二氯丙酰苯胺 | 17839-22-4

• 物质功能分类: 分析化学 - 标准品 - 农残、兽药及化肥类
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二氯丙酰苯胺
• 中文别名: 3',4'-二氯-N-丙酰苯胺;N-丙酰-3,4-二氯苯胺；敌稗
• 英文名称: 2.3-Dichlor-propionsaeure-anilid
• 英文别名: 2,3-Dichloropropionanilide；2,3-dichloro-N-phenylpropanamide
• CAS: 17839-22-4
• 化学式: C₉H₉Cl₂NO
• mdl: MFCD00142791
• 分子量: 218.083
• InChiKey: TZDRAQXFGLPUPV-UHFFFAOYSA-N

物化性质

• 沸点：
  377.1±32.0 °C(Predicted)
• 密度：
  1.344±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.222
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 危险品标志：
  Xn
• 危险类别码：
  R22
• 海关编码：
  2924299031
• 危险品运输编号：
  UN3077 9/PG 3

反应信息

• 作为产物：
  描述：

  2,3-二氯丙酰氯 、 苯胺 在 氨 、 N,N-二甲基苯胺 作用下， 以 苯 为溶剂， 生成 二氯丙酰苯胺
  参考文献：
  名称：

  Aliev,N.A. et al., Journal of general chemistry of the USSR, 1966, vol. 36, # 4, p. 653 - 654

  摘要：

  DOI：

文献信息

• Cyanbenzofuran derivatives, processes for their preparation and their use in herbicidal compositions; cyanobenzene, benzodioxepine, benzodioxaphosphepine and benzodioxathiepine derivatives
  申请人：FBC LIMITED

  公开号：EP0007719A2

  公开（公告）日：1980-02-06

  The invention provides herbicidally-active 2,3-dihydro-5-cyano-benzofurans of the formula: (wherein: R' and R2 together represent =O or R' represents hydrogen and R2 represents hydrogen, hydroxy, alkoxy, acyloxy, alkoxycarbonyloxy, alkylthiocarbonyloxy, halogen, isothiocyanato, amino, alkylamino, dialkylamino, arylamino, acylamino, alkoxycarbonylamino, alkyhhiocarbonylamino. N-bonded heterocyclyl, cyano or alkylthio; R3 and R4 together represent alkylene or each represent hydrogen or alkyl; and R5, R6 and R7, which may be the same or different, each represent hydrogen, halogen, alkyl, alkoxy, acyl or cyano), processes for their preparation and herbicidal compositions containing them.

  本发明提供了具有除草活性的 2,3-二氢-5-氰基苯并呋喃，其化学式为 其中R'和R2一起代表＝O或R'代表氢，R2代表氢、羟基、烷氧基、酰氧基、烷氧基羰氧基、烷硫基羰氧基、卤素、异硫氰基、氨基、烷基氨基、二烷基氨基、芳基氨基、酰氨基、烷氧基羰基氨基、烷硫基羰基氨基。R3和R4共同代表亚烷基或各自代表氢或烷基；R5、R6和R7可以相同或不同，各自代表氢、卤素、烷基、烷氧基、酰基或氰基），以及它们的制备方法和含有它们的除草组合物。
• Herbicidal cyclohexane-1,3-dione derivatives
  申请人：ICI AUSTRALIA LIMITED

  公开号：EP0124992A1

  公开（公告）日：1984-11-14

  The invention concerns novel compounds of the formula I wherein: A, B, D and E are selected from CH, N and N-Z wherein Z is selected from oxygen and the group YAn wherein Y is selected from alkyl and benzyl and An is an anion, and provided that no more than three of A, B, D and E are selected from N and N-Z and no more than one of A, B, D and E is selected from N-Z; W is a saturated or unsaturated C2 to C. hydrocarbon chain; X and X' are independently selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, alkanoyloxy, benzyloxy, substituted benzyloxy, amino, substituted amino and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof, ortwo ofX' on the same carbon atom may form an oxo group; R' is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation; R2 is selected from alkyl, substituted alkyl, alkenyl,haloalkenyl, alkynyl and haloalkynyl; R3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl; R4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl; n is 0 or an integer chosen from 1 to 3; and n' is 0 or an integer chosen from 1 to 5. The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula 1, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.

  本发明涉及式 I 的新型化合物 其中 A、B、D 和 E 选自 CH、N 和 N-Z，其中 Z 选自氧和基团 YAn，其中 Y 选自烷基和苄基，An 是阴离子，条件是 A、B、D 和 E 中不超过三个选自 N 和 N-Z，且 A、B、D 和 E 中不超过一个选自 N-Z； W 是饱和或不饱和的 C2 至 C.烃链； X 和 X'独立选自卤素、硝基、氰基、烷基、取代的烷基、羟基、烷氧基、取代的烷氧基、烯基、烯氧基、炔基、炔氧基、酰氧基、烷氧基羰基、烷硫基、烷基亚磺酰基、烷基磺酰基、氨基磺酰基、取代的氨基磺酰基、烷基硫酰基、烷基磺酰基、取代的氨基磺酰基、烷酰氧基、苄氧基、取代的苄氧基、氨基、取代的氨基、甲酰基和烷酰基及其肟、亚胺和希夫碱衍生物，或同一碳原子上的两个 X'可形成一个氧代基团； R' 选自氢、烷基、烯基、炔基、取代烷基、烷基磺酰基、芳基磺酰基、酰基和无机或有机阳离子； R2 选自烷基、取代烷基、烯基、卤代烯基、炔基和卤代炔基； R3 选自烷基、氟烷基、烯基、炔基和苯基； R4 选自氢、卤素、烷基、氰基和烷氧羰基； n 是 0 或 1 至 3 的整数；以及 n' 为 0 或 1 至 5 的整数。 本发明的化合物具有除草特性和植物生长调节特性，在进一步的实施方案中，本发明提供了制备式 I 化合物的工艺、用于制备式 1 化合物的中间体、含有式 I 化合物作为活性成分的组合物，以及利用式 I 化合物的除草和植物生长调节工艺。
• Optical isomer of triazolylpentenols, and their production and use as fungicide herbicide and/or plant growth regulant
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0175278A2

