1-(9-ethylcarbazol-3-ylmethylene)-2-(2,3-epoxypropyl)-2-phenylhydrazine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1-(9-ethylcarbazol-3-ylmethylene)-2-(2,3-epoxypropyl)-2-phenylhydrazine
• 英文别名: 9-ethyl-9H-3-carbazolecarbaldehyde N-2,3-epoxypropyl-N-phenylhydrazone；9-ethyl-3-carbazolecarbaldehyde N-(2,3-epoxy)propyl-N-phenylhydrazone；9-ethyl-3-carbazolecarboxaldehyde N-(2,3-epoxypropyl)-N-phenylhydrazone；9-ethyl-3-carbazolecarboxaldehyde N-2,3-epoxypropyl-N-phenylhydrazone；N-[(E)-(9-ethylcarbazol-3-yl)methylideneamino]-N-(oxiran-2-ylmethyl)aniline
• 化学式: C₂₄H₂₃N₃O
• 分子量: 369.466
• InChiKey: UJMMAKAVKIEQRO-MFKUBSTISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  33.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(9-ethylcarbazol-3-ylmethylene)-2-(2,3-epoxypropyl)-2-phenylhydrazine 在 三乙胺 作用下， 以 丁酮 为溶剂， 反应 19.0h， 生成 1,3-bis[6-(9-ethylcarbazol-3-ylmethylene)-3-hydroxy-5-phenyl-5,6-diaza-1-oxahexyl]benzene
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1020617317256
• 作为产物：
  描述：

  N-乙基咔唑-3-甲醛 在 氢氧化钾 、 sodium sulfate 作用下， 以 异丙醇 为溶剂， 反应 0.17h， 生成 1-(9-ethylcarbazol-3-ylmethylene)-2-(2,3-epoxypropyl)-2-phenylhydrazine
  参考文献：
  名称：

  An Efficient Scalable Synthesis of 2,3-Epoxypropyl Phenylhydrazones

  摘要：

  以9-乙基-3-咔唑甲醛、9-乙基-3,6-咔唑二甲醛、4 -二甲基-氨基-、4-二乙基氨基-、4-苄基乙基氨基-、4-(二苯基氨基)-、4-(4,4-4'-二甲基-二苯基氨基)-、4-(4-甲酰基二苯基氨基)-和4- (4-甲酰基-4'-甲基二苯基氨基)苯甲醛与环氧氯丙烷在 KOH 和无水 Na2SO4 存在下反应。

  DOI：

  10.3390/11010064

文献信息

• Linked dihydrazone-based charge transport compounds
  申请人：——

  公开号：US20030232261A1

  公开（公告）日：2003-12-18

  This invention relates to a novel organophotoreceptor that includes: (a) a charge transport compound having the formula 1 where n is an integer from 0 to 1 inclusive; X is an (N,N-disubstituted)arylamine, such as a carbazole group, a julolidine group, or a p-(N,N-disubstituted)arylamine group (which can be a triarylamine, an alkyldiarylamine or a dialkylarylamine); Ar is an aryl group or a heterocyclic group; A is a linking group having the formula —S—(CH 2 ) m —S— where m is an integer from 1 to 15 inclusive and; B is a second linking group with the formula —(CH 2 ) p — which can be branched or linear, where p is an integer from 3 and 20 inclusive and where one or more methylene groups can be optionally replaced by O, S, a carbonyl group, urethane, urea, an ester group, a —NR 21 group, a CHR 22 group, or a CR 23 R 24 group where R 21 , R 22 , R 23 and R 24 are, independently, H, hydroxyl, thiol, an amine group, an alkyl group, an alkaryl group, an aryl group, or part of a ring; (b) a charge generating compound; and (c) an electrically conductive substrate over which the charge transport compound and the charge generating compound are located.

  这项发明涉及一种新型的有机光感受器，其中包括：(a) 具有以下化学式的电荷传输化合物：其中n为0至1之间的整数；X为(N,N-二取代)芳胺，如咔唑基、茱萸啉基或p-(N,N-二取代)芳胺基（可以是三芳基胺、烷基二芳基胺或二烷基芳胺）；Ar为芳基或杂环基；A为具有以下化学式的连接基：—S—(CH2)m—S—，其中m为1至15之间的整数；B为具有以下化学式的第二连接基：—(CH2)p—，可以是支链或线性，其中p为3至20之间的整数，其中一个或多个亚甲基基团可以选择性地被O、S、羰基、脲基、尿素基、酯基、—NR21基团、CHR22基团或CR23R24基团取代，其中R21、R22、R23和R24分别独立地为H、羟基、硫醇基、胺基、烷基、烷基芳基、芳基或环的一部分；(b) 电荷生成化合物；和(c) 电导基底，覆盖在电荷传输化合物和电荷生成化合物之上。
• Organophotoreceptor with charge transport material having two linked hydrazone groups
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP1443039A1

