二癸二酸,混合物和己烷-1,6-二胺(1:1) | 13188-60-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 二癸二酸,混合物和己烷-1,6-二胺(1:1)
• 英文名称: Nylon 6/12
• 英文别名: dodecanedioic acid;hexane-1,6-diamine
• CAS: 13188-60-8
• 化学式: C18H38N2O4
• 分子量: 346.5
• InChiKey: ZMUCVNSKULGPQG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.52
• 重原子数：
  24
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  127
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  己内酰胺 、 12-氨基十二酸 、 水 反应 5.5h， 以obtaining a nylon 6/12 polymer的产率得到二癸二酸,混合物和己烷-1,6-二胺(1:1)
  参考文献：
  名称：

  Biaxilly oriented polyamide film and its production process

  摘要：

  一种双向拉伸的聚酰胺薄膜，不仅具有优异的折弯穿孔抗性和优异的尺寸稳定性，而且在薄膜纵向具有优异的撕裂线性。更具体地说，本发明提供了一种双向拉伸的聚酰胺薄膜，在其中将尼龙6和脂肪族聚酰胺树脂混合，其重量比为75:25至99:1，其中尼龙6和聚酰胺除尼龙6以外的表面张力差（dyne/cm）满足以下关系式（1）3.0≤γA-γB≤15.0（1），其中γA是N6的表面张力，γB是PA的表面张力。

  公开号：

  US05612105A1

文献信息

• Polyamide resin composition and process for producing the same
  申请人：Unitika Ltd.

  公开号：US06156838A1

  公开（公告）日：2000-12-05

  A polyamide resin composition comprising a copolyamide and silicate layers originating from a swellable fluoromica, dispersed in said copolyamide on a molecular level, wherein an average thickness and an average aspect ratio (length/thickness) of the silicate layers are within specific ranges. Also disclosed is a process for preparing the polyamide resin composition.

  一种聚酰胺树脂组合物，包括一种共聚酰胺和源于可膨胀氟云母的硅酸盐层，在分子水平上分散在所述共聚酰胺中，其中所述硅酸盐层的平均厚度和平均长宽比（长度/厚度）在特定范围内。还公开了制备聚酰胺树脂组合物的方法。
• Polyamide elastomer
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0095893A2

  公开（公告）日：1983-12-07

  Provided is a polyether-ester-amide consisting essentially of about 5 to 50 weight percent of polyamide segment (A) and about 95 to 50 weight percent of polyether ester segment (B), and having a melting point not lower than 160° C, a Shore hardness in the range of 80A to 45 D, a tensile modulus in the range of 100 to 1,000 kg/cm2 and an elastic recovery at 50 % elongation of not less than 70%, said polyamide segment (A) having been obtained from: a C6-C20 aliphatic diamine (A-1 and at least one dicarboxylic acid (A-2) selected from the group consisting of C6-C15 aliphatic dicarboxylic acids, terephthalic acid and hexahydroterephthalic acid, provided the total number of carbon atoms of said diamine and said dicarboxylic acid is not less than 16, said polyether ester segment (B) having been obtained from: a poly(alkylene oxide) glycol (B-1) having a ratio of carbon atoms number to oxygen atom number of not smaller than 2.3 and having a number average molecular weight in the range of 300 to 5.000; and a C4-C20 dicarboxylic acid (B-2).

  本发明提供了一种聚醚酯-酰胺，主要由约 5 至 50 重量百分比的聚酰胺段（A）和约 95 至 50 重量百分比的聚醚酯段 （B）组成，熔点不低于 160°C，邵氏硬度在 80A 至 45 D 之间，拉伸模量在 100 至 1,000 kg/cm2 之间，伸长率为 50%时的弹性恢复率不低于 70%，所述聚酰胺段（A）由以下材料制得： C6-C20 脂肪族二胺（A-1）和至少一种二羧酸（A-2），选自由 C6-C15 脂肪族二羧酸、对苯二甲酸和六氢对苯二甲酸组成的组，条件是所述二胺和所述二羧酸的碳原子总数不少于 16，所述聚醚酯段（B）由以下物质获得： 聚环氧烷二醇（B-1），其碳原子数与氧原子数之比不小于 2.3，且平均分子量在 300 至 5.000 之间；以及 C4-C20 二羧酸 (B-2)。
• Polyether-polyamide block copolymer and polyether prepolymer
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0293143A2

