(1R)-trans-2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropane-1-carboxylic acid chloride

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (1R)-trans-2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropane-1-carboxylic acid chloride
• 英文别名: (1R)-trans-3-(2,2-dichloro-1-ethenyl)-2,2-dimethyl cyclopropane carboxylic acid chloride；(1R)-trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid chloride；1R,cis-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylic acid chloride；(1R)-trans-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarbonyl chloride；1R-cis-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarbonyl chloride；(1R)-trans-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropane-1-carboxylic acid chloride；(1R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carbonyl chloride
• 化学式: C₈H₉Cl₃O
• 分子量: 227.518
• InChiKey: CHLAOFANYRDCPD-RZKHNPSRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (1R)-trans-2,2-dimethyl-3-(2,2-dichlorovinyl)-cyclopropane-1-carboxylic acid chloride 、 4-phenyl-2-indanol 以 吡啶 、 甲苯 为溶剂， 生成 (+)-4-phenyl-2-indanyl 1R,cis-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
  参考文献：
  名称：

  Process for producing (+)-4-substituted-2-indanols

  摘要：

  公开了以下式的新化合物##STR1##，其中R.sup.1是苯基、苯氧基、苯硫基、苄基或杂环基，可以被取代，R.sup.2是氢、取代的乙烯基环丙烷羰基、四甲基环丙烷羰基，或1-(取代苯基)-2-甲基丙基羰基，并且在茚环的C-2处具有S构型的异构体过量存在于R构型的异构体之上。还公开了一种制备光学活性醇的方法。其中R.sup.2不是氢的化合物是杀虫剂。

  公开号：

  US04417078A1

文献信息

• Heterocyclic substituted benzyl alcohol, insecticidal ester derivatives,
  申请人：FMC Corporation

  公开号：US04426524A1

  公开（公告）日：1984-01-17

  Disclosed and exemplified are insecticidal and acaricidal optionally substituted furylbenzyl, thienylbenzyl, pyrazinylbenzyl, or pyridinzylbenzyl esters of the pyrethroid acids, novel pyrethroid alcohols and other intermediates, and compositions, a method of use and a process for preparation of the esters.

  披露并举例说明了杀虫和杀螨的可选择取代的呋喃基苄基、噻吩基苄基、吡嗪基苄基或吡啶基苄基除虫酯，新型除虫醇和其他中间体，以及组合物，使用方法和酯类制备方法。
• Ester compound, active agent for controlling noxious insect pests
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05550258A1

  公开（公告）日：1996-08-27

  The present invention provides an ester compound represented by a formula I: ##STR1## wherein R.sub.1 denotes a hydrogen atom or a methyl group; R.sub.2 represents a 1-methyl-2-propenyl group, a 1-methyl-2-propynyl group, a 3,3-dihalogeno-1-methyl-2-propenyl group, or a C.sub.1 -C.sub.1 6 alkyl group which may be substituted with at least one halogen atom; and R.sub.3 represents an acid residue of pyrethroids. The invention also relates to an active agent for controlling noxious insect pests containing the ester compound as an active ingredient, an intermediate for production of the ester compound and a process for producing the intermediate. The ester compound represented by the formula I has good activities for controlling noxious insect pests.

  本发明提供了一种由公式I表示的酯化合物：##STR1## 其中R1表示氢原子或甲基；R2表示1-甲基-2-丙烯基，1-甲基-2-丙炔基，3,3-二卤代-1-甲基-2-丙烯基或C1-C16的烷基，该烷基可被至少一个卤素原子取代；R3表示拟除虫菊酯的酸残基。本发明还涉及一种含有该酯化合物作为活性成分的用于控制有害昆虫的活性剂，用于生产该酯化合物的中间体以及生产该中间体的方法。公式I所表示的酯化合物对控制有害昆虫具有良好的活性。
• Ester compounds pesticidal compositions containing the same and
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05925676A1

  公开（公告）日：1999-07-20

  An ester compound represented by the formula ##STR1## wherein R.sub.1 and R.sub.2 may be the same or different and each represent a C.sub.1 -C.sub.6 alkyl group, or other specified groups, which may be optionally substituted with one or more halogen atoms; and R.sub.3 represents a pyrethroid acid residue (a group resulting from elimination of the carboxyl group from pyrethroid acid), and a pesticidal composition containing the ester compound as an active ingredient.

  由公式##STR1##表示的酯化合物，其中R1和R2可以相同或不同，每个代表一个C1-C6烷基团，或者其他指定的团，可任选地用一个或多个卤素原子取代；R3代表拟除虫菊酯酸残基（即从拟除虫菊酯酸中消除羧基得到的团），以及包含该酯化合物作为活性成分的杀虫剂组合物。
• Ester compound, agent for controlling noxious organisms containing the
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05653990A1

  公开（公告）日：1997-08-05

  There is provided an ester compound represented by the formula I: ##STR1## wherein R.sub.1 is a methyl group or a hydrogen atom; R.sub.2 is a C.sub.1-6 haloalkyl group; and R.sub.3 is a pyrethroid acid residue, an agent for controlling noxious organisms containing the same as active ingredient and an intermediate for producing the same.

  提供了一种由公式I表示的酯化合物：##STR1## 其中R1是甲基或氢原子；R2是C1-6卤代烷基；R3是拟除虫菊酸残基，含有作为活性成分的同一控制有害生物的药剂以及用于生产该化合物的中间体。
• (+)-4-Substituted-2-indanol insecticidal ester derivatives
  申请人：FMC Corporation

  公开号：US04333950A1

  公开（公告）日：1982-06-08

  Novel compounds of the formula ##STR1## are disclosed in which R.sup.1 is a phenyl, phenoxy, phenylthio, benzyl or heterocyclic radical which may be substituted, R.sup.2 is hydrogen, a substituted-vinylcyclopropanecarbonyl group, a tetramethylcyclopropanecarbonyl group, or a 1-(substituted-phenyl)-2-methylpropylcarbonyl group, and the isomer of S configuration at C-2 of the indanyl ring is present in an enantiomeric excess over the isomer of R configuration. Also disclosed is a method for preparing the optically active alcohols. The compounds wherein R.sup.2 is other than hydrogen are insecticides.

  公开了化合物的新结构，其化学式为##STR1##其中R.sup.1是苯基、苯氧基、苯硫基、苄基或杂环基，可以是取代基，R.sup.2是氢、取代乙烯环丙烷羰基、四甲基环丙烷羰基，或者1-(取代苯基)-2-甲基丙烷羰基，并且在印地烯环的C-2处的S构型异构体的旋光过量超过了R构型的异构体。还公开了一种制备光学活性醇的方法。其中R.sup.2不是氢的化合物是杀虫剂。