  公开（公告）日：2004-08-04

  The present invention provides an organophotoreceptor comprising an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula    where R1, R2, R3, R4, and R5 are, independently, an alkyl group, an alkaryl group, an aryl group, or a heterocyclic group;    R6 and R7 are, independently, hydrogen, an alkyl group, an alkaryl group, an aryl group, or a heterocyclic group;    Y is a linking group having the formula -(CH2)m-, branched or linear, where m is an integer between 1 and 20, inclusive, and one or more of the methylene groups is optionally replaced;    X comprises an aromatic group, such as an aryl group or an aromatic heterocyclic group; and    Z comprises an arylamine group, such as a carbazole group, a julolidine group, or an (N,N-disubstituted)arylamine group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

  本发明提供了一种包括电导基底和位于电导基底上的光电元件的有机光感受器，其中光电元件包括： (a) 具有以下结构的电荷传输材料： 其中，R1、R2、R3、R4 和 R5 分别是烷基基团、烷芳基团、芳基团或杂环基团； R6 和 R7 分别是氢、烷基基团、烷芳基团、芳基团或杂环基团； Y 是具有以下结构的连接基团 -(CH2)m-，分支或直链，其中 m 是介于 1 和 20 之间的整数，包括 1 和 20，其中一个或多个亚甲基基团可选择性地被取代； X 包括芳香基团，例如芳基团或芳香杂环基团；以及 Z 包括芳胺基团，例如咔唑基团、茱萸啉基团或 (N,N-二取代)芳胺基团；以及 (b) 一种电荷生成化合物。 描述了相应的静电复印设备和成像方法。
• Heterocycle-hydrazone based charge transport materials
  申请人：Daskeviciene Maryte

  公开号：US20060166118A1

  公开（公告）日：2006-07-27

  Improved organophotoreceptor comprises an electrically conductive substrate and a photoconductive element on the electrically conductive substrate, the photoconductive element comprising: (a) a charge transport material having the formula: where n is an integer between 1 and 10, inclusive; R 1 comprises a functional group selected from the group consisting of a reactive ring group, an ethylenically unsaturated group, a reactive polar group, a hydrazone group, and an azine group; R 2 , R 3 , R 4 , R 5 , and R 6 comprise, each independently, H, an alkyl group, an alkenyl group, an alkynyl group, an aromatic group, a heterocyclic group, or a part of a ring group; X is a bond or a linking group; and Q is O, S, or NR where R is H, an alkyl group, an acyl group, an alkenyl group, an alkynyl group, a heterocyclic group, or an aromatic group; and (b) a charge generating compound.

  改进的有机光电接收器包括电导基底和电导基底上的光电元件，光电元件包括： （a）具有以下公式的电荷传输材料：其中n是1到10之间的整数，包括1和10；R1包括从反应性环基团、乙烯基不饱和基团、反应性极性基团、腙基团和偶氮基团中选择的官能团；R2、R3、R4、R5和R6分别独立地包括H、烷基、烯基、炔基、芳香基、杂环基或环基的一部分；X是键或连接基团；Q是O、S或NR，其中R是H、烷基、酰基、烯基、炔基、杂环基或芳香基；以及（b）电荷生成化合物。
• Organophotoreceptor with charge transport material having a thiiranyl group
  申请人：Tokarski Zbigniew

  公开号：US20050147904A1

  公开（公告）日：2005-07-07

  Improved organophotoreceptor comprises a photoconductive element comprising: (a) a charge transport material having the formula where Y 1 and Y 2 are, each independently, a bond, —CR 1 ═N—NR 2 —, or —CR 3 ═N—N═CR 4 — where R 1 , R 2 , R 3 , and R 4 comprise, each independently, H, an alkyl group, an alkenyl group, a heterocyclic group, or an aromatic group; X 1 and X 2 are, each independently, a linking group; T 1 and T 2 are, each independently, a thiiranyl group, H, an alkyl group, an alkenyl group, or an aromatic group with the proviso that at least one of T 1 and T 2 is a thiiranyl group; and Ar comprises an aromatic group with the proviso that when both Y 1 and Y 2 are a bond and one of T 1 and T 2 is not a thiiranyl group, Ar comprises a bis[(N,N-disubstituted)amino]aromatic group or a bicarbazole group; and (b) a charge generating compound. Corresponding electrophotographic apparatuses and imaging methods are described.

  改进的光电感受器包括一个光电传导元件，其包括：（a）一个具有以下式子的电荷传输材料，其中Y1和Y2分别独立地是键合，—CR1═N—NR2—，或—CR3═N—N═CR4—，其中R1、R2、R3和R4分别为H、烷基、烯基、杂环基或芳香基；X1和X2分别独立地是连接基；T1和T2分别独立地是硫杂环基、H、烷基、烯基或芳香基，但至少有一个是硫杂环基；而Ar是一个芳香基，但当Y1和Y2都是键合且T1和T2中的一个不是硫杂环基时，Ar是一个双[(N,N-二取代)氨基]芳香基或双咔唑基；以及（b）一个电荷发生化合物。还描述了相应的电子照相设备和成像方法。
• Bridged charge transport materials having a central sulfur atom linkage
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：EP1600821B1

  公开（公告）日：2007-02-28