  公开（公告）日：1988-11-30

  A polyether-polyamide block copolymer having an ethylenically unsaturated group is represented by formula (I): and a polyether prepolymer thereof is represented by formula (II):     R¹ is H or an aliphatic hydrocarbon group, R² and R³ are each C2-6 aliphatic hydrocarbon, A is -OOC- or -OOC-NH-; B is C1-18 aliphatic hydrocarbon which may contain -NH-CO-NH, -NH-COO- or -NH-CO-; M is a hydrocarbon amide chain; Q is an ether or amino group, E is an aliphatic hydrocarbon ether or ester C1-12 group; V is an ethylenic hydrocarbon group; k=1-6, m=0-140, n=1-140, m+n=7-140; j, p, q=0 or 1, i=1-1000, r=5-500; and     Y is an isocyanate carbamoyl lactam, acid chloride or (oxy)carbonyl lactam group. The prepolymer can be made by polymerizing an alcohol as R¹ component and an unsaturated 1,2- epoxy compound and/or a cyclic ether in the presence of an ionic catalyst to form a block or random copolymer; a component reactant then replaces the hydroxyl groups. The prepolymer is linked to a polyamide moiety by anionic polymerisation of a lactam; the block copolymer can be of A-B, A-B-A or multi-block type. The drawings show NMR spectra of a prepolymer and copolymer. The copolymer is moldable at high temperature and has good heat stability.

  一种具有乙烯基不饱和基团的聚醚-聚酰胺嵌段共聚物由式（I）表示： 及其聚醚预聚物由式（II）表示： R¹ 是 H 或脂肪族烃基，R² 和 R³ 分别是 C2-6 脂肪族烃，A 是 -OOC- 或 -OOC-NH-；B 是 C1-18 脂肪族烃，可含有 -NH-CO-NH、-NH-COO- 或 -NH-CO-；M 是烃酰胺链；Q 是醚基或氨基，E 是 C1-12 脂肪烃醚或酯基；V 是乙烯烃基；k=1-6，m=0-140，n=1-140，m+n=7-140；j、p、q=0 或 1，i=1-1000，r=5-500；以及 Y 是异氰酸酯氨基甲酰基内酰胺、酸氯化物或（氧）羰基内酰胺基团。 预聚物的制造方法是：在离子催化剂存在下，将作为 R¹ 组分的醇和不饱和 1,2-环氧化合物和/或环醚聚合，形成嵌段或无规共聚物；然后用一种组分反应物取代羟基。预聚物通过内酰胺的阴离子聚合与聚酰胺分子相连；嵌段共聚物可以是 A-B、A-B-A 或多嵌段类型。 图中显示了预聚物和共聚物的核磁共振光谱。 共聚物可在高温下成型，并具有良好的热稳定性。
• Thermoplastic resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0335506A1