  公开（公告）日：1986-03-26

  Triazolyl alcohol derivative having an optical activity of (-) or (+) and represented by the general formula (I), wherein X represents a hydrogen atom or a chlorine atom and the asterisk indicates an asymmetric carbon atom, are prepared by stereospecific reduction of the corresponding ketone or by resolution of the racemate. The (-)-isomer is useful as a fungicide while the (+)-isomer is useful as a plant growth regulant or herbicide.

  光学活性为(-)或(+)的三唑醇衍生物由通式(I)表示、 其中 X 代表氢原子或氯原子，星号表示不对称碳原子，通过相应酮的立体还原或外消旋体的解析制备。(-)-异构体可用作杀真菌剂，而(+)-异构体可用作植物生长调节剂或除草剂。
• A particle growth inhibitor
  申请人：Kao Corporation

  公开号：EP0226815A2

  公开（公告）日：1987-07-01

  A finely divided biocidal substance is maintained very fine and stable in an aqueous suspension over a long period of storage or cyclical storage between low and high temperatures by adding to said aqueous suspension a particle growth inhibitor comprising: (1) A water-soluble or water-dispersible polymer containing as its essential constituent at least one compound selected from the monomer group consisting of unsaturated carboxylic acids and their derivatives, (2) A water-soluble or water-dispersible polymer containing styrene sulfonates as its essential constituent, or (3) A formalin condensate or a salt thereof of sulfonation products of a polycyclic aromatic compound which may contain a hydrocarbon group as a substituent.

  在水悬浮液中加入颗粒生长抑制剂，可使细小的杀菌物质在长期储存或在低温和高温之间循环储存时保持非常细小和稳定，颗粒生长抑制剂包括 (1) 一种水溶性或水分散性聚合物，其基本成分至少含有一种选自不饱和羧酸及其衍生物单体组的化合物、 (2) 以苯乙烯磺酸盐为主要成分的水溶性或水分散性聚合物，或 (3) 多环芳香族化合物磺化产物的福尔马林缩合物或其盐，该化合物可含有一个烃基作为取代基。
• Iminophenylthiazolidines, process of preparation, and method of use
  申请人：ICI AMERICAS INC.

  公开号：EP0318253A1

  公开（公告）日：1989-05-31

  A 2-iminophenyl thiazolidine having the formula wherein R is hydrogen or methyl; R₁ is halo, nitro, cyano, C₁-C₄ alkyl, C₁-C₄ alkoxy, perhalomethyl, difluoromethyl, pentafluoroethyl, trifluoro­methylthio, difluoromethoxy, trifluoromethoxy, tetrafluoroethoxy, methylsul­fonyl, C₁-C₄ alkyloxyiminomethyl, benzyloxyiminomethyl, 1-(C₁-C₄ alkyl)-­oxyiminoethyl or 1-benzyloxyiminoethyl; R₂ is hydrogen or halo; R₃ and R₄ are independently hydrogen, halo, nitro, cyano, C₁-C₄ haloalkyl, C₁-C₄ alkyl, C₁-C₄ fluoroalkoxy, C₁-C₄ alkoxy or C₁-C₄ alkylthio; and X is hydrogen or halogen. Also disclosed is a process for making the compounds and a method of use which comprises applying the compound or composition to the locus where control is desired.

  一种 2-亚氨基苯基噻唑烷，其式如下 其中 R 是氢或甲基；R₁ 是卤素、硝基、氰基、C₁-C₄ 烷基、C₁-C₄ 烷氧基、全氟甲基、二氟甲基、五氟乙基、三氟甲硫基、二氟甲氧基三氟甲氧基、四氟乙氧基、甲磺酰基、C₁-C₄ 烷氧基亚氨基甲基、苄氧基亚氨基甲基、1-(C₁-C₄ 烷基)-氧亚氨基乙基或 1-苄氧基亚氨基乙基；R₂ 是氢或卤素；R₃ 和 R₄ 独立地是氢、卤素、硝基、氰基、C₁-C₄ 卤代烷基、C₁-C₄ 烷基、C₁-C₄ 氟代烷氧基、C₁-C₄ 烷氧基或 C₁-C₄ 烷硫基；以及 X 是氢或卤素。 还公开了一种制造化合物的工艺和一种使用方法，其包括将化合物或组合物施用到需要控制的部位。