-oxopropyl]calix[4]resorcinolarene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2,8,14,20-tetraoctyl-4,6,10,12,16,18,22,24-octa[3-(dimethoxyphosphoryl)-2-oxopropyl]calix[4]resorcinolarene
• 英文别名: 1-Dimethoxyphosphoryl-3-[[6,10,12,16,18,22,24-heptakis(3-dimethoxyphosphoryl-2-oxopropoxy)-2,8,14,20-tetraoctyl-4-pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(25),3(28),4,6,9(27),10,12,15,17,19(26),21,23-dodecaenyl]oxy]propan-2-one
• 化学式: C₁₀₀H₁₆₀O₄₀P₈
• 分子量: 2250.14
• InChiKey: JHTLEFWMKIWCPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.2
• 重原子数：
  148
• 可旋转键数：
  84
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  495
• 氢给体数：
  0
• 氢受体数：
  40

反应信息

• 作为产物：
  描述：

  甲基膦酸二甲酯 、 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 51.0h， 以79%的产率得到2,8,14,20-tetraoctyl-4,6,10,12,16,18,22,24-octa[3-(dimethoxyphosphoryl)-2-oxopropyl]calix[4]resorcinolarene
  参考文献：
  名称：

  摘要：

  An effective method for introduction of beta-phosphonate fragments to a calix[4]resorcinolarene matrix is presented octa(ketophosphonate)calix[4]resorcinolarenes are prepared. The effectiveness of 2,8,14,20-tetramethyl-4,6,10,12,16,18,22,24-octa[3-(dimethoxyphosphoryl)-2-oxopropyl]calix[4]-resorcinolarene for extraction of lanthanum ions from water to chloroform in the presence of picrate ions, accompanied by formation of a complex is demonstrated.

  DOI：

  10.1023/a:1026352801980

文献信息

• ——
  作者：A. V. Prosvirkin、E. Kh. Kazakova、V. L. Habicher、S. V. Fedorenko、A. R. Mustafina、A. I. Konovalov

  DOI：10.1023/a:1026352801980

  日期：——

  An effective method for introduction of beta-phosphonate fragments to a calix[4]resorcinolarene matrix is presented octa(ketophosphonate)calix[4]resorcinolarenes are prepared. The effectiveness of 2,8,14,20-tetramethyl-4,6,10,12,16,18,22,24-octa[3-(dimethoxyphosphoryl)-2-oxopropyl]calix[4]-resorcinolarene for extraction of lanthanum ions from water to chloroform in the presence of picrate ions, accompanied by formation of a complex is demonstrated.