  公开（公告）日：1989-10-04

  The present invention provides a themo­plastic resin composition which is superior in mechani­cal properties, especially less in reduction of flexural modulus when absorbing water and superior in process­ability. This composition comprises: (A) 10 - 70 parts by weight of a poly­phenylene ether, a mixture of a polyphenylene ether and a polystyrene or a polyphenylene ether-styrene graft copolymer, (B) 90 - 30 parts by weight of a mixture of (i) a thermoplastic aromatic copolyamide and/or an aromatic nuclear-hydrogenated copolyamide in an amount of 0.1 - 70 % by weight of existing total poly­amide and (ii) a thermoplastic aliphatic polyamide in a complementary amount of 99.9 - 30 % by weight of existing total polyamide, and (c) 0.01 - 30 parts by weight, based on 100 parts by weight of the above components (A) and (B) of, at least one compound selected from the group consisting of oxazoline and a compound having, in its molecule, (a) carbon-carbon double bond or a carbon-­carbon triple bond and (b) at least one functional group selected from carboxyl group, acid anhydride group, amino group, acid amide group, imido group, epoxy group, carboxylate ester group, isocyanate group, methylol group, oxazolidine group and hydroxyl group. This composition may further contain an impact strength modifier, namely, rubber-like material and/or modified rubber-like material.

  本发明提供了一种机械性能优异，尤其是吸水后弯曲模量降低较少，且加工性能优异的热塑性树脂组合物。这种组合物包括 (A) 10 - 70 重量份的聚苯醚、聚苯醚和聚苯乙烯的混合物或聚苯醚-苯乙烯接枝共聚物、 (B) 90-30(重量份數)以下兩者的混合物：(i)熱塑性芳香族共聚醯胺及 ／或芳香族核氫化共聚醯胺，其重量份數為現有聚醯胺總重量的 0.1-70%；及(ii)熱塑性脂肪族聚醯胺，其補充量為現有聚醯胺總重量的 99.9-30%，及 (c) 0.(c) 以上述组分(A)和(B)的 100 重量份数为基准，0.01 - 30 重量份数的至少一种选 自噁唑啉和一种在其分子中具有以下特征的化合物所组成的组的化合物、(a) 碳碳双键或碳碳三键和 (b) 至少一个官能团，选自羧基、酸酐基、氨基、酸酰胺基、亚胺基、环氧基、 羧酸酯基、异氰酸酯基、甲醇基、噁唑烷基和羟基。 这种组合物还可进一步含有抗冲击强度改性剂，即橡胶类物质和/或改性橡胶类物质。
• Surface treating of polyphenylene ether thermoplastic shaped articles
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0447239A2

  公开（公告）日：1991-09-18

  A composition is prepared of, by wt, (I) 100 parts of a mixture of 5 to 100% of a polyphenylene ether or a mixture thereof with a styrene polyester, or a graft copolymer thereof and styrene and (b) 95 to 0% of a thermoplastic polyamide and/or saturated polyester resin; and optionally (II) 0 to 50 parts of a rubbery substance; (III) 0 to 50 parts of inorganic filler and/or glass fibers; and (IV) 0 to 10 parts of at least one of seven types of compatibilizer which improves compatibility of the polymers (I) (a) and (b). The production of these components is described. The components are mixed in any order and molded. The surface of the molded article, e.g. a film, plate or fibers, may be degreased and is irradiated with ultraviolet light of wavelength less than 300 nm, preferably 185 and 254 nm as main wavelengths, for 20 seconds to 10 minutes: The irradiation improves the coatability of the surface, which may then be coated with a coating of an alkyd-melamine or an acrylic urethane.

  一种组合物的制备方法，按重量份计，包括(I)100 份 5 至 100%的聚苯醚或其与苯乙烯聚酯或其与苯乙烯的接枝共聚物的混合物，以及(b)95 至 0%的热塑性聚酰胺和/或饱和聚酯树脂；(II) 0 至 50 份橡胶物质；(III) 0 至 50 份无机填料和/或玻璃纤维；(IV) 0 至 10 份至少七种相容剂中的一种，可改善聚合物 (I) (a) 和 (b) 的相容性。 现介绍这些成分的生产方法。 各组分以任意顺序混合并模塑。模塑制品（如薄膜、板材或纤维）的表面可进行脱脂处理，然后用波长小于 300 纳米的紫外线（主波长最好为 185 纳米和 254 纳米）照射 20 秒至 10 分钟：辐照可提高表面的可涂覆性，然后在表面涂上一层醇酸-三聚氰胺或丙烯酸聚氨酯。